GB802740A - Copolymers containing an acrylamide - Google Patents

Copolymers containing an acrylamide

Info

Publication number
GB802740A
GB802740A GB20722/55A GB2072255A GB802740A GB 802740 A GB802740 A GB 802740A GB 20722/55 A GB20722/55 A GB 20722/55A GB 2072255 A GB2072255 A GB 2072255A GB 802740 A GB802740 A GB 802740A
Authority
GB
United Kingdom
Prior art keywords
acrylamide
copolymerization
vinyl acetate
methyl acrylate
copolymers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB20722/55A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NOBEL FRANCAISE SOC
Original Assignee
NOBEL FRANCAISE SOC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NOBEL FRANCAISE SOC filed Critical NOBEL FRANCAISE SOC
Publication of GB802740A publication Critical patent/GB802740A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/62—Polymers of compounds having carbon-to-carbon double bonds
    • C08G18/6216—Polymers of alpha-beta ethylenically unsaturated carboxylic acids or of derivatives thereof
    • C08G18/6266—Polymers of amides or imides from alpha-beta ethylenically unsaturated carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/52—Amides or imides
    • C08F20/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
    • C08F20/56—Acrylamide; Methacrylamide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
    • C08F218/02—Esters of monocarboxylic acids
    • C08F218/04—Vinyl esters
    • C08F218/08—Vinyl acetate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/14—Esterification
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/28—Condensation with aldehydes or ketones
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2810/00—Chemical modification of a polymer
    • C08F2810/20—Chemical modification of a polymer leading to a crosslinking, either explicitly or inherently

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polyurethanes Or Polyureas (AREA)

Abstract

Copolymers of vinyl acetate or acrylic or methacrylic esters with acrylamide or methacrylamide are cross-linked by adding thereto a polyisocyanate, e.g. toluylene isocyanate, or a polyaldehyde, e.g. glyoxal or trioxane, and heating the mixture at a temperature of from 25 DEG to 105 DEG C. In a modification of the process the amido groups of the copolymer are hydrolysed, e.g. with aqueous sulphuric acid, and the resulting carboxyl groups reacted with a polyalcohol, e.g. pentaerythritol, a polyamine or an inorganic polyvalent base. The examples describe the copolymerization of acrylamide with vinyl acetate or methyl acrylate in solution in toluene in the presence of benzoyl peroxide and the copolymerization of acrylamide with methyl acrylate in an aqueous medium containing sodium sulphoricinate, an oleic acid/ethylene oxide condensate and ammonium persulphate.
GB20722/55A 1954-07-22 1955-07-18 Copolymers containing an acrylamide Expired GB802740A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR1033414X 1954-07-22

Publications (1)

Publication Number Publication Date
GB802740A true GB802740A (en) 1958-10-08

Family

ID=9584450

Family Applications (1)

Application Number Title Priority Date Filing Date
GB20722/55A Expired GB802740A (en) 1954-07-22 1955-07-18 Copolymers containing an acrylamide

Country Status (3)

Country Link
DE (1) DE1033414B (en)
FR (1) FR1117408A (en)
GB (1) GB802740A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3419534A (en) * 1965-07-13 1968-12-31 Ici Ltd Polymers from polymerized unsaturated materials and uretidone dimers
US3931111A (en) * 1972-02-29 1976-01-06 Ceskoslovenska Akadamie Ved Soluble hydrophilic polymers and process for processing the same
WO1998047932A1 (en) * 1997-04-24 1998-10-29 Stockhausen Gmbh & Co. Kg Printable swelling paste and its use

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4051086A (en) * 1976-03-25 1977-09-27 Hercules Incorporated Absorption rate of absorbent polymers by treating with glyoxal

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3419534A (en) * 1965-07-13 1968-12-31 Ici Ltd Polymers from polymerized unsaturated materials and uretidone dimers
US3931111A (en) * 1972-02-29 1976-01-06 Ceskoslovenska Akadamie Ved Soluble hydrophilic polymers and process for processing the same
WO1998047932A1 (en) * 1997-04-24 1998-10-29 Stockhausen Gmbh & Co. Kg Printable swelling paste and its use
US6133369A (en) * 1997-04-24 2000-10-17 Stockhausen Gmbh & Co. Kc Printable swelling paste and the use thereof

Also Published As

Publication number Publication date
DE1033414B (en) 1958-07-03
FR1117408A (en) 1956-05-23

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