GB781449A - Improvements in or relating to drier compositions for use in coating compositions containing drying oils and/or synthetic resins - Google Patents
Improvements in or relating to drier compositions for use in coating compositions containing drying oils and/or synthetic resinsInfo
- Publication number
- GB781449A GB781449A GB22987/53A GB2298753A GB781449A GB 781449 A GB781449 A GB 781449A GB 22987/53 A GB22987/53 A GB 22987/53A GB 2298753 A GB2298753 A GB 2298753A GB 781449 A GB781449 A GB 781449A
- Authority
- GB
- United Kingdom
- Prior art keywords
- cobalt
- zirconium
- drier
- manganese
- lead
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title abstract 8
- 238000001035 drying Methods 0.000 title abstract 5
- 239000003921 oil Substances 0.000 title abstract 5
- 239000008199 coating composition Substances 0.000 title abstract 3
- 229920003002 synthetic resin Polymers 0.000 title abstract 3
- 239000000057 synthetic resin Substances 0.000 title abstract 3
- 229910017052 cobalt Inorganic materials 0.000 abstract 19
- 239000010941 cobalt Substances 0.000 abstract 19
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 19
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 abstract 15
- 229910052726 zirconium Inorganic materials 0.000 abstract 15
- 239000011133 lead Substances 0.000 abstract 14
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 abstract 13
- 229910052748 manganese Inorganic materials 0.000 abstract 13
- 239000011572 manganese Substances 0.000 abstract 13
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 10
- 229920000180 alkyd Polymers 0.000 abstract 7
- 210000003298 dental enamel Anatomy 0.000 abstract 5
- 239000000344 soap Substances 0.000 abstract 5
- 239000004408 titanium dioxide Substances 0.000 abstract 5
- 150000003754 zirconium Chemical class 0.000 abstract 5
- -1 2-ethyl Chemical group 0.000 abstract 4
- 235000019198 oils Nutrition 0.000 abstract 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 abstract 3
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 abstract 3
- 239000002253 acid Substances 0.000 abstract 3
- 125000001931 aliphatic group Chemical group 0.000 abstract 3
- 229910052791 calcium Inorganic materials 0.000 abstract 3
- 239000011575 calcium Substances 0.000 abstract 3
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 abstract 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 abstract 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 2
- 239000004359 castor oil Substances 0.000 abstract 2
- 235000019438 castor oil Nutrition 0.000 abstract 2
- 239000003822 epoxy resin Substances 0.000 abstract 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 abstract 2
- 235000021388 linseed oil Nutrition 0.000 abstract 2
- 239000000944 linseed oil Substances 0.000 abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- 239000005012 oleoresinous Substances 0.000 abstract 2
- 239000003973 paint Substances 0.000 abstract 2
- 229920000647 polyepoxide Polymers 0.000 abstract 2
- 229910052761 rare earth metal Inorganic materials 0.000 abstract 2
- 150000002910 rare earth metals Chemical class 0.000 abstract 2
- 235000012424 soybean oil Nutrition 0.000 abstract 2
- 239000010936 titanium Substances 0.000 abstract 2
- 229910052719 titanium Inorganic materials 0.000 abstract 2
- ZSLUVFAKFWKJRC-IGMARMGPSA-N 232Th Chemical compound [232Th] ZSLUVFAKFWKJRC-IGMARMGPSA-N 0.000 abstract 1
- 229910052684 Cerium Inorganic materials 0.000 abstract 1
- 240000006240 Linum usitatissimum Species 0.000 abstract 1
- 235000004431 Linum usitatissimum Nutrition 0.000 abstract 1
- 229910052779 Neodymium Inorganic materials 0.000 abstract 1
- 229910052772 Samarium Inorganic materials 0.000 abstract 1
- 229910052776 Thorium Inorganic materials 0.000 abstract 1
- GZCGUPFRVQAUEE-SLPGGIOYSA-N aldehydo-D-glucose Chemical class OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O GZCGUPFRVQAUEE-SLPGGIOYSA-N 0.000 abstract 1
- 229910000019 calcium carbonate Inorganic materials 0.000 abstract 1
- 229910001576 calcium mineral Inorganic materials 0.000 abstract 1
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 abstract 1
- 235000012343 cottonseed oil Nutrition 0.000 abstract 1
- 235000014113 dietary fatty acids Nutrition 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 229930195729 fatty acid Natural products 0.000 abstract 1
- 239000000194 fatty acid Substances 0.000 abstract 1
- 150000004665 fatty acids Chemical class 0.000 abstract 1
- 235000004426 flaxseed Nutrition 0.000 abstract 1
- 229910052746 lanthanum Inorganic materials 0.000 abstract 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 abstract 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 239000011707 mineral Substances 0.000 abstract 1
- 125000005609 naphthenate group Chemical group 0.000 abstract 1
- QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 abstract 1
- 239000010665 pine oil Substances 0.000 abstract 1
- KZUNJOHGWZRPMI-UHFFFAOYSA-N samarium atom Chemical compound [Sm] KZUNJOHGWZRPMI-UHFFFAOYSA-N 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 150000005846 sugar alcohols Polymers 0.000 abstract 1
- 239000002966 varnish Substances 0.000 abstract 1
- 229910052727 yttrium Inorganic materials 0.000 abstract 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C53/00—Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
- C07C53/126—Acids containing more than four carbon atoms
- C07C53/128—Acids containing more than four carbon atoms the carboxylic group being bound to a carbon atom bound to at least two other carbon atoms, e.g. neo-acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/003—Compounds containing elements of Groups 4 or 14 of the Periodic Table without C-Metal linkages
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B23/00—Methine or polymethine dyes, e.g. cyanine dyes
- C09B23/10—The polymethine chain containing an even number of >CH- groups
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09F—NATURAL RESINS; FRENCH POLISH; DRYING-OILS; OIL DRYING AGENTS, i.e. SICCATIVES; TURPENTINE
- C09F9/00—Compounds to be used as driers, i.e. siccatives
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
A drier composition for use in coating compositions containing drying oils and/or synthetic resins contains as a primary drier a cobalt and/or manganese drier, and a zirconium salt of a monocarboxylic aliphatic acid as a booster drier. The zirconium salt, which may be zirconyl 2-ethyl hexoate or zirconyl n-octoate, replaces up to 60 per cent of the cobalt drier and up to 80 per cent of the manganese drier, both calculated as metals, that would be required if the zirconium salt were omitted. Lead and calcium soaps may be added. The drier composition may be used in paints based on linseed oil, dehydrated castor oil, esters of drying or semi-drying oil fatty acids with polyhydric alcohols, oil-modified alkyd resins which may also be styrenated or phenol-modified, or an oil-modified epoxy resin.ALSO:Synthetic resin coating compositions comprise a drier composition consisting of a cobalt and/or manganese primary drier and a zirconium salt of a monocarboxylic aliphatic acid of a monocarboxylic aliphatic acid as a booster drier. The zirconium salt may be zirconyl n-octoate or zirconyl 2-ethyl hexoate. In examples: (1), (4) and (5) white enamels to be tested consist of a soya oil modified alkyd resin, titanium dioxide, and drier compositions containing the following combinations of metal radicles: lead and cobalt; lead, cobalt and zirconium; lead and zirconium; lead, cobalt and manganese; lead, cobalt, manganese and zirconium; cobalt and manganese; cobalt, manganese and zirconium; cobalt and zirconium; manganese and zirconium; (2) a titanium dioxide pigmented alkyd modified maleic medium oil length oleoresinous varnish is tested with drier compositions containing soaps of lead and cobalt; lead, cobalt and zirconium; lead and manganese; lead, manganese and zirconium; lead, cobalt and manganese; lead, cobalt, manganese and zirconium; (3) a slow-drying white enamel comprising bodied linseed oil, pentaerythritol-modified oleoresinous alkyd resin, titanium dioxide, calcium carbonate and mineral spirit is tested with drier compositions containing soaps of lead, cobalt and calcium; lead, cobalt and zirconium; cobalt, and zirconium; (6) a titanium dioxide-pigmented enamel containing a cottonseed oil-modified alkyd resin, a butylated urea-form-aldehyde resin, and xylol is tested with driers consisting of soaps of zirconium alone and of cobalt, manganese and rare earth metal with and without zirconium; the rare earth driers consist of naphthenates of cerium, lanthanum, praesodymium, neodymium, samarium, and trace amounts of calcium, thorium and yttrium; (7) a white enamel containing a phenol-modified medium oil length alkyd resin containing 52 per cent soya oil content, titanium dioxide and solvent naphtha is tested with driers consisting of soaps of cobalt and manganese, with or without zirconium and of zirconium alone; (8) a titanium dioxide-pigmented xylol solution of an epoxy resin that has been reacted with dehydrated castor oil is tested as in (6); (9) a white enamel containing a short linseed oil-modified styrenated alkyd resin, titanium dioxide, pine oil and xylol is tested as in (7).ALSO:Zirconyl n-octoate for use in a paint drier composition may be prepared by a method similar to the method for preparing zirconyl 2-ethyl hexoate described in Specification 781,450.
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US977089XA | 1952-08-29 | 1952-08-29 | |
| US781449XA | 1952-08-29 | 1952-08-29 | |
| US307153A US2739905A (en) | 1952-08-29 | 1952-08-29 | Zirconyl 2-ethylhexoate |
| US307152A US2739902A (en) | 1952-08-29 | 1952-08-29 | Drier compositions |
| US382459A US2739965A (en) | 1953-09-25 | 1953-09-25 | Sensitizing dyes containing a chain alkyl- or arylthio group |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB781449A true GB781449A (en) | 1957-08-21 |
Family
ID=33033332
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB22987/53A Expired GB781449A (en) | 1952-08-29 | 1953-08-20 | Improvements in or relating to drier compositions for use in coating compositions containing drying oils and/or synthetic resins |
Country Status (2)
| Country | Link |
|---|---|
| DE (1) | DE977089C (en) |
| GB (1) | GB781449A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2051093A (en) * | 1979-05-09 | 1981-01-14 | Nippon Mining Co | Accelerated hardening of unsaturated polyester resins |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2132997A (en) * | 1938-10-11 | Preparation of metallic soaps | ||
| GB395406A (en) * | 1931-01-16 | 1933-07-17 | Titanium Pigment Co Inc | Improvements in or relating to the manufacture of metallic soaps |
| US2095508A (en) * | 1931-03-02 | 1937-10-12 | Ig Farbenindustrie Ag | Process of manufacturing naphthenates |
| US2221975A (en) * | 1936-08-26 | 1940-11-19 | Titanium Alloy Mfg Co | Zirconium salts of water-insoluble fatty acids and methods of making same |
| US2225289A (en) * | 1939-01-19 | 1940-12-17 | Harris Seybold Potter Co | Printing ink extender manufacture |
-
1953
- 1953-08-20 GB GB22987/53A patent/GB781449A/en not_active Expired
- 1953-08-29 DE DEA18677A patent/DE977089C/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2051093A (en) * | 1979-05-09 | 1981-01-14 | Nippon Mining Co | Accelerated hardening of unsaturated polyester resins |
Also Published As
| Publication number | Publication date |
|---|---|
| DE977089C (en) | 1965-02-04 |
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