GB861373A - Process for partially oxidising organic compounds - Google Patents
Process for partially oxidising organic compoundsInfo
- Publication number
- GB861373A GB861373A GB12775/59A GB1277559A GB861373A GB 861373 A GB861373 A GB 861373A GB 12775/59 A GB12775/59 A GB 12775/59A GB 1277559 A GB1277559 A GB 1277559A GB 861373 A GB861373 A GB 861373A
- Authority
- GB
- United Kingdom
- Prior art keywords
- oxygen
- compounds
- produced
- partial oxidation
- olefinic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B35/00—Reactions without formation or introduction of functional groups containing hetero atoms, involving a change in the type of bonding between two carbon atoms already directly linked
- C07B35/04—Dehydrogenation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C47/00—Compounds having —CHO groups
Abstract
Oxygenated organic compounds and products comprising such compounds are produced by partially oxidizing an organic compound having at least one carbon to carbon linkage in vapour phase at temperatures of 300 DEG to 900 DEG F. and pressures of from 0-300 p.s.i.g. in the absence of a catalyst, with an oxygen-containing gas in the presence of from 0.05 to 8 volume per cent ozone based on oxygen. The oxygen may range from 0.05 to 2 mols. of 02 per mol. of feed, and may be employed as pure oxygen, air or diluted with nitrogen. The feedstocks include aliphatic, or cycloaliphatic saturated hydrocarbons, aromatic hydrocarbons, alkylated aromatic hydrocarbons, olefinic and cyclo-olefinic compounds, or acetylenes and may contain various radicals having little effect on the reactivity of the compound, e.g. carboxy, hydroxy, keto, nitrile, nitroso, halogen and inorganic radicals such as sulphate, sulphonate, phosphonate and phosphate. The major products of the partial oxidation are cyclic ethers, but with certain feedstocks olefines are produced, e.g. styrene from ethylbenzene, and small amounts of carbonyls and ketones are also formed. Examples describe the partial oxidation of n-hexane, n-hexene-1 and chloropentane.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US861373XA | 1958-07-30 | 1958-07-30 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB861373A true GB861373A (en) | 1961-02-22 |
Family
ID=22196515
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB12775/59A Expired GB861373A (en) | 1958-07-30 | 1959-04-15 | Process for partially oxidising organic compounds |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB861373A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5117011A (en) * | 1991-08-07 | 1992-05-26 | Olin Corporation | Non-catalytic oxidation of propylene to propylene oxide |
-
1959
- 1959-04-15 GB GB12775/59A patent/GB861373A/en not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5117011A (en) * | 1991-08-07 | 1992-05-26 | Olin Corporation | Non-catalytic oxidation of propylene to propylene oxide |
| WO1993003023A1 (en) * | 1991-08-07 | 1993-02-18 | Olin Corporation | Non-catalytic oxidation of propylene to propylene oxide |
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