GB867390A - Improved blends of synthetic polybutadiene and natural rubber - Google Patents

Improved blends of synthetic polybutadiene and natural rubber

Info

Publication number
GB867390A
GB867390A GB3790258A GB3790258A GB867390A GB 867390 A GB867390 A GB 867390A GB 3790258 A GB3790258 A GB 3790258A GB 3790258 A GB3790258 A GB 3790258A GB 867390 A GB867390 A GB 867390A
Authority
GB
United Kingdom
Prior art keywords
polybutadiene
natural rubber
sulphur
cyclohexyl
blend
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3790258A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Phillips Petroleum Co
Original Assignee
Phillips Petroleum Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Phillips Petroleum Co filed Critical Phillips Petroleum Co
Publication of GB867390A publication Critical patent/GB867390A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L7/00Compositions of natural rubber
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L21/00Compositions of unspecified rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00Compositions of homopolymers or copolymers of conjugated diene hydrocarbons

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

A blend of synthetic polybutadiene and natural rubber or a copolymer of butadiene and styrene, which when vulcanized has good hysteresis properties, low heat build-up, good flex life and high tensile strength, comprises at least 10 parts, per 100 parts of the blend, of natural rubber or the said copolymer, the remainder being a polybutadiene containing at least 75% cis-1, 4-butadiene addition. The blend may have Mooney ML-4 viscosity (explained in the Specification) of 10-130 at 212 DEG F. Formulations vulcanized according to Example I are of the polybutadiene, smoke sheet, HAF black, zinc oxide, stearic acid, an antioxidant containing a diarylamineketone reaction product and N, N1-diphenyl -p-phenylenediamine, disproportionated rosin, pine tar, sulphur and n-cyclohexyl-2-benzothiazole sulphenamide. Formulations vulcanized according to Example II are of the polybutadiene, smoked sheet, HAF black, zinc oxide, stearic acid, the same antioxidant as for Example I, disproportionated rosin, sulphur, n-cyclohexyl-2-benzothiazole sulphenamide and an aromatic petroleum oil plasticizer. Formulations vulcanized according to Example V are of the polybutadiene, natural rubber, SBR, HAF black, zinc oxide, stearic acid, an antioxidant, disproportionated rosin, a highly aromatic petroleum oil, sulphur, N-oxydiethylene-2-benzothiazylsulphenamide and N-cyclohexyl-2-benzothiazylsulphenamide.
GB3790258A 1957-11-27 1958-11-25 Improved blends of synthetic polybutadiene and natural rubber Expired GB867390A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US69918757A 1957-11-27 1957-11-27
US75115058A 1958-07-28 1958-07-28

Publications (1)

Publication Number Publication Date
GB867390A true GB867390A (en) 1961-05-10

Family

ID=40901812

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3790258A Expired GB867390A (en) 1957-11-27 1958-11-25 Improved blends of synthetic polybutadiene and natural rubber

Country Status (4)

Country Link
BE (1) BE698519A (en)
DE (1) DE1292843B (en)
FR (1) FR1223348A (en)
GB (1) GB867390A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3516977A (en) * 1967-05-15 1970-06-23 Gen Tire & Rubber Co Processability of elastomers having a narrow molecular weight distribution

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2128197C1 (en) * 1991-11-05 1999-03-27 Феникс АГ Natural rubber mix for making rubber products

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3516977A (en) * 1967-05-15 1970-06-23 Gen Tire & Rubber Co Processability of elastomers having a narrow molecular weight distribution

Also Published As

Publication number Publication date
DE1292843B (en) 1959-04-17
FR1223348A (en) 1960-06-16
BE698519A (en) 1967-11-03

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