GB878136A - Aluminium alkoxy and aryloxy hydrides, their complex salts with alkali hydrides and the production of the same - Google Patents
Aluminium alkoxy and aryloxy hydrides, their complex salts with alkali hydrides and the production of the sameInfo
- Publication number
- GB878136A GB878136A GB3613/60A GB361360A GB878136A GB 878136 A GB878136 A GB 878136A GB 3613/60 A GB3613/60 A GB 3613/60A GB 361360 A GB361360 A GB 361360A GB 878136 A GB878136 A GB 878136A
- Authority
- GB
- United Kingdom
- Prior art keywords
- aluminium
- hydrides
- aryloxy
- alkoxy
- alkali metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000004411 aluminium Substances 0.000 title abstract 7
- 229910052782 aluminium Inorganic materials 0.000 title abstract 7
- -1 aryloxy hydrides Chemical class 0.000 title abstract 4
- 150000003839 salts Chemical class 0.000 title abstract 2
- 239000003513 alkali Substances 0.000 title 1
- 150000004678 hydrides Chemical class 0.000 title 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 2
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 229910001508 alkali metal halide Inorganic materials 0.000 abstract 1
- 150000008045 alkali metal halides Chemical class 0.000 abstract 1
- 229910000102 alkali metal hydride Inorganic materials 0.000 abstract 1
- 150000008046 alkali metal hydrides Chemical class 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 150000002170 ethers Chemical class 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 239000012442 inert solvent Substances 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 150000003512 tertiary amines Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/06—Aluminium compounds
- C07F5/069—Aluminium compounds without C-aluminium linkages
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
Abstract
The invention comprises aluminium alkoxy or aluminium aryloxy hydrides or their salts with an alkali metal hydride and having the formula Al(OR)nH3-n, Me(Al(OR)nH4-n) or Al2(OR)3H3 in which R is an alkyl group, a phenyl group or an alkyl-substituted phenyl group, Me is an alkali metal and n is equal to 1 or 2. They may be produced by reacting the corresponding aluminium alkoxy or aryloxy halide with an alkali metal halide in an inert solvent. Suitable solvents are, for example, ethers, hydrocarbons or tertiary amines. The reaction may be carried out at temperatures in the range 0-130 DEG C. and at atmospheric or superatmospheric pressure. Before the reaction starts there is preferably added to the reaction mixture a small amount of an aluminium alkyl, aluminium phenyl, aluminium alkoxy or aluminium phenyloxy hydride or a small amount of the product.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE878136X | 1959-02-03 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB878136A true GB878136A (en) | 1961-09-27 |
Family
ID=6818372
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB3613/60A Expired GB878136A (en) | 1959-02-03 | 1960-02-02 | Aluminium alkoxy and aryloxy hydrides, their complex salts with alkali hydrides and the production of the same |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB878136A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3184492A (en) * | 1963-02-05 | 1965-05-18 | Hoffmann La Roche | Process for the preparation of sodium aluminum methoxy hydride |
| US3318934A (en) * | 1961-06-30 | 1967-05-09 | Ziegler Karl | Tertiary alkoxy-aluminum dialkyls and their manufacture |
| US3394158A (en) * | 1963-10-02 | 1968-07-23 | Snam Spa | Complex aluminium hydrides partly substituted with alcoxylic groups |
-
1960
- 1960-02-02 GB GB3613/60A patent/GB878136A/en not_active Expired
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3318934A (en) * | 1961-06-30 | 1967-05-09 | Ziegler Karl | Tertiary alkoxy-aluminum dialkyls and their manufacture |
| US3184492A (en) * | 1963-02-05 | 1965-05-18 | Hoffmann La Roche | Process for the preparation of sodium aluminum methoxy hydride |
| US3394158A (en) * | 1963-10-02 | 1968-07-23 | Snam Spa | Complex aluminium hydrides partly substituted with alcoxylic groups |
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