GB849526A - Improvements relating to the treatment of ferrous strip - Google Patents

Improvements relating to the treatment of ferrous strip

Info

Publication number
GB849526A
GB849526A GB2879/57A GB287957A GB849526A GB 849526 A GB849526 A GB 849526A GB 2879/57 A GB2879/57 A GB 2879/57A GB 287957 A GB287957 A GB 287957A GB 849526 A GB849526 A GB 849526A
Authority
GB
United Kingdom
Prior art keywords
strip
tetrasodium pyrophosphate
phosphate
titanium
treatment
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2879/57A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Pyrene Co Ltd
Original Assignee
Pyrene Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Pyrene Co Ltd filed Critical Pyrene Co Ltd
Publication of GB849526A publication Critical patent/GB849526A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
    • C23C22/08—Orthophosphates
    • C23C22/22—Orthophosphates containing alkaline earth metal cations
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21B—ROLLING OF METAL
    • B21B1/00—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
    • B21B1/22—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
    • C23C22/08—Orthophosphates
    • C23C22/12—Orthophosphates containing zinc cations

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Chemical Treatment Of Metals (AREA)

Abstract

Ferrous strip is phosphated by treatment with an aqueous acidic zinc phosphate solution containing, by weight 0.05-1.5% zinc 0.12-7.5% calcium, 0.4-2.5% phosphate (as PO4), and an oxidizing agent other than chlorate in an amount sufficient to produce a uniform coating weighing at least 50 mg/sq. foot in not more than 10 seconds, and is then cold rolled. The process is applied to pickled hot-rolled strip. Suitable oxidizing agents are nitrates, nitrites, sulphites, hypochlorites, iodates, periodates, bromates, hydrogen peroxide, t-butyl hydroperoxide, quinones, and organic nitro-compounds such as picric acid, nitroguanidine, nitromethane, nitrourethane, nitraniline, nitrophenol, m - nitrobenzene sulphonate and dinitrobenzene sulphonate. The coatings may be rinsed with a dilute aqueous solution of chromic acid, borax, sodium nitrite or soda ash. The strip is preferably activated after pickling and prior to coating by treating it with an aqueous solution of oxalic acid; tetrasodium pyrophosphate; a mixture of tetrasodium pyrophosphate and a metaphosphate; a dialkyl metal phosphate containing lead, tin or arsenic; or tetrasodium pyrophosphate and/or disodium phosphate containing titanium or zirconium: suitable titanium compounds are the chloride, hydroxide, nitride and titanium potassium oxalate.
GB2879/57A 1956-01-25 1957-01-25 Improvements relating to the treatment of ferrous strip Expired GB849526A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US1171459XA 1956-01-25 1956-01-25
US1121902XA 1956-01-25 1956-01-25
US561354A US2884351A (en) 1956-01-25 1956-01-25 Method of cold rolling ferrous strip stock

Publications (1)

Publication Number Publication Date
GB849526A true GB849526A (en) 1960-09-28

Family

ID=61026478

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2879/57A Expired GB849526A (en) 1956-01-25 1957-01-25 Improvements relating to the treatment of ferrous strip

Country Status (5)

Country Link
US (1) US2884351A (en)
BE (1) BE554334A (en)
DE (1) DE1121902B (en)
FR (1) FR1171459A (en)
GB (1) GB849526A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2137231A (en) * 1983-03-31 1984-10-03 Pyrene Chemical Services Ltd Phosphate coating processes
GB2155960A (en) * 1984-03-09 1985-10-02 Pyrene Chemical Services Ltd Processes and compositions for coating metal surfaces
WO2001014613A2 (en) * 1999-08-20 2001-03-01 Henkel Kommanditgesellschaft Auf Aktien Accelerator for phosphating metal surfaces

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3152018A (en) * 1961-11-01 1964-10-06 Wyandotte Chemicals Corp Room temperature phosphate coating composition
US3104177A (en) * 1961-12-12 1963-09-17 Lubrizol Corp Phosphating process
DE1234479B (en) * 1962-02-03 1967-02-16 Metallgesellschaft Ag Process for the aftertreatment of electrically insulating inorganic cover layers
US3144360A (en) * 1962-02-19 1964-08-11 Lubrizol Corp Phosphating process
US3355330A (en) * 1964-03-03 1967-11-28 Hooker Chemical Corp Metal treating processes
US3533859A (en) * 1966-06-18 1970-10-13 Hooker Chemical Corp Coating process for ferrous metal surfaces
JPS4930340B1 (en) * 1970-12-26 1974-08-12
US3939014A (en) * 1974-11-20 1976-02-17 Amchem Products, Inc. Aqueous zinc phosphating solution and method of rapid coating of steel for deforming
JPS6020463B2 (en) * 1982-06-04 1985-05-22 日本パ−カライジング株式会社 Cold working lubrication treatment method for steel materials
ES8606528A1 (en) * 1985-02-22 1986-04-01 Henkel Iberica Process for the phosphating of metal surfaces.
US5653790A (en) * 1994-11-23 1997-08-05 Ppg Industries, Inc. Zinc phosphate tungsten-containing coating compositions using accelerators
US5588989A (en) * 1994-11-23 1996-12-31 Ppg Industries, Inc. Zinc phosphate coating compositions containing oxime accelerators
US5797987A (en) * 1995-12-14 1998-08-25 Ppg Industries, Inc. Zinc phosphate conversion coating compositions and process
CA2467751A1 (en) * 2001-12-13 2003-07-03 Henkel Kommanditgesellschaft Auf Aktien Use of substituted hydroxylamines in metal phosphating processes

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1279101A (en) * 1918-04-30 1918-09-17 James H Gravell Method of preparing pickled iron and steel for painting.
US2105015A (en) * 1934-06-09 1938-01-11 Tubus A G Mechanically working metal article
US2230319A (en) * 1934-12-04 1941-02-04 Firm Eisen Und Huttenwerke A G Process of producing iron sheets for laminated electric transformer cores
BE434557A (en) * 1938-05-27
US2314887A (en) * 1940-03-30 1943-03-30 Parker Rust Proof Co Method of coating metal and material
DE747085C (en) * 1940-06-19 1944-09-06 Ig Farbenindustrie Ag Process for the production of phosphate layers on metals
US2298312A (en) * 1940-08-03 1942-10-13 American Chem Paint Co Method of phosphate coating ferrous metal surfaces
US2293716A (en) * 1941-02-03 1942-08-25 Parker Rust Proof Co Metal treating solution
DE752142C (en) * 1941-02-25 1950-10-03 Metallgesellschaft Ag Phosphate anti-rust process
DE741937C (en) * 1941-03-11 1943-11-20 Metallgesellschaft Ag Process for the production of phosphate coatings on metals
US2351605A (en) * 1942-03-02 1944-06-20 Parker Rust Proof Co Metal treatment
NL62521C (en) * 1943-07-29
US2479564A (en) * 1945-09-14 1949-08-23 Lloyd O Gilbert Phosphate coating of metallic articles
US2476345A (en) * 1946-09-03 1949-07-19 Zavarella Arthur Process for phosphating stainless steel surfaces
US2540314A (en) * 1947-07-24 1951-02-06 Parker Rust Proof Co Process and compositions for applying phosphate coatings
US2522176A (en) * 1947-10-14 1950-09-12 Parker Rust Proof Co Drawing ferrous wire and other metal-working processes
US2516008A (en) * 1948-06-19 1950-07-18 Westinghouse Electric Corp Composition and process for treating metal surfaces
US2608496A (en) * 1950-04-01 1952-08-26 J N Tuttle Inc Composition for producing protective coatings

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2137231A (en) * 1983-03-31 1984-10-03 Pyrene Chemical Services Ltd Phosphate coating processes
GB2155960A (en) * 1984-03-09 1985-10-02 Pyrene Chemical Services Ltd Processes and compositions for coating metal surfaces
WO2001014613A2 (en) * 1999-08-20 2001-03-01 Henkel Kommanditgesellschaft Auf Aktien Accelerator for phosphating metal surfaces
WO2001014613A3 (en) * 1999-08-20 2001-12-13 Henkel Kgaa Accelerator for phosphating metal surfaces

Also Published As

Publication number Publication date
BE554334A (en) 1957-02-15
US2884351A (en) 1959-04-28
FR1171459A (en) 1959-01-27
DE1121902B (en) 1962-01-11

Similar Documents

Publication Publication Date Title
GB849526A (en) Improvements relating to the treatment of ferrous strip
US2077450A (en) Method and composition for coating iron and steel articles
GB655070A (en) Improvements in or relating to the coating of metals with phosphates
SE8205333L (en) Aqueous, acidic zinc phosphate transfer solutions, low temperature procedures using them to form chemical and chemical transfers of iron and / or stalytes and the metal concentrate in concentrate.
DE3166602D1 (en) Method for the production of phosphate coatings on iron and steel surfaces, and its use
US2758949A (en) Alkali metal phosphate coating solutions and the method of forming coatings therewith
DE3566683D1 (en) Process for the zinc-calcium phosphatizing of metal surfaces at a low treating temperature
JPH0331790B2 (en)
GB1591039A (en) Processes and compositions for coating metal surfaces
GB1376669A (en) Lubricant compositions for application to metal surfaces and processes for applying such compositions to metal surfaces
GB2169620A (en) Phosphate coatings
GB828916A (en) Improvements in and relating to the formation of phosphate coatings
GB1355739A (en) Processes and compositions for forming phosphate coatings
US3338755A (en) Production of phosphate coatings on metals
US3181976A (en) Phosphating process and composition
GB2137231A (en) Phosphate coating processes
US3333988A (en) Phosphate coating process
US2302510A (en) Material and method for cleaning and coating metal
US2314887A (en) Method of coating metal and material
GB943169A (en) Improvements relating to the phosphate-coating of metals
GB755559A (en) Improvements in the formation of vitreous enamel coatings on metallic surfaces
US3479293A (en) Process and composition for etching ferrous metal surfaces
GB944419A (en) Process for applying firmly adhering phosphate coatings to metal surfaces in the presence of aluminium
GB812095A (en) Improvements relating to the formation of phosphate coatings
GB932987A (en) Improvements relating to the phosphate-coating of metals