GB909369A - Improvements in or relating to the polymerisation of acrylonitrile - Google Patents

Improvements in or relating to the polymerisation of acrylonitrile

Info

Publication number
GB909369A
GB909369A GB6173/61A GB617361A GB909369A GB 909369 A GB909369 A GB 909369A GB 6173/61 A GB6173/61 A GB 6173/61A GB 617361 A GB617361 A GB 617361A GB 909369 A GB909369 A GB 909369A
Authority
GB
United Kingdom
Prior art keywords
acrylonitrile
vinyl
added
polymerized
catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB6173/61A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Union Rheinische Braunkohlen Kraftstoff AG
Original Assignee
Union Rheinische Braunkohlen Kraftstoff AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Rheinische Braunkohlen Kraftstoff AG filed Critical Union Rheinische Braunkohlen Kraftstoff AG
Publication of GB909369A publication Critical patent/GB909369A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/42Nitriles
    • C08F20/44Acrylonitrile
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/36Polymerisation in solid state

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

Acrylonitrile is polymerized in solution in dimethyl sulphoxide in the presence of an anionic or free-radical catalyst, other than a peroxide, a portion only of the catalyst being added to the reaction mixture at the start of polymerization, the remainder being added in portions during the course of the reaction. The acrylonitrile may be polymerized alone or in the presence of a minor proportion of another monomer, e.g. allyl alcohol, vinyl acetate, methyl methacrylate, vinyl ethyl ether and 2-vinyl-5-ethyl pyridine. Catalysts specified are ammonium persulphate and azodiisobutyronitrile.
GB6173/61A 1960-03-12 1961-02-20 Improvements in or relating to the polymerisation of acrylonitrile Expired GB909369A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEU6971A DE1123833B (en) 1960-03-12 1960-03-12 Process for the polymerization of acrylonitrile

Publications (1)

Publication Number Publication Date
GB909369A true GB909369A (en) 1962-10-31

Family

ID=7565828

Family Applications (1)

Application Number Title Priority Date Filing Date
GB6173/61A Expired GB909369A (en) 1960-03-12 1961-02-20 Improvements in or relating to the polymerisation of acrylonitrile

Country Status (3)

Country Link
BE (1) BE600438A (en)
DE (1) DE1123833B (en)
GB (1) GB909369A (en)

Also Published As

Publication number Publication date
BE600438A (en) 1961-06-16
DE1123833B (en) 1962-02-15

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