GB893005A - Thickening agent for mixtures of water and organic solvents - Google Patents
Thickening agent for mixtures of water and organic solventsInfo
- Publication number
- GB893005A GB893005A GB2699/61A GB269961A GB893005A GB 893005 A GB893005 A GB 893005A GB 2699/61 A GB2699/61 A GB 2699/61A GB 269961 A GB269961 A GB 269961A GB 893005 A GB893005 A GB 893005A
- Authority
- GB
- United Kingdom
- Prior art keywords
- water
- organic solvents
- mixtures
- persulphate
- dioxane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8158—Homopolymers or copolymers of amides or imides, e.g. (meth) acrylamide; Compositions of derivatives of such polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/06—Solidifying liquids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
- C08J3/03—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
- C08J2333/24—Homopolymers or copolymers of amides or imides
- C08J2333/26—Homopolymers or copolymers of acrylamide or methacrylamide
Landscapes
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Veterinary Medicine (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Public Health (AREA)
- Organic Chemistry (AREA)
- General Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Polymers & Plastics (AREA)
- Dispersion Chemistry (AREA)
- Dermatology (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Copolymers are made which consist of acrylamide and N-tert.-butylacrylamide in weight proportions of 3:7 to 8:2. The monomers are preferably copolymerized in aqueous solution with the addition of an organic solvent miscible with water, e.g. methanol, ethanol, isopropanol, acetone and dioxane, and a catalyst such as a persulphate, hydrogen peroxide, benzoyl, diacetyl, cumene, cyclohexanone or lauroyl peroxides, azobisisobutyronitrile, or a redox system, e.g. a mixture of a persulphate and sodium bisulphite, pyrosulphite, dithionite or formaldehyde sulphoxylate. The catalyst may be added gradually or portionwise to the reaction mixture. At the end of polymerization the copolymer may be recovered by drying or by precipitation, or, if if it is desired to obtain an aqueous solution of copolymer, the solvent may be removed from the reaction mixture by heating in vacuo. The copolymers are used for thickening mixtures of water and organic solvents which are miscible with water, e.g. C1-C3 alkanols, ethylene glycol and its monoethyl ether, acetone, dioxane glycerine and dimethyl formamide.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEH38668A DE1110422B (en) | 1960-02-16 | 1960-02-16 | Process for the production of copolymers which are soluble in water and water-containing alcohols |
Publications (1)
Publication Number | Publication Date |
---|---|
GB893005A true GB893005A (en) | 1962-04-04 |
Family
ID=7153710
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB2699/61A Expired GB893005A (en) | 1960-02-16 | 1961-01-24 | Thickening agent for mixtures of water and organic solvents |
Country Status (6)
Country | Link |
---|---|
BE (1) | BE599384A (en) |
CH (1) | CH419179A (en) |
DE (1) | DE1110422B (en) |
FR (1) | FR1280411A (en) |
GB (1) | GB893005A (en) |
NL (2) | NL120209C (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3624018A (en) * | 1970-03-06 | 1971-11-30 | Dow Chemical Co | Cementitious compositions and methods |
EP0063018A1 (en) * | 1981-04-10 | 1982-10-20 | Rohm And Haas Company | Acrylamid-copolymers suitable as thickening agent for aqueous systems and aqueous compositions containing them |
EP0107403A1 (en) * | 1982-09-30 | 1984-05-02 | Rohm And Haas Company | Acrylamide-containing emulsion copolymers, their use for thickening and compositions containing them |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1254126B (en) * | 1961-06-20 | 1967-11-16 | Henkel & Cie Gmbh | Encapsulation of liquids |
DE3049178A1 (en) * | 1980-12-24 | 1982-07-29 | Röhm GmbH, 6100 Darmstadt | "METHOD FOR THICKENING AQUEOUS SYSTEMS" |
US4520182A (en) * | 1982-12-29 | 1985-05-28 | Exxon Research & Engineering Co. | Acrylamide-alkylacrylamide copolymers |
EP0115213B1 (en) * | 1982-12-29 | 1987-08-12 | Exxon Research And Engineering Company | A process for forming acrylamide-alkyl acrylamide copolymers |
EP0115703B1 (en) * | 1982-12-29 | 1987-08-12 | Exxon Research And Engineering Company | A micellar process for the formation of acrylamide-alkyl acrylamide copolymers |
US4521580A (en) * | 1982-12-29 | 1985-06-04 | Exxon Research & Engineering Co. | Microemulsion process for producing acrylamide-alkyl acrylamide copolymers |
CA1213606A (en) * | 1982-12-29 | 1986-11-04 | Donald N. Schulz | Process for the formation of novel acrylamide acrylate copolymers |
US4528348A (en) * | 1982-12-29 | 1985-07-09 | Exxon Research & Engineering Company | Micellar process for the production of acrylamide-alkyl acrylamide copolymers |
GB9413742D0 (en) * | 1994-07-07 | 1994-08-24 | Bicc Plc | Sectional concrete piles |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE964902C (en) * | 1955-01-26 | 1957-05-29 | Basf Ag | Process for the production of water-soluble copolymers from acrylic acid and methacrylic acid amide in aqueous solution |
BE566640A (en) * | 1957-04-10 | |||
DE1068013B (en) * | 1958-08-22 | 1959-10-29 | Henkel 6. Cie. G.m.b.H., Düsseldorf -Holthausen | Process for the preparation of concentrated aqueous polyacrylamide solutions |
-
0
- NL NL260942D patent/NL260942A/xx unknown
- NL NL120209D patent/NL120209C/xx active
-
1960
- 1960-02-16 DE DEH38668A patent/DE1110422B/en active Pending
- 1960-12-13 CH CH1389860A patent/CH419179A/en unknown
-
1961
- 1961-01-23 BE BE599384A patent/BE599384A/en unknown
- 1961-01-24 GB GB2699/61A patent/GB893005A/en not_active Expired
- 1961-02-16 FR FR852911A patent/FR1280411A/en not_active Expired
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3624018A (en) * | 1970-03-06 | 1971-11-30 | Dow Chemical Co | Cementitious compositions and methods |
EP0063018A1 (en) * | 1981-04-10 | 1982-10-20 | Rohm And Haas Company | Acrylamid-copolymers suitable as thickening agent for aqueous systems and aqueous compositions containing them |
US4395524A (en) | 1981-04-10 | 1983-07-26 | Rohm And Haas Company | Acrylamide copolymer thickener for aqueous systems |
EP0107403A1 (en) * | 1982-09-30 | 1984-05-02 | Rohm And Haas Company | Acrylamide-containing emulsion copolymers, their use for thickening and compositions containing them |
Also Published As
Publication number | Publication date |
---|---|
CH419179A (en) | 1966-08-31 |
DE1110422B (en) | 1961-07-06 |
FR1280411A (en) | 1961-12-29 |
NL260942A (en) | |
NL120209C (en) | |
BE599384A (en) | 1961-05-16 |
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