GB878585A - Improvements in or relating to the manufacture of organic fluoro-halogen compounds - Google Patents

Improvements in or relating to the manufacture of organic fluoro-halogen compounds

Info

Publication number
GB878585A
GB878585A GB2705759A GB2705759A GB878585A GB 878585 A GB878585 A GB 878585A GB 2705759 A GB2705759 A GB 2705759A GB 2705759 A GB2705759 A GB 2705759A GB 878585 A GB878585 A GB 878585A
Authority
GB
United Kingdom
Prior art keywords
chclf
clf3
olefine
reaction
relating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2705759A
Inventor
Jan Muray
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to GB2705759A priority Critical patent/GB878585A/en
Priority to FR835165A priority patent/FR1431653A/en
Publication of GB878585A publication Critical patent/GB878585A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00Preparation of halogenated hydrocarbons
    • C07C17/013Preparation of halogenated hydrocarbons by addition of halogens
    • C07C17/04Preparation of halogenated hydrocarbons by addition of halogens to unsaturated halogenated hydrocarbons

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Partially halogenated paraffins are prepared by bringing gaseous chlorine trifluoride into contact with a liquid partially halogented mono-olefine; the CIF3 acts as F2 + ClF, and these groups are added across the double bond in separate molecules of olefine. The preferred molecular proportion of ClF3 is hence approximately one half of the olefine. The ClF3 may be diluted with an inert gas such as nitrogen, at least in the early stages of the reaction. The temperature is preferably raised during the reaction. Examples react sym-dichloroethylene and trichloroethylene with ClF3 to obtain CHClF.CHCl2 and CHClF.CHClF, and CHClF.CCl2F and CHCl2CCl2F respectively.
GB2705759A 1959-08-07 1959-08-07 Improvements in or relating to the manufacture of organic fluoro-halogen compounds Expired GB878585A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
GB2705759A GB878585A (en) 1959-08-07 1959-08-07 Improvements in or relating to the manufacture of organic fluoro-halogen compounds
FR835165A FR1431653A (en) 1959-08-07 1960-08-05 Manufacture of partially halogenated paraffins

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB2705759A GB878585A (en) 1959-08-07 1959-08-07 Improvements in or relating to the manufacture of organic fluoro-halogen compounds

Publications (1)

Publication Number Publication Date
GB878585A true GB878585A (en) 1961-10-04

Family

ID=10253461

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2705759A Expired GB878585A (en) 1959-08-07 1959-08-07 Improvements in or relating to the manufacture of organic fluoro-halogen compounds

Country Status (1)

Country Link
GB (1) GB878585A (en)

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