GB1084412A - Improvements in and relating to adhesives - Google Patents

Improvements in and relating to adhesives

Info

Publication number
GB1084412A
GB1084412A GB51499/64A GB5149964A GB1084412A GB 1084412 A GB1084412 A GB 1084412A GB 51499/64 A GB51499/64 A GB 51499/64A GB 5149964 A GB5149964 A GB 5149964A GB 1084412 A GB1084412 A GB 1084412A
Authority
GB
United Kingdom
Prior art keywords
carbon atoms
acrylate
ester
ethyl
ethylenically unsaturated
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB51499/64A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Monsanto Co
Original Assignee
Monsanto Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Monsanto Co filed Critical Monsanto Co
Publication of GB1084412A publication Critical patent/GB1084412A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
    • C08F220/32—Esters containing oxygen in addition to the carboxy oxygen containing epoxy radicals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
    • C08F220/32—Esters containing oxygen in addition to the carboxy oxygen containing epoxy radicals
    • C08F220/325—Esters containing oxygen in addition to the carboxy oxygen containing epoxy radicals containing glycidyl radical, e.g. glycidyl (meth)acrylate

Abstract

A cross-linkable polymer is obtained by heating together at a temperature of from 65 DEG to 80 DEG C. in the presence of from 0.1 to 0.5% of an addition polymerization catalyst, a mixture comprising 35 to 75% by weight of an alkyl ester of an a -b -ethylenically unsaturated carboxylic acid having more than six carbon atoms per molecule, 10 to 60% of a lower alkyl ester of an acrylic acid having not more than 4 carbon atoms in the acid moiety and not more than 2 carbon atoms in the alkyl group, 0.1 to 10% of a carboxyl, carboxamide or ester group containing vinyl or vinylidene type monomer having active hydrogen in the molecule as determined by the Zerewitinoff method and 0.1 to 10% of a glycidyl ester of an ethylenically unsaturated carboxylic acid. Conventional free radical catalysts are used, e.g. azobisisobutyronitrile. Examples refer to the polymerization of the following monomers. 2, ethyl-hexyl acrylate, lauryl acrylate, methyl acrylate, ethyl acrylate, acrylic acid and glycidyl methacrylate. Solutions of the copolymers in, for example, ethyl acetate-hexane are used as adhesives, they are cured by heating at an elevated temperature.
GB51499/64A 1963-12-20 1964-12-18 Improvements in and relating to adhesives Expired GB1084412A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US33223863A 1963-12-20 1963-12-20

Publications (1)

Publication Number Publication Date
GB1084412A true GB1084412A (en) 1967-09-20

Family

ID=23297346

Family Applications (1)

Application Number Title Priority Date Filing Date
GB51499/64A Expired GB1084412A (en) 1963-12-20 1964-12-18 Improvements in and relating to adhesives

Country Status (1)

Country Link
GB (1) GB1084412A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004044021A2 (en) * 2002-11-14 2004-05-27 Lohmann Gmbh & Co.Kg Chemically inert contact adhesive having improved adhesive properties, method for the production thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004044021A2 (en) * 2002-11-14 2004-05-27 Lohmann Gmbh & Co.Kg Chemically inert contact adhesive having improved adhesive properties, method for the production thereof
WO2004044021A3 (en) * 2002-11-14 2004-12-09 Lohmann Gmbh & Co Kg Chemically inert contact adhesive having improved adhesive properties, method for the production thereof

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