GB834411A - Quaternary ammonium compounds - Google Patents
Quaternary ammonium compoundsInfo
- Publication number
- GB834411A GB834411A GB35388/57A GB3538857A GB834411A GB 834411 A GB834411 A GB 834411A GB 35388/57 A GB35388/57 A GB 35388/57A GB 3538857 A GB3538857 A GB 3538857A GB 834411 A GB834411 A GB 834411A
- Authority
- GB
- United Kingdom
- Prior art keywords
- ethyleneurea
- prepared
- formula
- reacting
- chloroacetamido
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
- C07D233/04—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
- C07D233/28—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D233/30—Oxygen or sulfur atoms
- C07D233/32—One oxygen atom
- C07D233/36—One oxygen atom with hydrocarbon radicals, substituted by nitrogen atoms, attached to ring nitrogen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C275/00—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups
- C07C275/46—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups containing any of the groups, X being a hetero atom, Y being any atom, e.g. acylureas
- C07C275/48—Y being a hydrogen or a carbon atom
- C07C275/50—Y being a hydrogen or an acyclic carbon atom
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
The invention comprises compounds of the formula <FORM:0834411/IV (b)/1> where R is hydrogen or methyl; Y is O, -CONR, or -COO-; A is a straight or branched chain C2-10 alkylene group optionally substituted with hydroxy groups and in which at least two of the carbon atoms are connected in a chain between the N-atom and the group Y; R1 and R2 are either (1) separate groups which are saturated C1-4 hydrocarbon groups which may be ethylenically unsaturated or (2) a single group which is the morpholine residue = (C2H4)2O, the pyrrolidino residue -C4H8-, the piperidino residue -C5H10-or an N-alkyl piperazino residue =(C2H4)2:NR4 where R4 is a C1-18 alkyl group; X is halogen (especially chlorine); and R3 is a radical represented by the formula -CH2CONHCONHR0, or the formula <FORM:0834411/IV (b)/2> wherein R0 is H, -CH2OH, or -CH2IR5\t where R5 is a C1-4 alkyl group, p is an integer of 1 or 2, n is an integer of 1 or 2 when p is 2, but only 1 when p is 1, and Z is -CO- or -CH2- when p is 1, but is only -CH2-when p is 2. The compounds are prepared by quaterizing an amine of the formula CH2=C(R)YANR1R2 with a quaternizing agent of the formula R3X. Alkoxymethylol and methylol derivatives of a - chloroacetylurea, N - (a - chloroacetyl)-N : N1 - ethyleneurea, N - (b - chloroethyl)-N : N1 - ethyleneurea, N - [b - (a - chloroacetamido)ethyl] - N : N1 - ethyleneurea and N - [3 - (a - chloroacetamido)propyl] - N : N1 - trimethyleneurea are obtained by reacting the appropriate urea with formaldehyde in the presence or absence of a C1-4 alcohol, respectively. N - (a - chloroacetyl) - N : N1 - ethyleneurea is prepared by reacting N : N1-ethyleneurea with a -chloroacetyl chloride. N - (b - chloroethyl) - N : N1 - ethyleneurea is prepared by reacting N - (b - hydroxyethyl)-N : N1-ethyleneurea with thionyl chloride. N - [b - (a - chloroacetamido)ethyl] - N : N1-ethyleneurea is prepared by reacting methyl a -chloroacetate with N-(b -aminoethyl)-N : N1-ethyleneurea. N - [3 - (a - chloroacetamido)propyl] - N : N1-trimethyleneurea is prepared by reacting methyl a -chloroacetate with N-(3-aminopropyl)-N : N1-trimethyleneurea. Specification 777,488 is referred to.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US834411XA | 1955-03-21 | 1955-03-21 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB834411A true GB834411A (en) | 1960-05-11 |
Family
ID=22178352
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB35388/57A Expired GB834411A (en) | 1955-03-21 | 1956-03-13 | Quaternary ammonium compounds |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB834411A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5399706A (en) * | 1993-03-02 | 1995-03-21 | H. B. Fuller Licensing & Financing, Inc. | Imidazolidinone diamine and derivatives thereof |
-
1956
- 1956-03-13 GB GB35388/57A patent/GB834411A/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5399706A (en) * | 1993-03-02 | 1995-03-21 | H. B. Fuller Licensing & Financing, Inc. | Imidazolidinone diamine and derivatives thereof |
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