GB872756A - ª--metallo derivatives of metal carboxylates - Google Patents
ª--metallo derivatives of metal carboxylatesInfo
- Publication number
- GB872756A GB872756A GB3385057A GB3385057A GB872756A GB 872756 A GB872756 A GB 872756A GB 3385057 A GB3385057 A GB 3385057A GB 3385057 A GB3385057 A GB 3385057A GB 872756 A GB872756 A GB 872756A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acetate
- sodium
- sodio
- acid
- metallo
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910052751 metal Inorganic materials 0.000 title abstract 5
- 239000002184 metal Substances 0.000 title abstract 5
- 150000007942 carboxylates Chemical class 0.000 title abstract 3
- 239000001632 sodium acetate Substances 0.000 abstract 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 abstract 2
- 239000004215 Carbon black (E152) Substances 0.000 abstract 2
- 150000001242 acetic acid derivatives Chemical class 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 2
- 238000000354 decomposition reaction Methods 0.000 abstract 2
- MNWFXJYAOYHMED-UHFFFAOYSA-N heptanoic acid Chemical compound CCCCCCC(O)=O MNWFXJYAOYHMED-UHFFFAOYSA-N 0.000 abstract 2
- 229930195733 hydrocarbon Natural products 0.000 abstract 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 2
- 239000000376 reactant Substances 0.000 abstract 2
- 125000006273 (C1-C3) alkyl group Chemical group 0.000 abstract 1
- GYSCBCSGKXNZRH-UHFFFAOYSA-N 1-benzothiophene-2-carboxamide Chemical compound C1=CC=C2SC(C(=O)N)=CC2=C1 GYSCBCSGKXNZRH-UHFFFAOYSA-N 0.000 abstract 1
- QEAUORCZKIOKQZ-UHFFFAOYSA-N 3-(cyclohexen-1-yl)propanoic acid Chemical compound OC(=O)CCC1=CCCCC1 QEAUORCZKIOKQZ-UHFFFAOYSA-N 0.000 abstract 1
- XMIIGOLPHOKFCH-UHFFFAOYSA-N 3-phenylpropionic acid Chemical compound OC(=O)CCC1=CC=CC=C1 XMIIGOLPHOKFCH-UHFFFAOYSA-N 0.000 abstract 1
- OBKXEAXTFZPCHS-UHFFFAOYSA-N 4-phenylbutyric acid Chemical compound OC(=O)CCCC1=CC=CC=C1 OBKXEAXTFZPCHS-UHFFFAOYSA-N 0.000 abstract 1
- GHVNFZFCNZKVNT-UHFFFAOYSA-N Decanoic acid Natural products CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 abstract 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 abstract 1
- 150000001408 amides Chemical class 0.000 abstract 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Substances C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 1
- 150000001735 carboxylic acids Chemical class 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- WNEDFFOLOBIVDA-UHFFFAOYSA-L disodium oct-4-enedioate Chemical compound C(CC=CCCC(=O)[O-])C(=O)[O-].[Na+].[Na+] WNEDFFOLOBIVDA-UHFFFAOYSA-L 0.000 abstract 1
- 150000004820 halides Chemical class 0.000 abstract 1
- -1 hydrocarbon halide Chemical class 0.000 abstract 1
- 229940046892 lead acetate Drugs 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 229950009215 phenylbutanoic acid Drugs 0.000 abstract 1
- SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Substances [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 229940006198 sodium phenylacetate Drugs 0.000 abstract 1
- 229910052725 zinc Inorganic materials 0.000 abstract 1
- 239000011701 zinc Substances 0.000 abstract 1
- 239000004246 zinc acetate Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
- C07C51/353—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by isomerisation; by change of size of the carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic Table
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
The invention comprises a -metallo metallic acetates of formula <FORM:0872756/IV (b)/1> where M and M1 are metals which may be the same or different and z and y are the valencies of M and M1 respectively, and a process for preparing these and other metallo metallic carboxylates by reacting a metal carboxylate of formula <FORM:0872756/IV (b)/2> where R and R1 are the same or different and are hydrogen atoms or univalent hydrocarbon radicals, M1 is as above defined and u is the valency of M1 with a metal amide of formula <FORM:0872756/IV (b)/3> where M is as above defined, a and b are hydrogen atoms or C1-C3 alkyl groups and w is the valency of M. Reaction is preferably carried out at a temperature above 60 DEG C. and below about 250 DEG C. and below the decomposition temperature of the reactants. Among the many compounds prepared and specified are a -sodio-sodium acetate, a -sodio-sodium phenyl acetate, a -sodio-sodium vinyl acetate, a -lithio-sodium acetate, a -sodio-potassium acetate, a -sodio-zinc acetate, a -bariocerous acetate and a -zinc lead acetate. The a -metallo metallic acetates may be reacted with a hydrocarbon halide in proportions of 1 mole of acetate to 0.75 to 1.5 equivalents of halide to give metal salts of carboxylic acids which may be readily converted into the free acid. The process may be carried out between 60 DEG C. and upwards of 140 DEG C. but below the decomposition temperature of the reactants. Essentially equivalent proportions are preferred. The examples describe the preparation of Ex 12) phenyl propionic acid; 13) 3-(1-cyclohexenyl) propionic acid; 14) heptanoic acid; 15) sodium-4-phenyl butyrate; 16) decanoic acid; 17) 2,5-bis(b -carboxyethyl)-p-xylene; 18) p-phthaloyldiacetic acid; 20) sodium 3-hexene-1,6-dicarboxylate; 21) 1-pentynoic acid; 22) a -(1,4-cyclohexadine-3)-sodium acetate; and 23) 1,4-bis-(b -carboxyethyl)-benzene. Specification 872,757 is referred to.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB3385057A GB872756A (en) | 1957-10-30 | 1957-10-30 | ª--metallo derivatives of metal carboxylates |
| GB2719260A GB937239A (en) | 1957-10-30 | 1960-08-05 | Organic salts |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB3385057A GB872756A (en) | 1957-10-30 | 1957-10-30 | ª--metallo derivatives of metal carboxylates |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB872756A true GB872756A (en) | 1961-07-12 |
Family
ID=10358262
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB3385057A Expired GB872756A (en) | 1957-10-30 | 1957-10-30 | ª--metallo derivatives of metal carboxylates |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB872756A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2599737A1 (en) * | 1986-06-10 | 1987-12-11 | Sanofi Sa | Process for attaching alkyl, alkenyl, cycloalkyl or aralkyl groups to a carbon chain carrying a functional group |
-
1957
- 1957-10-30 GB GB3385057A patent/GB872756A/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2599737A1 (en) * | 1986-06-10 | 1987-12-11 | Sanofi Sa | Process for attaching alkyl, alkenyl, cycloalkyl or aralkyl groups to a carbon chain carrying a functional group |
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