GB875775A - Zinc and cadmium selenides - Google Patents

Zinc and cadmium selenides

Info

Publication number
GB875775A
GB875775A GB35678/59A GB3567859A GB875775A GB 875775 A GB875775 A GB 875775A GB 35678/59 A GB35678/59 A GB 35678/59A GB 3567859 A GB3567859 A GB 3567859A GB 875775 A GB875775 A GB 875775A
Authority
GB
United Kingdom
Prior art keywords
selenide
zinc
heating
cadmium
hydrazinates
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB35678/59A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Merck and Co Inc
Original Assignee
Merck and Co Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Merck and Co Inc filed Critical Merck and Co Inc
Publication of GB875775A publication Critical patent/GB875775A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B19/00Selenium; Tellurium; Compounds thereof
    • C01B19/007Tellurides or selenides of metals
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00Crystal-structural characteristics
    • C01P2002/50Solid solutions
    • C01P2002/52Solid solutions containing elements as dopants

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Zinc and cadmium selenides are prepared by heating the corresponding selenide hydrazinates in an inert non-oxidizing atmosphere or reacting it with an acid. The zinc or cadmium selenide hydrazinates may be prepared from the corresponding selenites and hydrazine as described and claimed in Specification 875,773. Conversion of the selenide hydrazinate may be effected by heating in an inert atmosphere at 50-70 DEG C. but preferably the heating is effected in the presence of an acid such as hydrochloric, hydrobromic or sulphuric acids or organic carboxylic acids such as formic, acetic, propionic, butyric, valeric, or benzoic. Copper or silver activators may be added to the selenite from which the selenide hydrazinate intermediate is formed whereby they may be incorporated in the final selenide in amounts of about 0.01% mol. or less.
GB35678/59A 1956-10-05 1957-10-01 Zinc and cadmium selenides Expired GB875775A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US875775XA 1956-10-05 1956-10-05

Publications (1)

Publication Number Publication Date
GB875775A true GB875775A (en) 1961-08-23

Family

ID=22206002

Family Applications (1)

Application Number Title Priority Date Filing Date
GB35678/59A Expired GB875775A (en) 1956-10-05 1957-10-01 Zinc and cadmium selenides

Country Status (1)

Country Link
GB (1) GB875775A (en)

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