GB891382A - Process for the catalytic desulphurisation of hydrocarbon oils - Google Patents
Process for the catalytic desulphurisation of hydrocarbon oilsInfo
- Publication number
- GB891382A GB891382A GB41952/60A GB4195260A GB891382A GB 891382 A GB891382 A GB 891382A GB 41952/60 A GB41952/60 A GB 41952/60A GB 4195260 A GB4195260 A GB 4195260A GB 891382 A GB891382 A GB 891382A
- Authority
- GB
- United Kingdom
- Prior art keywords
- catalyst
- sulphide
- steam
- cobalt
- molybdenum
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
- C10G45/24—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing with hydrogen-generating compounds
- C10G45/26—Steam or water
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/148—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
- C10G45/14—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing with moving solid particles
- C10G45/16—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing with moving solid particles suspended in the oil, e.g. slurries
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02B—INTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
- F02B75/00—Other engines
- F02B75/02—Engines characterised by their cycles, e.g. six-stroke
- F02B2075/022—Engines characterised by their cycles, e.g. six-stroke having less than six strokes per cycle
- F02B2075/025—Engines characterised by their cycles, e.g. six-stroke having less than six strokes per cycle two
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- Water Supply & Treatment (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
Abstract
The desulphurization of hydrocarbon oils is effected by passing with steam at 350 DEG -450 DEG C. and not less than 15 atmospheres absolute over a catalyst comprising at least one sulphide of chromium, molybdenum or tungsten and at least one sulphide of iron, cobalt or nickel supported on a carrier consisting wholly or in part of alumina. The hydrocarbon oil may be a petroleum gasoline, kerosine, gas oil or residue, a coal tar crude benzene, toluene or xylene fraction or n-decane. The feed may be in liquid or vapour phase, preferably the "trickle" technique is employed. The catalyst is preferably cobalt and molybdenum sulphides, the support containing at least 90% alumina silica forming any balance. The space velocity may be 0,25-4 kg./litre of catalyst/hour and the amount of steam 0,5-500 mols. per gram atom of sulphur present. Both cyclic and acyclic sulphur compounds are decomposed.ALSO:The desulphurisation of hydrocarbon oils is effected by passing with steam at 350 DEG C-450 DEG C. and not less than 15 atmospheres absolute over a catalyst comprising at least one sulphide of chromium, molybdenum or tungsten and at least one sulphide of iron, cobalt or nickel supported on a carrier consisting wholly or in part of alumina. The hydrocarbon oil may be a petroleum gasoline, kerosine, gas oil or residue, a coal tar crude benzene, toluene or xylene fraction or n-decane. The feed may be in liquid or vapour phase, preferably the "trickle" technique is employed. The catalyst is preferably cobalt and molybdenum sulphides, the support containing at least 90% alumina silica forming any balance. The space velocity may be 0.25-4 kg./litre of catalyst/hour and the amount of steam 0.5-500 mols per gram atom of sulphur present. Both cyclic and acyclic sulphur compounds are decomposed.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL891382X | 1959-12-08 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB891382A true GB891382A (en) | 1962-03-14 |
Family
ID=19855903
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB41952/60A Expired GB891382A (en) | 1959-12-08 | 1960-12-06 | Process for the catalytic desulphurisation of hydrocarbon oils |
Country Status (6)
| Country | Link |
|---|---|
| BE (1) | BE597855A (en) |
| CA (1) | CA640733A (en) |
| DE (1) | DE1258004B (en) |
| GB (1) | GB891382A (en) |
| IT (1) | IT640941A (en) |
| NL (2) | NL246160A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2240258A1 (en) * | 1971-08-17 | 1973-03-01 | Shell Int Research | PROCESS FOR MANUFACTURING METAL SULFIDE CATALYSTS ON A POROUS CARRIER MATERIAL |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2121169A (en) * | 1937-03-26 | 1938-06-21 | Franklin E Kimball | Process of contacting hydrocarbon vapors with ammonium pentachlorodizincate |
| US2177343A (en) * | 1937-07-19 | 1939-10-24 | Standard Oil Co | Process of removing sulphur from mineral oil distillates |
| DE1005224B (en) * | 1954-11-26 | 1957-03-28 | Metallgesellschaft Ag | Process for the hydrogen refining of hydrocarbons or hydrocarbon fractions |
| DE1013025B (en) * | 1955-11-11 | 1957-08-01 | Metallgesellschaft Ag | Process for the hydrogen refining of hydrocarbons or hydrocarbon fractions |
-
0
- CA CA640733A patent/CA640733A/en not_active Expired
- BE BE597855D patent/BE597855A/xx unknown
- IT IT640941D patent/IT640941A/it unknown
- NL NL104874D patent/NL104874C/xx active
- NL NL246160D patent/NL246160A/xx unknown
-
1960
- 1960-12-06 DE DES71548A patent/DE1258004B/en active Pending
- 1960-12-06 GB GB41952/60A patent/GB891382A/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2240258A1 (en) * | 1971-08-17 | 1973-03-01 | Shell Int Research | PROCESS FOR MANUFACTURING METAL SULFIDE CATALYSTS ON A POROUS CARRIER MATERIAL |
Also Published As
| Publication number | Publication date |
|---|---|
| NL246160A (en) | |
| IT640941A (en) | |
| BE597855A (en) | |
| DE1258004B (en) | 1968-01-04 |
| CA640733A (en) | 1962-05-01 |
| NL104874C (en) |
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