GB871767A - Improvements in or relating to monoesters of 1:2-ethanediol and 1:2-propanediol - Google Patents

Improvements in or relating to monoesters of 1:2-ethanediol and 1:2-propanediol

Info

Publication number
GB871767A
GB871767A GB790859A GB790859A GB871767A GB 871767 A GB871767 A GB 871767A GB 790859 A GB790859 A GB 790859A GB 790859 A GB790859 A GB 790859A GB 871767 A GB871767 A GB 871767A
Authority
GB
United Kingdom
Prior art keywords
ethanediol
monoesters
propanediol
relating
diol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB790859A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Roehm and Haas GmbH
Original Assignee
Roehm and Haas GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Roehm and Haas GmbH filed Critical Roehm and Haas GmbH
Publication of GB871767A publication Critical patent/GB871767A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/24—Preparation of carboxylic acid esters by reacting carboxylic acids or derivatives thereof with a carbon-to-oxygen ether bond, e.g. acetal, tetrahydrofuran
    • C07C67/26—Preparation of carboxylic acid esters by reacting carboxylic acids or derivatives thereof with a carbon-to-oxygen ether bond, e.g. acetal, tetrahydrofuran with an oxirane ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
    • C07C69/12—Acetic acid esters
    • C07C69/16—Acetic acid esters of dihydroxylic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
    • C07C69/22—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen having three or more carbon atoms in the acid moiety
    • C07C69/28—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen having three or more carbon atoms in the acid moiety esterified with dihydroxylic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
    • C07C69/533—Monocarboxylic acid esters having only one carbon-to-carbon double bond
    • C07C69/54—Acrylic acid esters; Methacrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10—Esters
    • C08F20/12—Esters of monohydric alcohols or phenols
    • C08F20/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F20/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10—Esters
    • C08F20/26—Esters containing oxygen in addition to the carboxy oxygen

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Mono-esters of 1,2-ethane-diol and/or 1,2-propane-diol with acrylic and/or methacrylic acid are prepared by reacting ethylene oxide and/or propylene oxide with acrylic and/or methacrylic acid at above 30 DEG C. in the presence of ferric chloride, a ferric alcoholate or carboxylate, or chromium tribromide. A polymerization inhibitor such as hydroquinone monomethyl ether may be present. In examples the alkylene oxide is led into a mixture of acid and catalyst.
GB790859A 1958-03-06 1959-03-06 Improvements in or relating to monoesters of 1:2-ethanediol and 1:2-propanediol Expired GB871767A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DER22845A DE1144262B (en) 1958-03-06 1958-03-06 Process for the preparation of AEthane-1, 2-diol and propane-1, 2-diol monoacrylate and monomethacrylate

Publications (1)

Publication Number Publication Date
GB871767A true GB871767A (en) 1961-06-28

Family

ID=7401233

Family Applications (1)

Application Number Title Priority Date Filing Date
GB790859A Expired GB871767A (en) 1958-03-06 1959-03-06 Improvements in or relating to monoesters of 1:2-ethanediol and 1:2-propanediol

Country Status (6)

Country Link
BE (1) BE576414A (en)
CH (1) CH385814A (en)
DE (1) DE1144262B (en)
FR (1) FR1218241A (en)
GB (1) GB871767A (en)
NL (1) NL236750A (en)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1248036B (en) * 1962-12-12 1967-08-24 Basf Ag Process for the preparation of alpha, beta-unsaturated carboxylic acid esters by esterifying the carboxylic acids with alkylene oxides
US3399229A (en) * 1965-04-03 1968-08-27 Cassella Farbwerke Mainkur Ag Process for the production of hydroxyalkyl esters of the alpha, beta-unsaturated carboxylic acids
US3441599A (en) * 1966-05-09 1969-04-29 Mitsubishi Gas Chemical Co Process for preparing hydroxyalkylacrylate or hydroxyalkylmethacrylate
US3441598A (en) * 1966-01-06 1969-04-29 Jefferson Chem Co Inc Acrylate production
DE1911447A1 (en) * 1968-03-09 1970-01-02 Bp Chem Int Ltd Production of carboxylic acid esters
US4069242A (en) 1969-02-06 1978-01-17 The Dow Chemical Company Process for preparation of β-hydroxy esters by reaction of organic carboxylic acids and vicinal epoxides
US4141865A (en) 1977-10-06 1979-02-27 The Dow Chemical Company Catalysts for reaction of carboxylic acids with polyepoxides
US4271312A (en) * 1971-04-07 1981-06-02 Standard Oil Company (Indiana) Suppression of diglycol ether ester in chromium (III) catalyzed ethylene oxide reaction with aromatic carboxylic acids
US4415747A (en) * 1981-09-29 1983-11-15 Union Carbide Corporation Process for making ethylene glycol derivatives

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1287065B (en) * 1963-05-24 1969-01-16 Dow Chemical Co Process for the production of ª ‰ -hydroxyalkyl acrylates and methacrylates by esterification of acrylic acid and methacrylic acid with alkylene oxides
US3340295A (en) * 1963-12-23 1967-09-05 Celanese Corp Process of producing a monoester of an alkylene glycol moiety and a carboxylic acid
US3472775A (en) * 1968-08-14 1969-10-14 Emery Industries Inc Synthetic ester lubricant base fluid containing a polyester thickener

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE515306C (en) * 1926-01-30 1931-10-29 I G Farbenindustrie Akt Ges Process for the preparation of esters
US2484487A (en) * 1948-09-08 1949-10-11 Eastman Kodak Co Process for preparing glycol monoesters of acrylic and alpha-methacrylic acids

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1248036B (en) * 1962-12-12 1967-08-24 Basf Ag Process for the preparation of alpha, beta-unsaturated carboxylic acid esters by esterifying the carboxylic acids with alkylene oxides
US3399229A (en) * 1965-04-03 1968-08-27 Cassella Farbwerke Mainkur Ag Process for the production of hydroxyalkyl esters of the alpha, beta-unsaturated carboxylic acids
US3441598A (en) * 1966-01-06 1969-04-29 Jefferson Chem Co Inc Acrylate production
US3441599A (en) * 1966-05-09 1969-04-29 Mitsubishi Gas Chemical Co Process for preparing hydroxyalkylacrylate or hydroxyalkylmethacrylate
DE1911447A1 (en) * 1968-03-09 1970-01-02 Bp Chem Int Ltd Production of carboxylic acid esters
US4069242A (en) 1969-02-06 1978-01-17 The Dow Chemical Company Process for preparation of β-hydroxy esters by reaction of organic carboxylic acids and vicinal epoxides
US4271312A (en) * 1971-04-07 1981-06-02 Standard Oil Company (Indiana) Suppression of diglycol ether ester in chromium (III) catalyzed ethylene oxide reaction with aromatic carboxylic acids
US4141865A (en) 1977-10-06 1979-02-27 The Dow Chemical Company Catalysts for reaction of carboxylic acids with polyepoxides
US4415747A (en) * 1981-09-29 1983-11-15 Union Carbide Corporation Process for making ethylene glycol derivatives

Also Published As

Publication number Publication date
FR1218241A (en) 1960-05-09
BE576414A (en) 1959-07-01
NL236750A (en)
DE1144262B (en) 1963-02-28
CH385814A (en) 1964-12-31

Similar Documents

Publication Publication Date Title
GB871767A (en) Improvements in or relating to monoesters of 1:2-ethanediol and 1:2-propanediol
GB1244576A (en) PREPARATION OF beta-DIMETHYLAMINO ETHYL METHACRYLATE
GB1084997A (en) Carboxylic acid ester production
GB1197353A (en) Production of Molybdenum Catalysts
GB1257371A (en)
ES305302A1 (en) Procedure for preparation of fluorate acrylic compounds. (Machine-translation by Google Translate, not legally binding)
GB1204253A (en) Production of beta-hydroxypropyl methacrylate
GB1030566A (en) Improvements in and relating to dithiocarbamic ester derivatives
GB1167623A (en) Ethyl Esters of Unsaturated Monocarboxylic Acids
GB852384A (en) Process for preparing dihydroxy alkyl acrylates and methacrylates
GB1002181A (en) Fungicidal preparations
GB994091A (en) Continuous production of acrylic esters
GB1374360A (en) Transesterification of quinoxaline-2-carboxylic acid esters
ES259018A1 (en) A method of esterification (Machine-translation by Google Translate, not legally binding)
GB943195A (en) Improvements in and relating to the polymerisation of olefines and catalyst therefor
GB1004286A (en) Manufacture of carboxylic acid esters
FR2142803A1 (en) 3,4-disubstd anilides - having antiandrogenic activity
GB573575A (en) Improvements in or relating to the manufacture of ethylene oxide
GB836544A (en) Production of benzoate esters
ES302483A1 (en) Procedure for the obtaining of an insatured polyesteric resin. (Machine-translation by Google Translate, not legally binding)
CA642149A (en) Reaction of olefins with perfluoro acids
GB1132040A (en) Complex salts of alkyl phenols and alkyl phenol sulphides
GB1209193A (en) Process for making glycol esters
NL7108495A (en) 3,4-disubstd anilides - having antiandrogenic activity
IL62244A (en) Preparation of 3-bromo-4-fluorotoluene