GB795142A - Process for the preparation of salts of dithiocarbamic acids, having a low water solubility - Google Patents
Process for the preparation of salts of dithiocarbamic acids, having a low water solubilityInfo
- Publication number
- GB795142A GB795142A GB16767/56A GB1676756A GB795142A GB 795142 A GB795142 A GB 795142A GB 16767/56 A GB16767/56 A GB 16767/56A GB 1676756 A GB1676756 A GB 1676756A GB 795142 A GB795142 A GB 795142A
- Authority
- GB
- United Kingdom
- Prior art keywords
- preparation
- salts
- water solubility
- low water
- zinc
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title abstract 2
- 239000002253 acid Substances 0.000 title 1
- 150000007513 acids Chemical class 0.000 title 1
- 150000003839 salts Chemical class 0.000 title 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 4
- QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 abstract 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 abstract 2
- 229910021529 ammonia Inorganic materials 0.000 abstract 2
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 abstract 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- YNNGZCVDIREDDK-UHFFFAOYSA-N aminocarbamodithioic acid Chemical compound NNC(S)=S YNNGZCVDIREDDK-UHFFFAOYSA-N 0.000 abstract 1
- 150000003863 ammonium salts Chemical class 0.000 abstract 1
- 125000000129 anionic group Chemical group 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 239000007900 aqueous suspension Substances 0.000 abstract 1
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 abstract 1
- 239000002270 dispersing agent Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 abstract 1
- 238000011065 in-situ storage Methods 0.000 abstract 1
- 229920005610 lignin Polymers 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- 239000011734 sodium Substances 0.000 abstract 1
- 229940007718 zinc hydroxide Drugs 0.000 abstract 1
- 229910021511 zinc hydroxide Inorganic materials 0.000 abstract 1
- 239000011787 zinc oxide Substances 0.000 abstract 1
- MBBWTVUFIXOUBE-UHFFFAOYSA-L zinc;dicarbamodithioate Chemical class [Zn+2].NC([S-])=S.NC([S-])=S MBBWTVUFIXOUBE-UHFFFAOYSA-L 0.000 abstract 1
- AMHNZOICSMBGDH-UHFFFAOYSA-L zineb Chemical compound [Zn+2].[S-]C(=S)NCCNC([S-])=S AMHNZOICSMBGDH-UHFFFAOYSA-L 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
- C07F3/003—Compounds containing elements of Groups 2 or 12 of the Periodic Table without C-Metal linkages
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
Abstract
Zinc dithiocarbamates of low solubility in water are obtained by reacting an aqueous suspension of zinc oxide or hydroxide with an aqueous solution of an ammonium dithiocarbamate, if desired in the presence of excess ammonia to get the product in a suitable physical form. There may be present an anionic or non-ionic dispersing agent such as sodium lignin sulphonate. The reaction temperature may be 10-40 DEG C. Examples are given of the preparation of zinc ethylene-bis-dithiocarbamate, in one case the ammonium salt being made in situ from ethylene diamine, carbon disulphide and ammonia.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT795142X | 1955-06-01 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB795142A true GB795142A (en) | 1958-05-14 |
Family
ID=11316761
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB16767/56A Expired GB795142A (en) | 1955-06-01 | 1956-05-30 | Process for the preparation of salts of dithiocarbamic acids, having a low water solubility |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB795142A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3081323A (en) * | 1958-12-02 | 1963-03-12 | Albert Ag Chem Werke | Fungicides and their production |
| US4831171A (en) * | 1985-09-26 | 1989-05-16 | Akzo N.V. | Process for synthesizing an ammonia complex of zinc bisdithiocarbamate |
| US4853475A (en) * | 1985-09-26 | 1989-08-01 | Akzo N.V. | Process for synthesizing alkylene bisdithiocarbamates or the ammonia adducts thereof as well as mixtures that can be synthesized thereby |
-
1956
- 1956-05-30 GB GB16767/56A patent/GB795142A/en not_active Expired
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3081323A (en) * | 1958-12-02 | 1963-03-12 | Albert Ag Chem Werke | Fungicides and their production |
| US4831171A (en) * | 1985-09-26 | 1989-05-16 | Akzo N.V. | Process for synthesizing an ammonia complex of zinc bisdithiocarbamate |
| US4853475A (en) * | 1985-09-26 | 1989-08-01 | Akzo N.V. | Process for synthesizing alkylene bisdithiocarbamates or the ammonia adducts thereof as well as mixtures that can be synthesized thereby |
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