GB820146A - Method of preparing alkyls or alkyl chlorides of the elements boron, mercury, gallium, germanium, arsenic, antimony and bismuth - Google Patents
Method of preparing alkyls or alkyl chlorides of the elements boron, mercury, gallium, germanium, arsenic, antimony and bismuthInfo
- Publication number
- GB820146A GB820146A GB31485/57A GB3148557A GB820146A GB 820146 A GB820146 A GB 820146A GB 31485/57 A GB31485/57 A GB 31485/57A GB 3148557 A GB3148557 A GB 3148557A GB 820146 A GB820146 A GB 820146A
- Authority
- GB
- United Kingdom
- Prior art keywords
- boron
- triethyl
- chlorides
- germanium
- alkyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910052796 boron Inorganic materials 0.000 title abstract 6
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 title abstract 5
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 title abstract 3
- 125000000217 alkyl group Chemical group 0.000 title abstract 3
- 229910052787 antimony Inorganic materials 0.000 title abstract 3
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 title abstract 3
- 229910052785 arsenic Inorganic materials 0.000 title abstract 3
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 title abstract 3
- 229910052797 bismuth Inorganic materials 0.000 title abstract 3
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 title abstract 3
- 229910052733 gallium Inorganic materials 0.000 title abstract 3
- 229910052732 germanium Inorganic materials 0.000 title abstract 3
- 229910052753 mercury Inorganic materials 0.000 title abstract 3
- 150000001348 alkyl chlorides Chemical class 0.000 title abstract 2
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 title abstract 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 title abstract 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 abstract 4
- 101100058670 Aeromonas hydrophila subsp. hydrophila (strain ATCC 7966 / DSM 30187 / BCRC 13018 / CCUG 14551 / JCM 1027 / KCTC 2358 / NCIMB 9240 / NCTC 8049) bsr gene Proteins 0.000 abstract 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 abstract 3
- QPUYECUOLPXSFR-UHFFFAOYSA-N 1-methylnaphthalene Chemical compound C1=CC=C2C(C)=CC=CC2=C1 QPUYECUOLPXSFR-UHFFFAOYSA-N 0.000 abstract 2
- 229910052782 aluminium Inorganic materials 0.000 abstract 2
- 239000004411 aluminium Substances 0.000 abstract 2
- -1 aluminium alkyl chlorides Chemical class 0.000 abstract 2
- 238000006243 chemical reaction Methods 0.000 abstract 2
- 150000001805 chlorine compounds Chemical class 0.000 abstract 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 abstract 2
- 239000011780 sodium chloride Substances 0.000 abstract 2
- 229910001538 sodium tetrachloroaluminate Inorganic materials 0.000 abstract 2
- 239000002904 solvent Substances 0.000 abstract 2
- FAQYAMRNWDIXMY-UHFFFAOYSA-N trichloroborane Chemical compound ClB(Cl)Cl FAQYAMRNWDIXMY-UHFFFAOYSA-N 0.000 abstract 2
- LALRXNPLTWZJIJ-UHFFFAOYSA-N triethylborane Chemical group CCB(CC)CC LALRXNPLTWZJIJ-UHFFFAOYSA-N 0.000 abstract 2
- JGMOKGBVKVMRFX-UHFFFAOYSA-N 17-acetyl-10,13-dimethyl-1,2,8,9,11,12,14,15,16,17-decahydrocyclopenta[a]phenanthren-3-one Chemical compound C1=CC2=CC(=O)CCC2(C)C2C1C1CCC(C(=O)C)C1(C)CC2 JGMOKGBVKVMRFX-UHFFFAOYSA-N 0.000 abstract 1
- 229910015844 BCl3 Inorganic materials 0.000 abstract 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract 1
- 229910001514 alkali metal chloride Inorganic materials 0.000 abstract 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 1
- LCWVIHDXYOFGEG-UHFFFAOYSA-N diboron tetrachloride Chemical compound ClB(Cl)B(Cl)Cl LCWVIHDXYOFGEG-UHFFFAOYSA-N 0.000 abstract 1
- 239000003085 diluting agent Substances 0.000 abstract 1
- 239000002270 dispersing agent Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/30—Germanium compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
- C07F3/10—Mercury compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/02—Boron compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
The chlorides of boron, mercury, gallium, germanium, arsenic, antimony and bismuth are reacted with aluminium trialkyls, their etherates or aluminium alkyl chlorides in the presence of or with the subsequent addition of alkali metal chlorides to give the alkyls or alkyl chlorides of said elements. Typical reactions are: AlR3 + BCl3 + NaCl --> BR3 + NaAlCl4 3HgCl2 + AlR3 + 2NaCl --> 3HgR2 + 2NaAlCl4 3BCl3 + AlR3 + NaCl --> 3BRCl2 + NaAlCl4 The reaction may take place in the presence of solvents, diluents or dispersants such as methylene chloride, chlorobenzene or methyl naphthalene or even the elemental alkyl it is intended to prepare may act as solvent. Instead of boron trichloride, boron alkyl chloride, boron dialkyl chloride or higher chlorides such as B2Cl4 may be reacted. The examples describe the preparation of: (1) boron triethyl, (2) boron triethyl and gallium triethyl; (4) boron tributyl; (5) mercury diethyl; (7) arsenic triethyl and antimony triethyl; (8) bismuth triethyl; (9) germanium tetra-ethyl and diethyl germanium dichloride; and (10) boron trioctyl.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE820146X | 1956-10-10 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB820146A true GB820146A (en) | 1959-09-16 |
Family
ID=6736254
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB31485/57A Expired GB820146A (en) | 1956-10-10 | 1957-10-08 | Method of preparing alkyls or alkyl chlorides of the elements boron, mercury, gallium, germanium, arsenic, antimony and bismuth |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB820146A (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3318931A (en) * | 1960-05-14 | 1967-05-09 | Siemens Schukertwerke Ag | Method of producing alkylgalliums |
US5043462A (en) * | 1989-04-28 | 1991-08-27 | Messer Greisheim | Process for the production of gallium-alkyl compounds |
EP1464647A2 (en) * | 2003-04-05 | 2004-10-06 | Rohm and Haas Electronic Materials, L.L.C. | Process for the preparation of group IVA and group VIA compounds |
WO2013116025A1 (en) | 2012-02-01 | 2013-08-08 | Chemtura Corporation | Preparation of tri-alkyl gallium or tri-alkyl indium compounds |
-
1957
- 1957-10-08 GB GB31485/57A patent/GB820146A/en not_active Expired
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3318931A (en) * | 1960-05-14 | 1967-05-09 | Siemens Schukertwerke Ag | Method of producing alkylgalliums |
US5043462A (en) * | 1989-04-28 | 1991-08-27 | Messer Greisheim | Process for the production of gallium-alkyl compounds |
EP1464647A2 (en) * | 2003-04-05 | 2004-10-06 | Rohm and Haas Electronic Materials, L.L.C. | Process for the preparation of group IVA and group VIA compounds |
EP1464647A3 (en) * | 2003-04-05 | 2007-01-03 | Rohm and Haas Electronic Materials, L.L.C. | Process for the preparation of group IVA and group VIA compounds |
WO2013116025A1 (en) | 2012-02-01 | 2013-08-08 | Chemtura Corporation | Preparation of tri-alkyl gallium or tri-alkyl indium compounds |
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