GB868111A - Improvements in or relating to thiolcarbamates - Google Patents
Improvements in or relating to thiolcarbamatesInfo
- Publication number
- GB868111A GB868111A GB31728/58A GB3172858A GB868111A GB 868111 A GB868111 A GB 868111A GB 31728/58 A GB31728/58 A GB 31728/58A GB 3172858 A GB3172858 A GB 3172858A GB 868111 A GB868111 A GB 868111A
- Authority
- GB
- United Kingdom
- Prior art keywords
- radical
- methallyl
- compounds
- propylthiolcarbamate
- crotyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01Q—ANTENNAS, i.e. RADIO AERIALS
- H01Q1/00—Details of, or arrangements associated with, antennas
- H01Q1/12—Supports; Mounting means
- H01Q1/1235—Collapsible supports; Means for erecting a rigid antenna
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D307/52—Radicals substituted by nitrogen atoms not forming part of a nitro radical
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
The invention comprises compounds of the general formula: <FORM:0868111/IV (b)/1> wherein R1 are methallyl, methyl-mercaptomethyl, crotyl, lower chloroalkyl, 3-chloro-2-butenyl, propargyl or the radical <FORM:0868111/IV (b)/2> one of the x or y representing a halogen atom whilst the other represents a hydrogen atom and R2, R3 are each an alkyl, alkenyl cycloaliphatic, or chloroalkenyl radical or both R2 and R3 with the nitrogen atom constitute a pyrrolidino-ring or a piperidino or alkylsubstituted piperidino ring, or R2 and R3 are each an alkynyl radical when R1 is a lower chloroalkyl radical or wherein R1, R2 are each a lower alkyl, lower alkenyl, methoxyalkyl or haloalkenyl radical when R3 is a methallyl radical. The term "lower" is defined to mean a carbon atom content of from 1 to 6 inclusive. Such compounds, which are employed in phytocidal compositions (see Group VI), are obtained by reacting an appropriate alkali metal mercaptide with the appropriate carbamyl chloride; by reacting an appropriate organic chlorothiolformate with the appropriate amine (using the amine itself as acid binding agent or using caustic alkali as an acid binding agent); by using an appropriate organic chlorothiolformate with an amine hydrochloride with an acid binding agent or by reacting carbonyl sulphide with an appropriate amine and an acid binding agent and treating the product with an appropriate organic sulphate. Representative of the many products specified are methallyl N,N-diethylthiolcarbamate, -N.N-diallylthiolcarbamate, -N-2-chlorallyl-N-n propylthiolcarbamate, -1-piperidinecarbothiolate and 1-(2-methyl)-piperidinecarbothiolate, similar crotyl compounds including crotyl -1(2-methyl)-piperidinecarbothiolate and 1-pyrrolidine-carbothiolate, similar chloalkyl compounds, similar 2-bromo- and 3-bromoallyl compounds, similar 3-chloro-2-butenyl compounds, similar propargyl compounds allyl N-methallyl-N-ethylthiolcarbamate, methoxymethyl N-methallyl-N-ethylthiolcarbamate, ethyl N-methallyl-N-ethylthiolcarbamate, 2-bromoallyl N-methallyl-N-ethylcyclohexylthiolcarbamate, 2-chlorethyl N-thiolcarbamate, 2-chloroethyl N-ethyl-N-propargyl-N-n-propylthiolcarbamate. methylmercaptomethyl N-ethyl-N-cyclohexyl-thiolcarbamate, methylmercaptomethyl-N-2-chlorallyl-N-n-propylthiolcarbamate, methylmercaptomethyl 1-piperidinecarbothiolate and 1-pyrrolidinecarbothiolate. Specification 862,548 also is referred to.ALSO:A phytocidal composition of matter for combatting undesired plants contains as its essential ingredient a compound of the formula <FORM:0868111/VI/1> wherein R1 may be a methallyl, mercaptomethyl, crotyl, lower chloroalkyl, 3-chloro-2-butenyl, propargyl or the <FORM:0868111/VI/2> radical, one of x or y representing a halogen atom, whilst the other represents a hydrogen atom and R2, R3 are each an alkyl, alkenyl, cycloaliphatic or chloroalkenyl radical or both R2 and R3 together with the nitrogen atom constitute a pyrrolidino ring or a piperidino- or alkyl-substituted piperidino ring, or R2 and R3 are each an alkynyl radical when R1 is a lower chloralkyl radical or wherein R1 and R2 may each be a lower alkenyl, lower alkyl, methoxyalkyl or haloalkenyl radical when R3 is a methallyl radical, the term "lower" being defined to mean a carbon atom content of from 1 to 6 inclusive (see Group IV (b)). Representative of the large number of active substances specified are methallyl N,N - diallyl thiolcarbamate, methylmercaptomethyl N,N - diethylthiolcarbamate, crotyl N,N-diethylthiolcarbamate, methoxymethyl N-methallyl-N-ethylthiolcarbamate, 2-chloroethyl N-ethyl-N-cyclohexylthiolcarbamate, 3 - bromoally - N,N - di - n - propylthiolcarbamate, 3 - chloro - 2 - butenyl - N,N - di - n - propylthiolcarbamate and propargyl - N,N - diethylthiol - carbamate. Solvents for use in the compositions specified include, benzene, toluene, xylene, petroleum solvents, acetone, isopropanol or methanol. Emulsifying agents for use in the compositions may be anionic, cationic or non-ionic, e.g. quaternary ammonium salts, sulphonated oils and polyhydric alcohol esters and ethers, mixtures of the first or second with the third type being optionally employed. Dry carriers specified include granular vermiculite, clay granules, finely-ground clay and talc. Specification 862,548 also is referred to.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US559541A US2913327A (en) | 1956-01-17 | 1956-01-17 | Certain thiolcarbamates and use as herbicides |
Publications (1)
Publication Number | Publication Date |
---|---|
GB868111A true GB868111A (en) | 1961-05-17 |
Family
ID=24233981
Family Applications (4)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1845/57A Expired GB808753A (en) | 1956-01-17 | 1957-01-17 | Improvements in or relating to thiolcarbamates |
GB23841/57A Expired GB862548A (en) | 1956-01-17 | 1957-07-26 | Improvements in or relating to phytocidal compositions of matter |
GB31728/58A Expired GB868111A (en) | 1956-01-17 | 1958-10-03 | Improvements in or relating to thiolcarbamates |
GB30509/59A Expired GB862250A (en) | 1956-01-17 | 1959-09-07 | Improvements in or relating to thiolcarbamates |
Family Applications Before (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1845/57A Expired GB808753A (en) | 1956-01-17 | 1957-01-17 | Improvements in or relating to thiolcarbamates |
GB23841/57A Expired GB862548A (en) | 1956-01-17 | 1957-07-26 | Improvements in or relating to phytocidal compositions of matter |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB30509/59A Expired GB862250A (en) | 1956-01-17 | 1959-09-07 | Improvements in or relating to thiolcarbamates |
Country Status (8)
Country | Link |
---|---|
US (1) | US2913327A (en) |
BE (4) | BE571955A (en) |
CH (3) | CH357238A (en) |
DE (3) | DE1031571B (en) |
FR (4) | FR1171404A (en) |
GB (4) | GB808753A (en) |
MY (1) | MY6200002A (en) |
NL (3) | NL213753A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4696947A (en) * | 1980-10-21 | 1987-09-29 | Hodogaya Chemical Co., Ltd. | Nematocide |
WO1989009208A1 (en) * | 1988-03-30 | 1989-10-05 | Bio-Tox Diagnostics Kommanditbolag | Carbamic acid ester and a preparation thereof for treatment of addiction to alcohol |
Families Citing this family (79)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL232065A (en) * | 1956-01-17 | |||
US3046189A (en) * | 1957-05-18 | 1962-07-24 | Merck Ag E | Nematocidal agents |
US3037853A (en) * | 1958-04-04 | 1962-06-05 | Du Pont | Herbicidal composition and method employing a mixture of ethyl n, n-dipropylthiolcarbamate and a herbicidal s-triazine |
US3298817A (en) * | 1959-04-16 | 1967-01-17 | Tilles Harry | Method of combating weeds |
US3101263A (en) * | 1959-04-20 | 1963-08-20 | Stauffer Chemical Co | Herbicidal method |
DE1142464B (en) * | 1959-05-11 | 1963-01-17 | Monsanto Chemicals | Combat unwanted vegetation, weed killing, leaf removal, soil decontamination, fungus and nematode control |
US3318676A (en) * | 1959-07-10 | 1967-05-09 | Monsanto Co | Controlling vegetation with haloalkyl thiolcarbamates |
US3305576A (en) * | 1959-07-10 | 1967-02-21 | Monsanto Co | 3-chloropropyl diisopropylthiolcarbamate |
US3095299A (en) * | 1960-05-11 | 1963-06-25 | Du Pont | Herbicidal composition and method |
NL277794A (en) * | 1961-05-01 | |||
US3154402A (en) * | 1962-03-12 | 1964-10-27 | Exxon Research Engineering Co | Wax formulations of thiolcarbamate herbicides |
US3185720A (en) * | 1962-08-21 | 1965-05-25 | Stauffer Chemical Co | Asymmetric thiolcarbamates |
US3175897A (en) * | 1962-08-21 | 1965-03-30 | Stauffer Chemical Co | Asymmetric thiolcarbamates as herbicides |
US3839010A (en) * | 1970-05-19 | 1974-10-01 | Exxon Research Engineering Co | Thiocarbamic acid ester pesticides |
US4137070A (en) * | 1971-04-16 | 1979-01-30 | Stauffer Chemical Company | Herbicide compositions |
US4208203A (en) * | 1971-09-17 | 1980-06-17 | Gulf Research & Development Co. | Method of protecting corn from herbicides |
US4021224A (en) * | 1971-12-09 | 1977-05-03 | Stauffer Chemical Company | Herbicide compositions |
US4036628A (en) * | 1972-11-13 | 1977-07-19 | Stauffer Chemical Company | Phosphorus containing herbicide antidotes |
US3893838A (en) * | 1972-11-16 | 1975-07-08 | Stauffer Chemical Co | Halogenated esters as herbicide antidotes |
US3976469A (en) * | 1972-11-16 | 1976-08-24 | Stauffer Chemical Company | Halogenated ketones as herbicide antidotes |
US3923494A (en) * | 1973-05-24 | 1975-12-02 | Stauffer Chemical Co | Gem-bis amide herbicide antidote compositions and methods of use |
DE2329043A1 (en) * | 1973-06-07 | 1975-01-02 | Basf Ag | CARBOTHIOLATES |
US4098599A (en) * | 1975-09-12 | 1978-07-04 | Stauffer Chemical Company | Antidote compositions and method of use with herbicides |
US4056549A (en) | 1976-06-07 | 1977-11-01 | Ppg Industries, Inc. | S-3-Methoxyphenyl N-alkylthiolcarbamates and S-3-methylthiophenyl N-alkylthiolcarbamates |
US4321084A (en) * | 1977-09-23 | 1982-03-23 | Stauffer Chemical Company | Certain halogenated phenols as antidotes for thiocarbamate herbicides |
US4276078A (en) * | 1978-08-04 | 1981-06-30 | Stauffer Chemical Company | Herbicide compositions |
US4915725A (en) * | 1978-09-20 | 1990-04-10 | Ici Americas, Inc. | Herbicide compositions of extended soil life |
US5011526A (en) * | 1978-09-20 | 1991-04-30 | Ici Americas Inc. | Herbicide compositions of extended soil life |
US4222938A (en) * | 1978-09-29 | 1980-09-16 | Monsanto Company | Preparation of thiolcarbamates |
US4650516A (en) * | 1979-03-23 | 1987-03-17 | Stauffer Chemical Co. | α-halo-Ω-haloalkylamides herbicidal antidotes |
US4420322A (en) * | 1979-04-02 | 1983-12-13 | Stauffer Chemical Company | Herbicidal antidotes |
US4517012A (en) * | 1979-07-09 | 1985-05-14 | Stauffer Chemical Company | Herbicide compositions |
US4268456A (en) * | 1979-09-24 | 1981-05-19 | Ppg Industries, Inc. | Process for preparing chlorothiolformates |
ES8104796A1 (en) * | 1979-07-25 | 1981-05-16 | Hoechst Ag | Fungicidal thioglycolic acid anilides, process for their preparation and pesticides containing them. |
US4273725A (en) * | 1979-07-25 | 1981-06-16 | Ppg Industries, Inc. | Process for preparing chlorothiolformates |
US4279638A (en) * | 1979-08-13 | 1981-07-21 | Stauffer Chemical Company | 3,5-Disubstituted 1,2,4-oxadiazole herbicidal antidotes |
US4320070A (en) * | 1979-09-24 | 1982-03-16 | Ppg Industries, Inc. | Process for preparing chlorothiolformates |
US4400197A (en) * | 1979-12-26 | 1983-08-23 | Ppg Industries, Inc. | N-(Optionally substituted 1,3-dioxolan- or dioxan-2-ylmethyl)-N-alkyl, alkenyl, or alkynyl-2,2-dichloroacetamides |
US4381936A (en) * | 1980-03-31 | 1983-05-03 | Stauffer Chemical Company | Herbicide compositions of extended soil life |
US4299616A (en) * | 1980-03-31 | 1981-11-10 | Stauffer Chemical Company | Herbicide compositions of extended soil life |
US4321083A (en) * | 1980-04-21 | 1982-03-23 | Stauffer Chemical Company | N-Acyl-phenyl-thiourea herbicidal antidotes |
US4338120A (en) * | 1980-04-21 | 1982-07-06 | Stauffer Chemical Company | Halo-substituted thionoacyl ketone herbicidal antidotes |
US4380468A (en) * | 1980-10-14 | 1983-04-19 | Stauffer Chemical Company | Isonitriles as herbicide extenders |
US4495365A (en) * | 1980-11-21 | 1985-01-22 | Stauffer Chemical Co. | N-Acylsulfonamide herbicidal antidotes |
US4432909A (en) * | 1981-03-12 | 1984-02-21 | Stauffer Chemical Company | Amine oxanilic acid salts as herbicide extenders |
US4380467A (en) * | 1981-03-12 | 1983-04-19 | Stauffer Chemical Company | Amine oxanilic acid salts as herbicide extenders |
US4540429A (en) * | 1981-03-16 | 1985-09-10 | Stauffer Chemical Company | 4-Phenyl-1,2,3-thiadiazoles as herbicide extenders |
US4396419A (en) * | 1981-03-16 | 1983-08-02 | Stauffer Chemical Company | Chloroacetamido alkoxy ethane herbicide antidotes |
US4422869A (en) * | 1981-04-20 | 1983-12-27 | Stauffer Chemical Company | Halogenated allylthioisopropyl N-methylcarbamates as herbicide extenders |
US4546199A (en) * | 1981-04-20 | 1985-10-08 | Stauffer Chemical Company | Halogenated allylthioisopropyl N-methyl carbamates as herbicide extenders |
US4386955A (en) * | 1981-04-20 | 1983-06-07 | Stauffer Chemical Company | O-(Substituted phenyl) N-methylcarbamates as herbicide extenders |
US4381195A (en) * | 1981-04-20 | 1983-04-26 | Stauffer Chemical Company | N-Methylcarbamoyloxy anilides as herbicide extenders |
US4381196A (en) * | 1981-04-20 | 1983-04-26 | Stauffer Chemical Company | O-(Substituted phenyl) N-methylcarbamates as herbicide extenders |
US4378239A (en) * | 1981-04-27 | 1983-03-29 | Stauffer Chemical Company | N-Methylcarbamoyloxy benzaldehyde imine herbicide extenders |
HU184467B (en) * | 1981-07-08 | 1984-08-28 | Eszakmagyar Vegyimuevek | Herbicide composition containing the mixture of two active agents |
US4433999A (en) | 1981-07-20 | 1984-02-28 | Stauffer Chemical Company | Herbicide compositions containing soil life extenders and antidotes |
US4441916A (en) * | 1981-10-19 | 1984-04-10 | Stauffer Chemical Company | Haloalkyloxime herbicidal antidotes |
US4545805A (en) * | 1982-03-24 | 1985-10-08 | Stauffer Chemical Company | Herbicide compositions of extended soil life |
US4420323A (en) * | 1982-05-10 | 1983-12-13 | Stauffer Chemical Company | Thiophosphoryl carbamate herbicide antidotes |
US4478636A (en) * | 1982-06-01 | 1984-10-23 | Stauffer Chemical Company | Herbicidal compositions of extended soil life |
US4490166A (en) * | 1982-06-01 | 1984-12-25 | Stauffer Chemical Company | Iminophenyl N-methylcarbamates as herbicide extenders |
US4652298A (en) * | 1983-05-16 | 1987-03-24 | Stauffer Chemical Co. | Herbicide compositions of extended soil life |
US4652300A (en) * | 1983-05-16 | 1987-03-24 | Stauffer Chemical Co. | Herbicide compositions of extended soil life |
US4652296A (en) * | 1983-05-16 | 1987-03-24 | Stauffer Chemical Co. | Herbicide compositions of extended soil life |
US4652301A (en) * | 1983-05-16 | 1987-03-24 | Stauffer Chemical Co. | Herbicide compositions of extended soil life |
US4613358A (en) * | 1983-05-20 | 1986-09-23 | Stauffer Chemical Co. | Herbicide compositions of extended soil life |
US4662930A (en) * | 1983-05-20 | 1987-05-05 | Stauffer Chemical Co. | Herbicide compositions of extended soil life |
US4648894A (en) * | 1983-05-20 | 1987-03-10 | Stauffer Chemical Co. | Herbicide compositions of extended soil life |
US4652302A (en) * | 1983-05-20 | 1987-03-24 | Stauffer Chemical Co. | Herbicide compositions of extended soil life |
US4559082A (en) * | 1983-08-12 | 1985-12-17 | Stauffer Chemical Co. | Herbicide compositions of extended soil life |
US5171356A (en) * | 1984-09-19 | 1992-12-15 | Ici Americas Inc. | Herbicide compositions of extended soil life |
US5041599A (en) * | 1990-07-30 | 1991-08-20 | Phillips Petroleum Company | Catalytic synthesis of thionocarbamates from xanthates and amines |
US5527762A (en) * | 1990-12-12 | 1996-06-18 | Zeneca Limited | Antidoting herbicidal 3-isoxazolidinone compounds |
EP2052606A1 (en) | 2007-10-24 | 2009-04-29 | Bayer CropScience AG | Herbicide combination |
DE102008037620A1 (en) | 2008-08-14 | 2010-02-18 | Bayer Crop Science Ag | Herbicide combination with dimethoxytriazinyl-substituted difluoromethanesulfonylanilides |
HUE034803T2 (en) | 2010-10-15 | 2018-02-28 | Bayer Ip Gmbh | Use of als inhibitor herbicides for control of unwanted vegetation in als inhibitor herbicide tolerant beta vulgaris plants |
CA2834965C (en) | 2011-05-04 | 2019-08-20 | Bayer Intellectual Property Gmbh | Use of als inhibitor herbicides for control of unwanted vegetation in als inhibitor herbicide tolerant brassica, such as b. napus, plants |
MD4571C1 (en) | 2012-12-13 | 2019-01-31 | Bayer Cropscience Aktiengesellschaft | Use of ALS inhibitor herbicides for control of unwanted vegetation in ALS inhibitor herbicide tolerant Beta vulgaris plants |
AR127377A1 (en) | 2021-10-15 | 2024-01-17 | Kws Saat Se & Co Kgaa | BETA VULGARIS MUTANTS TOLERANT TO ALS-INHIBITING HERBICIDES |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2642451A (en) * | 1953-06-16 | Thiolurethanes and processes for | ||
US2060733A (en) * | 1934-09-04 | 1936-11-10 | Du Pont | Process of treating cellulose and derivatives thereof |
US2160880A (en) * | 1936-11-02 | 1939-06-06 | Standard Oil Co | Lubricant |
DE858352C (en) * | 1948-10-02 | 1952-12-04 | Schering Ag | Prevention of germination in root crops and the like like |
US2562011A (en) * | 1948-12-10 | 1951-07-24 | Goodrich Co B F | Herbicidal compositions and application thereof |
US2687348A (en) * | 1952-09-17 | 1954-08-24 | Monsanto Chemicals | Herbicidal compositions |
NL232065A (en) * | 1956-01-17 |
-
0
- NL NL232065D patent/NL232065A/xx unknown
- BE BE554214D patent/BE554214A/xx unknown
- BE BE559977D patent/BE559977A/xx unknown
- NL NL108235D patent/NL108235C/xx active
- BE BE582794D patent/BE582794A/xx unknown
- BE BE571955D patent/BE571955A/xx unknown
- NL NL213753D patent/NL213753A/xx unknown
-
1956
- 1956-01-17 US US559541A patent/US2913327A/en not_active Expired - Lifetime
-
1957
- 1957-01-15 FR FR1171404D patent/FR1171404A/en not_active Expired
- 1957-01-17 GB GB1845/57A patent/GB808753A/en not_active Expired
- 1957-01-17 DE DEST1239A patent/DE1031571B/en active Pending
- 1957-07-26 GB GB23841/57A patent/GB862548A/en not_active Expired
- 1957-07-31 CH CH357238D patent/CH357238A/en unknown
- 1957-08-06 DE DEST12853A patent/DE1081715B/en active Pending
- 1957-08-07 FR FR72159D patent/FR72159E/en not_active Expired
-
1958
- 1958-10-03 GB GB31728/58A patent/GB868111A/en not_active Expired
- 1958-10-10 DE DEST14328A patent/DE1082452B/en active Pending
- 1958-10-23 FR FR777391A patent/FR74319E/en not_active Expired
- 1958-11-24 CH CH6652558A patent/CH371921A/en unknown
-
1959
- 1959-09-07 GB GB30509/59A patent/GB862250A/en not_active Expired
- 1959-09-25 FR FR806064A patent/FR77056E/en not_active Expired
- 1959-11-10 CH CH8043159A patent/CH368015A/en unknown
-
1962
- 1962-12-31 MY MY19622A patent/MY6200002A/en unknown
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4696947A (en) * | 1980-10-21 | 1987-09-29 | Hodogaya Chemical Co., Ltd. | Nematocide |
WO1989009208A1 (en) * | 1988-03-30 | 1989-10-05 | Bio-Tox Diagnostics Kommanditbolag | Carbamic acid ester and a preparation thereof for treatment of addiction to alcohol |
US5100916A (en) * | 1988-03-30 | 1992-03-31 | Bio-Tox Diagnostics Kommanditbolag | Carbamic acid ester for treatment of addiction to alcohol |
Also Published As
Publication number | Publication date |
---|---|
BE582794A (en) | |
MY6200002A (en) | 1962-12-31 |
GB808753A (en) | 1959-02-11 |
DE1031571B (en) | 1958-06-04 |
FR1171404A (en) | 1959-01-26 |
NL213753A (en) | |
NL108235C (en) | |
CH371921A (en) | 1963-09-15 |
BE559977A (en) | |
FR77056E (en) | 1962-01-12 |
GB862548A (en) | 1961-03-15 |
CH368015A (en) | 1963-03-15 |
BE554214A (en) | |
DE1082452B (en) | 1960-05-25 |
DE1081715B (en) | 1960-05-12 |
US2913327A (en) | 1959-11-17 |
FR74319E (en) | 1960-11-07 |
GB862250A (en) | 1961-03-08 |
NL232065A (en) | |
BE571955A (en) | |
CH357238A (en) | 1961-09-30 |
FR72159E (en) | 1960-03-30 |
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