GB906527A - Production of alkanols - Google Patents

Production of alkanols

Info

Publication number
GB906527A
GB906527A GB22336/60A GB2233660A GB906527A GB 906527 A GB906527 A GB 906527A GB 22336/60 A GB22336/60 A GB 22336/60A GB 2233660 A GB2233660 A GB 2233660A GB 906527 A GB906527 A GB 906527A
Authority
GB
United Kingdom
Prior art keywords
supported
reacting
hydrogen
copper catalyst
temperature
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB22336/60A
Inventor
Kenneth George Pickup
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Distillers Co Yeast Ltd
Distillers Co Ltd
Original Assignee
Distillers Co Yeast Ltd
Distillers Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Distillers Co Yeast Ltd, Distillers Co Ltd filed Critical Distillers Co Yeast Ltd
Priority to GB22336/60A priority Critical patent/GB906527A/en
Priority to DE1961D0036293 priority patent/DE1161250B/en
Publication of GB906527A publication Critical patent/GB906527A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
    • C07C29/141—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group with hydrogen or hydrogen-containing gases
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/17—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds
    • C07C29/175—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds with simultaneous reduction of an oxo group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/02—Monohydroxylic acyclic alcohols
    • C07C31/125—Monohydroxylic acyclic alcohols containing five to twenty-two carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/02—Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

An alkanol is produced by reacting in the vapour phase at elevated temperature an olefinically unsaturated aliphatic aldehyde with hydrogen in the presence of a supported copper catalyst and reacting the vaporized product with hydrogen in the presence of a supported nickel catalyst. Both catalysts are preferably supported on a siliceous earth such as kieselguhr. The copper catalyst may, if desired, contain one or more modifiers, for example, zinc, magnesium, chromium, iron or compounds of these metals, or a phosphate, tungstate, chromate, dichromate, molybdate, silicate or metaborate. The process is preferably carried out at a temperature of 130-180 DEG C. In the examples crotonaldehyde is converted to n-butanol and ethyl propyl acrolein to 2-ethyl hexanol.
GB22336/60A 1960-06-25 1960-06-25 Production of alkanols Expired GB906527A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
GB22336/60A GB906527A (en) 1960-06-25 1960-06-25 Production of alkanols
DE1961D0036293 DE1161250B (en) 1960-06-25 1961-06-09 Process for the preparation of saturated aliphatic alcohols.

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB22336/60A GB906527A (en) 1960-06-25 1960-06-25 Production of alkanols

Publications (1)

Publication Number Publication Date
GB906527A true GB906527A (en) 1962-09-26

Family

ID=10177749

Family Applications (1)

Application Number Title Priority Date Filing Date
GB22336/60A Expired GB906527A (en) 1960-06-25 1960-06-25 Production of alkanols

Country Status (2)

Country Link
DE (1) DE1161250B (en)
GB (1) GB906527A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5093534A (en) * 1990-08-09 1992-03-03 Huels Aktiengesellschaft Process for the preparation of saturated alcohols from aldehydes
CN104151138A (en) * 2014-08-13 2014-11-19 中国石油大学(华东) Process for producing alcohol type high-carbon organic solvent by using n-butanol and n-octanol residual liquid

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3542595A1 (en) * 1985-12-03 1987-06-04 Basf Ag METHOD FOR PRODUCING C (DOWN ARROW) 3 (DOWN ARROW) -C (DOWN ARROW) 2 (DOWN ARROW) (DOWN ARROW) 5 (DOWN ARROW) ALKANOLS

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE838746C (en) * 1948-10-02 1954-02-22 Farbwerke Hoechst Vormals Meis Process for the production of 2-AEthylhexanal- (1) or 2-AEthylhexanol- (1)
DE848944C (en) * 1950-07-27 1954-05-06 Hoechst Ag Process for the production of 2-AEthylhexanal- (1) or 2-AEthylhexanol- (1)
DE931827C (en) * 1952-05-01 1955-08-18 Huels Chemische Werke Ag Process for the production of saturated aldehydes and alcohols from the corresponding unsaturated aldehydes

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5093534A (en) * 1990-08-09 1992-03-03 Huels Aktiengesellschaft Process for the preparation of saturated alcohols from aldehydes
CN104151138A (en) * 2014-08-13 2014-11-19 中国石油大学(华东) Process for producing alcohol type high-carbon organic solvent by using n-butanol and n-octanol residual liquid
CN104151138B (en) * 2014-08-13 2016-08-24 中国石油大学(华东) The technique that a kind of octyl alconyl residual liquid produces alcohols high-carbon organic solvent

Also Published As

Publication number Publication date
DE1161250B (en) 1964-01-16

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