GB1041088A - Improvements in or relating to the preparation of linear peroxy-group-containing copolymers - Google Patents

Improvements in or relating to the preparation of linear peroxy-group-containing copolymers

Info

Publication number
GB1041088A
GB1041088A GB36549/64A GB3654964A GB1041088A GB 1041088 A GB1041088 A GB 1041088A GB 36549/64 A GB36549/64 A GB 36549/64A GB 3654964 A GB3654964 A GB 3654964A GB 1041088 A GB1041088 A GB 1041088A
Authority
GB
United Kingdom
Prior art keywords
radical
butylpermethacrylate
styrene
group
hydrogen atom
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB36549/64A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Noury & Van Der Lande
Original Assignee
Noury & Van Der Lande
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Noury & Van Der Lande filed Critical Noury & Van Der Lande
Publication of GB1041088A publication Critical patent/GB1041088A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/10—Esters
    • C08F222/12—Esters of phenols or saturated alcohols
    • C08F222/20—Esters containing oxygen in addition to the carboxy oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/62—Monocarboxylic acids having ten or more carbon atoms; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F22/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides or nitriles thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
    • C08F220/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Graft Or Block Polymers (AREA)

Abstract

A linear copolymer has in its main chain (a) units derived from polymerizable ethylenicallyunsaturated monomers and (b) at least one unit of the general formula <FORM:1041088/C3/1> in which R1 is a tertiary alkyl or aralkyl radical, R2 is a methyl radical or a hydrogen atom and R3 is a hydrogen atom, a substituted or unsubstituted phenyl radical or a <FORM:1041088/C3/2> or <FORM:1041088/C3/3> group wherein R4 stands for an alkyl or aralkyl radical. In the examples, the copolymer is produced by copolymerization in aqueous emulsion of methyl methacrylate with t-butylpermethacrylate or t-butylpermonobutylfumarate, of vinyl acetate with mono-t-butylpermaleate, and of vinyl chloride with t-butylpermethacrylate, and by tercopolymerization of methyl methacrylate, styrene and t-butylpermonobutylmaleate. Other a ,b -unsaturated peresters and comonomers are also specified. Emulsifying agents used are partially hydrolysed polyvinyl acetate alone or together with lauryl alcohol and glyceryl monostearate. Catalysts used are diisopropylperoxydicarbonate and acetylcyclohexyl-sulphonylperoxide. Graft polymers are prepared from the above copolymers by graft polymerization with styrene or butyl acrylate in aqueous emulsion, or with acrylonitrile in dimethylformamide solution.
GB36549/64A 1963-10-25 1964-09-07 Improvements in or relating to the preparation of linear peroxy-group-containing copolymers Expired GB1041088A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
NL299793 1963-10-25

Publications (1)

Publication Number Publication Date
GB1041088A true GB1041088A (en) 1966-09-01

Family

ID=19755166

Family Applications (1)

Application Number Title Priority Date Filing Date
GB36549/64A Expired GB1041088A (en) 1963-10-25 1964-09-07 Improvements in or relating to the preparation of linear peroxy-group-containing copolymers

Country Status (4)

Country Link
BE (1) BE654070A (en)
DE (1) DE1292858B (en)
GB (1) GB1041088A (en)
NL (1) NL299793A (en)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4045463A (en) * 1975-04-04 1977-08-30 Nippon Oil And Fats Co., Ltd. Peroxyesters of sorbic acid
US4119657A (en) 1976-06-16 1978-10-10 Nihon Oil And Fats Co., Ltd. Novel peroxycarbonate
FR2464273A1 (en) * 1979-03-13 1981-03-06 Ivanchev Sergei PROCESS FOR OBTAINING LATEX FROM COPOLYMERS OF BUTYLACRYLATE AND METHACRYLATE-1 TERTIOBUTYL-1 PEROXYETHANE
JPS56149406A (en) * 1980-04-21 1981-11-19 Mitsui Toatsu Chem Inc Production of styrene polymer
US5082912A (en) * 1989-12-14 1992-01-21 Tomei Sangyo Kabushiki Kaisha Polymer-type polymerization initiator
US5274059A (en) * 1988-12-27 1993-12-28 Nippon Oil And Fats Co., Ltd. Maleimide copolymer and process for preparing same
US5420173A (en) * 1994-03-30 1995-05-30 Sanchez; Jose Multi-component ethylenically unsaturate peroxyesters
US5475072A (en) * 1994-02-09 1995-12-12 Elf Atochem North America, Inc. Unsaturated peroxide compositions, polymeric-peroxides derived therefrom and their uses
US5910553A (en) * 1994-11-14 1999-06-08 Basf Aktiengesellschaft Preparation of rubber-modified molding materials by means of groups which are incorporated in the rubber and form free radicals on thermal decomposition
JP2012111944A (en) * 2010-11-19 2012-06-14 Ivoclar Vivadent Ag Polymerizable composition having improved penetration curing depth

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3536676A (en) * 1967-03-17 1970-10-27 Pennwalt Corp Polymers of alkylene diperoxyesters
DE4135984A1 (en) * 1991-10-31 1993-05-06 Wacker-Chemie Gmbh, 8000 Muenchen, De Graft copolymers with improved phase connection between graft base and grafted polymer phase

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4045463A (en) * 1975-04-04 1977-08-30 Nippon Oil And Fats Co., Ltd. Peroxyesters of sorbic acid
US4119657A (en) 1976-06-16 1978-10-10 Nihon Oil And Fats Co., Ltd. Novel peroxycarbonate
FR2464273A1 (en) * 1979-03-13 1981-03-06 Ivanchev Sergei PROCESS FOR OBTAINING LATEX FROM COPOLYMERS OF BUTYLACRYLATE AND METHACRYLATE-1 TERTIOBUTYL-1 PEROXYETHANE
JPS56149406A (en) * 1980-04-21 1981-11-19 Mitsui Toatsu Chem Inc Production of styrene polymer
US5274059A (en) * 1988-12-27 1993-12-28 Nippon Oil And Fats Co., Ltd. Maleimide copolymer and process for preparing same
US5134213A (en) * 1989-12-14 1992-07-28 Tomei Sangyo Kabushiki Kaisha Polymer-type polymerization initiator
US5082912A (en) * 1989-12-14 1992-01-21 Tomei Sangyo Kabushiki Kaisha Polymer-type polymerization initiator
US5475072A (en) * 1994-02-09 1995-12-12 Elf Atochem North America, Inc. Unsaturated peroxide compositions, polymeric-peroxides derived therefrom and their uses
US5489699A (en) * 1994-02-09 1996-02-06 Elfatochem North America, Inc. Unsaturated peroxide compositions, polymeric-peroxides derived therefrom and their uses
US5494988A (en) * 1994-02-09 1996-02-27 Elf Atochem North America, Inc. Unsaturated peroxide compositions, polymeric-peroxides derived therefrom and their uses
US5420173A (en) * 1994-03-30 1995-05-30 Sanchez; Jose Multi-component ethylenically unsaturate peroxyesters
US5644004A (en) * 1994-03-30 1997-07-01 Elf Atochem North America, Inc. Multi-component ethylenically unsaturated peroxyesters
US5910553A (en) * 1994-11-14 1999-06-08 Basf Aktiengesellschaft Preparation of rubber-modified molding materials by means of groups which are incorporated in the rubber and form free radicals on thermal decomposition
JP2012111944A (en) * 2010-11-19 2012-06-14 Ivoclar Vivadent Ag Polymerizable composition having improved penetration curing depth
US8557888B2 (en) 2010-11-19 2013-10-15 Ivoclar Vivadent Ag Polymerizable compositions with improved through-curing depth

Also Published As

Publication number Publication date
NL299793A (en)
DE1292858B (en) 1969-04-17
BE654070A (en) 1965-02-01

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