GB861962A - New polyesters and their method of preparation - Google Patents

New polyesters and their method of preparation

Info

Publication number
GB861962A
GB861962A GB25867/57A GB2586757A GB861962A GB 861962 A GB861962 A GB 861962A GB 25867/57 A GB25867/57 A GB 25867/57A GB 2586757 A GB2586757 A GB 2586757A GB 861962 A GB861962 A GB 861962A
Authority
GB
United Kingdom
Prior art keywords
formula
mol
carbon atoms
integer
alcohol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB25867/57A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BP PLC
Original Assignee
BP PLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to BE570400D priority Critical patent/BE570400A/xx
Application filed by BP PLC filed Critical BP PLC
Priority to GB25867/57A priority patent/GB861962A/en
Priority to FR1211544D priority patent/FR1211544A/en
Priority to CH6298658A priority patent/CH384560A/en
Publication of GB861962A publication Critical patent/GB861962A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M3/00—Liquid compositions essentially based on lubricating components other than mineral lubricating oils or fatty oils and their use as lubricants; Use as lubricants of single liquid substances
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/34—Esters of acyclic saturated polycarboxylic acids having an esterified carboxyl group bound to an acyclic carbon atom
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/282—Esters of (cyclo)aliphatic oolycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/30—Complex esters, i.e. compounds containing at leasst three esterified carboxyl groups and derived from the combination of at least three different types of the following five types of compounds: monohydroxyl compounds, polyhydroxy xompounds, monocarboxylic acids, polycarboxylic acids or hydroxy carboxylic acids
    • C10M2207/304—Complex esters, i.e. compounds containing at leasst three esterified carboxyl groups and derived from the combination of at least three different types of the following five types of compounds: monohydroxyl compounds, polyhydroxy xompounds, monocarboxylic acids, polycarboxylic acids or hydroxy carboxylic acids derived from the combination of monohydroxy compounds, dihydroxy compounds and dicarboxylic acids only and having no free hydroxy or carboxyl groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/34—Esters having a hydrocarbon substituent of thirty or more carbon atoms, e.g. substituted succinic acid derivatives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/11—Complex polyesters
    • C10M2209/112—Complex polyesters having dihydric acid centres
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/08—Resistance to extreme temperature
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/12—Gas-turbines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/12—Gas-turbines
    • C10N2040/13—Aircraft turbines

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Lubricants (AREA)

Abstract

New monohydric alcohol terminated polyesters, useful in synthetic lubricant blends (see Specification 861,964) are the reaction products of (1) one or more dicarboxylic acids of formula HOOC-R1-COOH, where R1 is an alkylene group of 4-14 carbon atoms, or anhydrides thereof; (2) one or more diols of formula <FORM:0861962/IV (a)/1> where x is 0 or an integer, y is an integer, x+y does not exceed 5, R6 is a methyl or ethyl group and R7 is an alkyl group of 1-4 carbon atoms (see Specification 861,961), and (3) one or more monohydric alcohols of formula ROH, where R is an alkyl group of 4-18 carbon atoms. Specified dicarboxylic acids are sebacic, adipic, pimelic, suberic, azelaic and brassylic acids. Specified monohydric alcohol are 2-ethylhexyl-, 2-ethylbutyl-, cetyl-, neopentyl-, trimethyl-hexyl- and trimethylnonyl alcohol. In an example a polyester is made by reacting a mixture of (1) 0.5 mol. sebacic acid, (2) 0.5 mol. of the reaction product of 4 mols. of neopentyl glycol and 7 mols. of ethylene oxide and (3) 0.05 mol. of 2-ethylhexyl alcohol. Specification 824,249 also is referred to.ALSO:New polyesters, useful in synthetic lubricant blends (see Specification 861,964), have the formula ROOCR1COO(R2OOCR1COO)nR where n is an integer, the R's are alkyl groups of 4-18 carbon atoms, the R1's are alkylene groups of 4-14 carbon atoms and the R2's are oxygenated hydrocarbon radicals of the formula <FORM:0861962/IV (b)/1> where x is 0 or an integer, y is an integer, x+y does not exceed 5, R6 is a methyl or ethyl group and R7 is an alkyl group having 1-4 carbon atoms. The polyesters are made by reacting in one or more stages (1) one or more dicarboxylic acids of formula HOOCR1COOH or anhydrides thereof (e.g. sebacic, adipic, pimelic, suberic, azelaic or brassylic acid); (2) one or more diols of formula <FORM:0861962/IV (b)/2> (see Specification 861,961), especially wherein x+y=1-2; and (3) one or more monohydric alcohols of formula ROH (e.g. 2-ethyl hexyl-, 2-ethylbutyl-, cetyl-, neopentyl-, trimethylhexyl- or trimethylnonyl alcohol). In an example a polyester is made by reacting a mixture of (1) 0.5 mol. of sebacic acid, (2) 0.5 mol. of the reaction product of 4 mols. of neopentyl glycol and 7 mols. of ethylene oxide and (3) 0.05 mol. of 2-ethyl hexyl alcohol. Specification 824,249 also is referred to.
GB25867/57A 1957-08-16 1957-08-16 New polyesters and their method of preparation Expired GB861962A (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
BE570400D BE570400A (en) 1957-08-16
GB25867/57A GB861962A (en) 1957-08-16 1957-08-16 New polyesters and their method of preparation
FR1211544D FR1211544A (en) 1957-08-16 1958-08-14 Polyesters and their manufacturing process
CH6298658A CH384560A (en) 1957-08-16 1958-08-15 Process for making a polyester

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB25867/57A GB861962A (en) 1957-08-16 1957-08-16 New polyesters and their method of preparation

Publications (1)

Publication Number Publication Date
GB861962A true GB861962A (en) 1961-03-01

Family

ID=10234661

Family Applications (1)

Application Number Title Priority Date Filing Date
GB25867/57A Expired GB861962A (en) 1957-08-16 1957-08-16 New polyesters and their method of preparation

Country Status (4)

Country Link
BE (1) BE570400A (en)
CH (1) CH384560A (en)
FR (1) FR1211544A (en)
GB (1) GB861962A (en)

Also Published As

Publication number Publication date
CH384560A (en) 1964-11-30
BE570400A (en)
FR1211544A (en) 1960-03-16

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