GB885531A - Improvements in or relating to the production of amides - Google Patents
Improvements in or relating to the production of amidesInfo
- Publication number
- GB885531A GB885531A GB2785559A GB2785559A GB885531A GB 885531 A GB885531 A GB 885531A GB 2785559 A GB2785559 A GB 2785559A GB 2785559 A GB2785559 A GB 2785559A GB 885531 A GB885531 A GB 885531A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acid
- ketoximes
- amides
- oxime
- aldoximes
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D201/00—Preparation, separation, purification or stabilisation of unsubstituted lactams
- C07D201/02—Preparation of lactams
- C07D201/04—Preparation of lactams from or via oximes by Beckmann rearrangement
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Hydrogenated Pyridines (AREA)
- Other In-Based Heterocyclic Compounds (AREA)
Abstract
Amides are prepared by bringing an oxime in the vapour phase, in contact with an acid-reacting catalyst in the form of a liquid film. Such film may be maintained by the downward flow of a continuous stream of catalyst over an inert support. Acid-reacting catalysts are for example, polyphosphoric acid, silico-molybdic acid, molybdic acid, sodium hydrogen sulphate and Friedel-Crafts catalysts. The oxime vapour may be diluted with inert gases and may also be admixed with a polymerization inhibitor. Suitable starting materials are dialkyl ketoximes, diaryl ketoximes, alkylaryl ketoximes, alkyl aldoximes and aryl aldoximes, which yield linear amides, and cycloalkanone oximes, which yield lactams, e.g. epsilon-caprolactam.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB2785559A GB885531A (en) | 1959-08-14 | 1959-08-14 | Improvements in or relating to the production of amides |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB2785559A GB885531A (en) | 1959-08-14 | 1959-08-14 | Improvements in or relating to the production of amides |
Publications (1)
Publication Number | Publication Date |
---|---|
GB885531A true GB885531A (en) | 1961-12-28 |
Family
ID=10266414
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB2785559A Expired GB885531A (en) | 1959-08-14 | 1959-08-14 | Improvements in or relating to the production of amides |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB885531A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3418314A (en) * | 1964-02-26 | 1968-12-24 | Bayer Ag | Process for the production of lactams |
-
1959
- 1959-08-14 GB GB2785559A patent/GB885531A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3418314A (en) * | 1964-02-26 | 1968-12-24 | Bayer Ag | Process for the production of lactams |
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