GB785751A - Improvements in and relating to the purification of germanium - Google Patents

Improvements in and relating to the purification of germanium

Info

Publication number
GB785751A
GB785751A GB2060152A GB2060152A GB785751A GB 785751 A GB785751 A GB 785751A GB 2060152 A GB2060152 A GB 2060152A GB 2060152 A GB2060152 A GB 2060152A GB 785751 A GB785751 A GB 785751A
Authority
GB
United Kingdom
Prior art keywords
germanium
chlorine
less
purification
relating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2060152A
Inventor
Frederick Murray Reynolds
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
National Research Development Corp UK
Original Assignee
National Research Development Corp UK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by National Research Development Corp UK filed Critical National Research Development Corp UK
Priority to GB2060152A priority Critical patent/GB785751A/en
Publication of GB785751A publication Critical patent/GB785751A/en
Expired legal-status Critical Current

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  • Inorganic Compounds Of Heavy Metals (AREA)

Abstract

Germanium tetrachoride in association with such an amount of aqueous hydrochloric acid of 5.5 to 6N strength to form a second liquid phase, is distilled in the presence of suficient chlorine to saturate the system whereby the arsenical contamination is reduced to 0.005 p.p.m. or less. The chlorine may be generated in situ by the addition of an oxidizing agent such as potassium dichromate or chlorate, but is preferably added from an outside source. The tetrachloride may be converted by hydrolysis to the dioxide which has an arsenic contamination of 0.01 p.p.m. or less.
GB2060152A 1952-08-15 1952-08-15 Improvements in and relating to the purification of germanium Expired GB785751A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB2060152A GB785751A (en) 1952-08-15 1952-08-15 Improvements in and relating to the purification of germanium

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB2060152A GB785751A (en) 1952-08-15 1952-08-15 Improvements in and relating to the purification of germanium

Publications (1)

Publication Number Publication Date
GB785751A true GB785751A (en) 1957-11-06

Family

ID=10148633

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2060152A Expired GB785751A (en) 1952-08-15 1952-08-15 Improvements in and relating to the purification of germanium

Country Status (1)

Country Link
GB (1) GB785751A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2317366A1 (en) * 1975-07-08 1977-02-04 Penarroya Miniere Metall PROCESS FOR THE RECOVERY AND PURIFICATION OF GERMANIUM FROM ZINC ORE
WO2001005720A1 (en) * 1999-07-14 2001-01-25 Corning Incorporated Methods for the separation of compounds from acidic aqueous solutions

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2317366A1 (en) * 1975-07-08 1977-02-04 Penarroya Miniere Metall PROCESS FOR THE RECOVERY AND PURIFICATION OF GERMANIUM FROM ZINC ORE
US4090871A (en) 1975-07-08 1978-05-23 Societe Miniere Et Metallurgique De Penarroya Process for the recovery and purification of germanium from zinc ores
WO2001005720A1 (en) * 1999-07-14 2001-01-25 Corning Incorporated Methods for the separation of compounds from acidic aqueous solutions
US6238462B1 (en) 1999-07-14 2001-05-29 Corning Incorporated Methods for the separation of compounds from acidic aqueous solutions

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