GB882747A - Process of making cyclopentadienyl nickel nitrosyl compounds - Google Patents

Process of making cyclopentadienyl nickel nitrosyl compounds

Info

Publication number
GB882747A
GB882747A GB1286360A GB1286360A GB882747A GB 882747 A GB882747 A GB 882747A GB 1286360 A GB1286360 A GB 1286360A GB 1286360 A GB1286360 A GB 1286360A GB 882747 A GB882747 A GB 882747A
Authority
GB
United Kingdom
Prior art keywords
butylamine
nickel carbonyl
tri
molar ratio
nitric oxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1286360A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Inco Ltd
Mond Nickel Co Ltd
Original Assignee
Inco Ltd
Mond Nickel Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Inco Ltd, Mond Nickel Co Ltd filed Critical Inco Ltd
Publication of GB882747A publication Critical patent/GB882747A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/30—Organic compounds compounds not mentioned before (complexes)
    • C10L1/305—Organic compounds compounds not mentioned before (complexes) organo-metallic compounds (containing a metal to carbon bond)
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
    • C07F15/04—Nickel compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/30—Organic compounds compounds not mentioned before (complexes)

Abstract

Nickel carbonyl, nitric oxide and a cyclopentadiene compound of formula <FORM:0882747/IV (b)/1> where R1 to R5 each represents a hydrocarbon radical or a hydrogen atom are reacted in the presence of a base and a liquid reaction medium. The invention also comprises the compounds prepared by this process. Specified bases include ammonia, diethylamine, triethylamine, pyridine, di-n-butylamine, diethanolamine, morphine, tri-n-butylamine, n-butylamine, piperidine, ethylenediamine, triethylphosphine, tri-n-butylphosphine, sodium ethoxide, potassium isopropoxide and caesium butoxide. The partial pressure of nitric oxide should be maintained at least at 15 psi and its molar ratio to nickel carbonyl should be greater than 2 : 1. The molar ratio of cyclopentadiene compound to nickel carbonyl is greater than 1 : 1, for example from 1.1 : 1 to 2 : 1. Free oxygen must be excluded from the reaction vessel. Reaction media specified include alcohols, e.g. methanol, ethanol or iso-octanol, ethers, e.g. ethylene glycol dimethyl ether, and high-boiling esters, e.g. di-2-ethylhexyl adipate.
GB1286360A 1959-04-15 1960-04-11 Process of making cyclopentadienyl nickel nitrosyl compounds Expired GB882747A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US80642659A 1959-04-15 1959-04-15

Publications (1)

Publication Number Publication Date
GB882747A true GB882747A (en) 1961-11-22

Family

ID=25194018

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1286360A Expired GB882747A (en) 1959-04-15 1960-04-11 Process of making cyclopentadienyl nickel nitrosyl compounds

Country Status (4)

Country Link
BE (1) BE589755A (en)
CH (1) CH409955A (en)
GB (1) GB882747A (en)
NL (2) NL250518A (en)

Also Published As

Publication number Publication date
NL250518A (en)
BE589755A (en) 1960-10-14
NL106069C (en)
CH409955A (en) 1966-03-31

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