GB1167524A - Copolymers of Unsaturated Surface Active Agents - Google Patents
Copolymers of Unsaturated Surface Active AgentsInfo
- Publication number
- GB1167524A GB1167524A GB4810666A GB4810666A GB1167524A GB 1167524 A GB1167524 A GB 1167524A GB 4810666 A GB4810666 A GB 4810666A GB 4810666 A GB4810666 A GB 4810666A GB 1167524 A GB1167524 A GB 1167524A
- Authority
- GB
- United Kingdom
- Prior art keywords
- mono
- polyethylene glycol
- ether
- allyl
- nonyl phenyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
- C08F290/02—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
- C08F290/06—Polymers provided for in subclass C08G
- C08F290/062—Polyethers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Paper (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
1,167,524. Copolymers. IMPERIAL CHEMICAL INDUSTRIES Ltd. 13 Oct., 1967 [26 Oct., 1966], No. 48106/66. Heading C3P. A water- or alkali-soluble or swellable copolymer is prepared by co-polymerizing an ethylenically unsaturated monomer or a mixture of two or more such monomers, which monomer or mixture is polymerizable to a polymer soluble or swellable in water or aqueous alkali, with an ethylenically unsaturated surface-active agent of general formula wherein R<SP>1</SP> is a monovalent aliphatic, cycloaliphatic, aryl aliphatic, aryl, alkylaryl or acyl radical containing more than 4 carbon atoms; R<SP>2</SP> is an alkylene radical containing not more than 5 carbon atoms, at least 10% by weight of the units -R<SP>2</SP>O- having a structure -CH 2 CH 2 O-; R<SP>3</SP> is an aliphatic organic radical containing in its structure wherein R<SP>4</SP> and R<SP>5</SP> are hydrogen, alkyl radicals or halogen atoms and may be the same or different, and n is an integer from 3 to 100. In the examples, the following monomers are copolymerized using as free radical catalysts either azobisisobutyronitrile, lauroyl peroxide or potassium persulphate:- (i) maleic anhydride, methyl vinyl ether and one of polyethylene glycol mono-allyl monononylphenyl ether, polyethylene glycol monoallyl mono-cetyl ether, polyethylene glycol mono-methaorylate mono-nonyl phenyl ether, polyethylene glycol nonylphenyl mono-vinyl ether, and polyethylene/polypropylene glycol mono-allyl mono-iso-octyl ether; (ii) maleic anhydride, vinyl acetate and polyethylene glycol mono-allyl mono-cetyl ether; (iii) maleic anhydride and polyethylene glycol mono-allyl mono-nonyl phenyl ether; (iv) maleic anhydride, styrene and polyethylene glycol mono-methacrylate mono-nonyl phenyl ether; (v) acrylic acid and polyethylene glycol mono-allyl mono-nonyl phenyl ether; (vi) acrylamide and polyethylene monomethacrylate mono-nonyl phenyl ether. These copolymers may be converted to aliphatic partial esters by reaction with a lower aliphatic alcohol or may be converted to solid salts by reaction with an alkali metal hydroxide. The copolymers are, in the examples, used to thicken (1) nonionic and anionic surface-active agents and (2) natural and synthetic rubber latexes.
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB4810666A GB1167524A (en) | 1966-10-26 | 1966-10-26 | Copolymers of Unsaturated Surface Active Agents |
NL6714411A NL6714411A (en) | 1966-10-26 | 1967-10-24 | |
BE705714D BE705714A (en) | 1966-10-26 | 1967-10-26 | |
DE19671745006 DE1745006A1 (en) | 1966-10-26 | 1967-10-26 | Interpolymers of unsaturated surfactants |
FR126028A FR1541974A (en) | 1966-10-26 | 1967-10-26 | Process for the manufacture of copolymers which are swellable or soluble in water or in alkalis |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB4810666A GB1167524A (en) | 1966-10-26 | 1966-10-26 | Copolymers of Unsaturated Surface Active Agents |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1167524A true GB1167524A (en) | 1969-10-15 |
Family
ID=10447412
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB4810666A Expired GB1167524A (en) | 1966-10-26 | 1966-10-26 | Copolymers of Unsaturated Surface Active Agents |
Country Status (4)
Country | Link |
---|---|
BE (1) | BE705714A (en) |
DE (1) | DE1745006A1 (en) |
GB (1) | GB1167524A (en) |
NL (1) | NL6714411A (en) |
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4125677A (en) * | 1976-05-03 | 1978-11-14 | Dulux Australia Ltd. | Levelling control of polar liquids |
US4323363A (en) * | 1975-09-18 | 1982-04-06 | Cassella Aktiengesellschaft | Dyeing of mixed fibers |
GB2129819A (en) * | 1982-11-06 | 1984-05-23 | Goldschmidt Ag Th | Process for the preparation of polymers with polyoxyalkylene chains bonded in side positions and their use for the preparation of polyurethanes |
US4892916A (en) * | 1984-08-15 | 1990-01-09 | Allied Colloids Limited | Polymeric thickeners and their production |
EP0363534A1 (en) * | 1987-05-01 | 1990-04-18 | Nippon Oil And Fats Company, Limited | Magnetic powder, aqueous coating material containing the same and magnetic recording medium |
EP0462183A1 (en) * | 1989-03-07 | 1991-12-27 | Dsm N.V. | Free-radical curable compositions |
US5703174A (en) * | 1995-06-21 | 1997-12-30 | W. R. Grace & Co.-Conn. | Air controlling superplasticizers |
FR2760459A1 (en) * | 1997-03-08 | 1998-09-11 | Henkel Kgaa | PROCESS FOR THE MANUFACTURE OF POLYMERS |
EP0884332A1 (en) * | 1997-06-11 | 1998-12-16 | The Nippon Synthetic Chemical Industry Co., Ltd. | Dispersing stabilizer |
US6139623A (en) * | 1997-01-21 | 2000-10-31 | W. R. Grace & Co.-Conn. | Emulsified comb polymer and defoaming agent composition and method of making same |
EP1069142A1 (en) | 1999-07-15 | 2001-01-17 | Clariant GmbH | Water soluble polymers and their use in cosmetic and pharmaceutic products |
US8062630B2 (en) | 2000-12-01 | 2011-11-22 | Clariant Produkte (Deutschland) Gmbh | Surfactant-free cosmetic, dermatological and pharmaceutical agents |
US8187581B2 (en) | 2000-12-01 | 2012-05-29 | Clariant Produkte (Deutschland) Gmbh | Surfactant-containing cosmetic, dermatological and pharmaceutical agents |
-
1966
- 1966-10-26 GB GB4810666A patent/GB1167524A/en not_active Expired
-
1967
- 1967-10-24 NL NL6714411A patent/NL6714411A/xx unknown
- 1967-10-26 DE DE19671745006 patent/DE1745006A1/en active Pending
- 1967-10-26 BE BE705714D patent/BE705714A/xx unknown
Cited By (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4323363A (en) * | 1975-09-18 | 1982-04-06 | Cassella Aktiengesellschaft | Dyeing of mixed fibers |
US4125677A (en) * | 1976-05-03 | 1978-11-14 | Dulux Australia Ltd. | Levelling control of polar liquids |
GB2129819A (en) * | 1982-11-06 | 1984-05-23 | Goldschmidt Ag Th | Process for the preparation of polymers with polyoxyalkylene chains bonded in side positions and their use for the preparation of polyurethanes |
US4892916A (en) * | 1984-08-15 | 1990-01-09 | Allied Colloids Limited | Polymeric thickeners and their production |
EP0363534A1 (en) * | 1987-05-01 | 1990-04-18 | Nippon Oil And Fats Company, Limited | Magnetic powder, aqueous coating material containing the same and magnetic recording medium |
EP0462183A1 (en) * | 1989-03-07 | 1991-12-27 | Dsm N.V. | Free-radical curable compositions |
EP0462183A4 (en) * | 1989-03-07 | 1992-02-26 | Desoto, Inc. | Free-radical curable compositions |
US5703174A (en) * | 1995-06-21 | 1997-12-30 | W. R. Grace & Co.-Conn. | Air controlling superplasticizers |
US6139623A (en) * | 1997-01-21 | 2000-10-31 | W. R. Grace & Co.-Conn. | Emulsified comb polymer and defoaming agent composition and method of making same |
FR2760459A1 (en) * | 1997-03-08 | 1998-09-11 | Henkel Kgaa | PROCESS FOR THE MANUFACTURE OF POLYMERS |
US6107426A (en) * | 1997-06-11 | 2000-08-22 | The Nippon Synthetic Chemical Industry Co., Ltd. | Dispersing stabilizer |
EP0884332A1 (en) * | 1997-06-11 | 1998-12-16 | The Nippon Synthetic Chemical Industry Co., Ltd. | Dispersing stabilizer |
EP1069142A1 (en) | 1999-07-15 | 2001-01-17 | Clariant GmbH | Water soluble polymers and their use in cosmetic and pharmaceutic products |
US6645476B1 (en) | 1999-07-15 | 2003-11-11 | Clariant Gmbh | Water-soluble polymers and their use in cosmetic and pharmaceutical compositions |
US8062630B2 (en) | 2000-12-01 | 2011-11-22 | Clariant Produkte (Deutschland) Gmbh | Surfactant-free cosmetic, dermatological and pharmaceutical agents |
US8187581B2 (en) | 2000-12-01 | 2012-05-29 | Clariant Produkte (Deutschland) Gmbh | Surfactant-containing cosmetic, dermatological and pharmaceutical agents |
Also Published As
Publication number | Publication date |
---|---|
BE705714A (en) | 1968-04-26 |
DE1745006A1 (en) | 1972-03-30 |
NL6714411A (en) | 1968-04-29 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
PLNP | Patent lapsed through nonpayment of renewal fees |