GB552644A - Improvements in or relating to resinous ester products - Google Patents
Improvements in or relating to resinous ester productsInfo
- Publication number
- GB552644A GB552644A GB9825/41A GB982541A GB552644A GB 552644 A GB552644 A GB 552644A GB 9825/41 A GB9825/41 A GB 9825/41A GB 982541 A GB982541 A GB 982541A GB 552644 A GB552644 A GB 552644A
- Authority
- GB
- United Kingdom
- Prior art keywords
- oil
- linseed
- glycerol
- adduct
- fatty acids
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000002148 esters Chemical class 0.000 title abstract 8
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 abstract 21
- 239000000047 product Substances 0.000 abstract 11
- 235000014113 dietary fatty acids Nutrition 0.000 abstract 9
- 239000000194 fatty acid Substances 0.000 abstract 9
- 229930195729 fatty acid Natural products 0.000 abstract 9
- 150000004665 fatty acids Chemical class 0.000 abstract 9
- 239000003921 oil Substances 0.000 abstract 7
- 235000019198 oils Nutrition 0.000 abstract 7
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract 6
- 240000006240 Linum usitatissimum Species 0.000 abstract 6
- 235000004431 Linum usitatissimum Nutrition 0.000 abstract 6
- 235000004426 flaxseed Nutrition 0.000 abstract 6
- 238000007792 addition Methods 0.000 abstract 5
- ZSWFCLXCOIISFI-UHFFFAOYSA-N cyclopentadiene Chemical compound C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 abstract 5
- 238000001035 drying Methods 0.000 abstract 5
- 239000002966 varnish Substances 0.000 abstract 5
- 244000068988 Glycine max Species 0.000 abstract 4
- 235000010469 Glycine max Nutrition 0.000 abstract 4
- 210000003298 dental enamel Anatomy 0.000 abstract 4
- 238000010438 heat treatment Methods 0.000 abstract 4
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 abstract 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 abstract 3
- 239000002253 acid Substances 0.000 abstract 3
- 239000000944 linseed oil Substances 0.000 abstract 3
- 235000021388 linseed oil Nutrition 0.000 abstract 3
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 abstract 3
- 229920005989 resin Polymers 0.000 abstract 3
- 239000011347 resin Substances 0.000 abstract 3
- 239000002904 solvent Substances 0.000 abstract 3
- FJKROLUGYXJWQN-UHFFFAOYSA-N 4-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 abstract 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 abstract 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract 2
- 235000004347 Perilla Nutrition 0.000 abstract 2
- 244000124853 Perilla frutescens Species 0.000 abstract 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 abstract 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 abstract 2
- 239000011280 coal tar Substances 0.000 abstract 2
- 239000011248 coating agent Substances 0.000 abstract 2
- 239000008199 coating composition Substances 0.000 abstract 2
- 238000000576 coating method Methods 0.000 abstract 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 abstract 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 abstract 2
- 239000011976 maleic acid Substances 0.000 abstract 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 abstract 2
- 239000002383 tung oil Substances 0.000 abstract 2
- -1 wires Chemical class 0.000 abstract 2
- LDVVTQMJQSCDMK-UHFFFAOYSA-N 1,3-dihydroxypropan-2-yl formate Chemical compound OCC(CO)OC=O LDVVTQMJQSCDMK-UHFFFAOYSA-N 0.000 abstract 1
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 abstract 1
- DVIVBQJVHLJFFS-UHFFFAOYSA-N 3-cyclopenta-1,3-dien-1-ylfuran-2,5-dione Chemical compound O=C1OC(=O)C(C=2CC=CC=2)=C1 DVIVBQJVHLJFFS-UHFFFAOYSA-N 0.000 abstract 1
- BTXXTMOWISPQSJ-UHFFFAOYSA-N 4,4,4-trifluorobutan-2-one Chemical compound CC(=O)CC(F)(F)F BTXXTMOWISPQSJ-UHFFFAOYSA-N 0.000 abstract 1
- 229940090248 4-hydroxybenzoic acid Drugs 0.000 abstract 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 abstract 1
- BQACOLQNOUYJCE-FYZZASKESA-N Abietic acid Natural products CC(C)C1=CC2=CC[C@]3(C)[C@](C)(CCC[C@@]3(C)C(=O)O)[C@H]2CC1 BQACOLQNOUYJCE-FYZZASKESA-N 0.000 abstract 1
- 244000105624 Arachis hypogaea Species 0.000 abstract 1
- 229920001342 Bakelite® Polymers 0.000 abstract 1
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 abstract 1
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 abstract 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 abstract 1
- 229930195725 Mannitol Natural products 0.000 abstract 1
- 229910002651 NO3 Inorganic materials 0.000 abstract 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 abstract 1
- 239000000020 Nitrocellulose Substances 0.000 abstract 1
- 240000002834 Paulownia tomentosa Species 0.000 abstract 1
- 235000010678 Paulownia tomentosa Nutrition 0.000 abstract 1
- 235000019483 Peanut oil Nutrition 0.000 abstract 1
- 239000004372 Polyvinyl alcohol Substances 0.000 abstract 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 abstract 1
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 abstract 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 abstract 1
- 229920001807 Urea-formaldehyde Polymers 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- 150000001298 alcohols Chemical class 0.000 abstract 1
- 229920000180 alkyd Polymers 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 235000020661 alpha-linolenic acid Nutrition 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 239000004637 bakelite Substances 0.000 abstract 1
- OGBUMNBNEWYMNJ-UHFFFAOYSA-N batilol Chemical class CCCCCCCCCCCCCCCCCCOCC(O)CO OGBUMNBNEWYMNJ-UHFFFAOYSA-N 0.000 abstract 1
- 239000011230 binding agent Substances 0.000 abstract 1
- YXVFYQXJAXKLAK-UHFFFAOYSA-N biphenyl-4-ol Chemical compound C1=CC(O)=CC=C1C1=CC=CC=C1 YXVFYQXJAXKLAK-UHFFFAOYSA-N 0.000 abstract 1
- 239000006229 carbon black Substances 0.000 abstract 1
- 239000005018 casein Substances 0.000 abstract 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 abstract 1
- 235000021240 caseins Nutrition 0.000 abstract 1
- 239000004359 castor oil Substances 0.000 abstract 1
- 235000019438 castor oil Nutrition 0.000 abstract 1
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical class OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 abstract 1
- 229920002678 cellulose Polymers 0.000 abstract 1
- 239000002385 cottonseed oil Substances 0.000 abstract 1
- 235000012343 cottonseed oil Nutrition 0.000 abstract 1
- VWONMYIGFCXQCV-UHFFFAOYSA-N cyclopenta-1,3-diene;furan-2,5-dione Chemical compound C1C=CC=C1.O=C1OC(=O)C=C1 VWONMYIGFCXQCV-UHFFFAOYSA-N 0.000 abstract 1
- 238000007865 diluting Methods 0.000 abstract 1
- 239000003995 emulsifying agent Substances 0.000 abstract 1
- 239000000839 emulsion Substances 0.000 abstract 1
- 125000004494 ethyl ester group Chemical group 0.000 abstract 1
- 239000004744 fabric Substances 0.000 abstract 1
- 235000010985 glycerol esters of wood rosin Nutrition 0.000 abstract 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 abstract 1
- 239000000976 ink Substances 0.000 abstract 1
- 229910052740 iodine Inorganic materials 0.000 abstract 1
- 239000011630 iodine Substances 0.000 abstract 1
- DCYOBGZUOMKFPA-UHFFFAOYSA-N iron(2+);iron(3+);octadecacyanide Chemical compound [Fe+2].[Fe+2].[Fe+2].[Fe+3].[Fe+3].[Fe+3].[Fe+3].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] DCYOBGZUOMKFPA-UHFFFAOYSA-N 0.000 abstract 1
- 239000004922 lacquer Substances 0.000 abstract 1
- HTUMBQDCCIXGCV-UHFFFAOYSA-N lead oxide Chemical compound [O-2].[Pb+2] HTUMBQDCCIXGCV-UHFFFAOYSA-N 0.000 abstract 1
- YEXPOXQUZXUXJW-UHFFFAOYSA-N lead(II) oxide Inorganic materials [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 abstract 1
- 235000020778 linoleic acid Nutrition 0.000 abstract 1
- OYHQOLUKZRVURQ-HZJYTTRNSA-N linoleic acid group Chemical group C(CCCCCCC\C=C/C\C=C/CCCCC)(=O)O OYHQOLUKZRVURQ-HZJYTTRNSA-N 0.000 abstract 1
- 125000005481 linolenic acid group Chemical group 0.000 abstract 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 abstract 1
- 239000000594 mannitol Substances 0.000 abstract 1
- 235000010355 mannitol Nutrition 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 229920001220 nitrocellulos Polymers 0.000 abstract 1
- 235000021313 oleic acid Nutrition 0.000 abstract 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid group Chemical group C(CCCCCCC\C=C/CCCCCCCC)(=O)O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 abstract 1
- 235000006408 oxalic acid Nutrition 0.000 abstract 1
- 239000000312 peanut oil Substances 0.000 abstract 1
- 239000003208 petroleum Substances 0.000 abstract 1
- 229920001568 phenolic resin Polymers 0.000 abstract 1
- 239000005011 phenolic resin Substances 0.000 abstract 1
- 150000002989 phenols Chemical class 0.000 abstract 1
- 239000000049 pigment Substances 0.000 abstract 1
- 239000004014 plasticizer Substances 0.000 abstract 1
- 229920002451 polyvinyl alcohol Polymers 0.000 abstract 1
- 229960003351 prussian blue Drugs 0.000 abstract 1
- 239000013225 prussian blue Substances 0.000 abstract 1
- 239000012262 resinous product Substances 0.000 abstract 1
- 239000000600 sorbitol Substances 0.000 abstract 1
- 150000005846 sugar alcohols Polymers 0.000 abstract 1
- 229920003002 synthetic resin Polymers 0.000 abstract 1
- 239000000057 synthetic resin Substances 0.000 abstract 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 abstract 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 abstract 1
- 150000003626 triacylglycerols Chemical class 0.000 abstract 1
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 abstract 1
- 239000011787 zinc oxide Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/08—Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/52—Polycarboxylic acids or polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation
- C08G63/54—Polycarboxylic acids or polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation the acids or hydroxy compounds containing carbocyclic rings
- C08G63/553—Acids or hydroxy compounds containing cycloaliphatic rings, e.g. Diels-Alder adducts
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D155/00—Coating compositions based on homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C09D123/00 - C09D153/00
- C09D155/04—Polyadducts obtained by the diene synthesis
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Paints Or Removers (AREA)
- Phenolic Resins Or Amino Resins (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
552,644. Coating compositions derived from resinous ester products. BAKELITE, Ltd. Aug. 1, 1941, No. 9825. [Class 2 (iii)] Resinous ester products suitable for use alone or with additions as coating compositions, in particular as varnishes, enamels and for coating wires, are prepared by re-acting together a cyclopentadiene adduct of maleic acid or anhydride with a polyhydric alcohol and a monobasic fatty acid derived from a drying or semi-drying oil. Specified alcohols are glycol, glycerol, sorbitol, mannitol and pentaerythritol. Specified monobasic fatty acids are the acids containing oleic, linoleic or linolenic acids derived from drying or semidrying oils ; they may be replaced wholly or partly by their monoglycerides or triglycerides which latter have been oxidized to an iodine value of 105 to 135, the proportion of glycerol being correspondingly reduced. It is preferred that the monobasic acid calculated as triglyceride makes 50 per cent. of the re-action mass. The acid may be wholly or partly replaced by dehydrated castor oil. The cyclopentadiene adducts are referred to in " The Chemistry of Synthetic Resins " (Ellis, 1935 ed.) chap. 40 ; the adduct may be partially replaced by an oil-soluble phenolic resin such as that prepared from an alkyl or aryl substituted phenol or an hydroxy phenol. The resinous ester products may be modified by the addition of alkyd or urea-formaldehyde resins, casein, and plasticisers such as tricresyl phosphate, dibutyl phthalate or the non-drying monobasic fatty acid derived from peanut or cottonseed oils. The resinous ester products are suitable for coating metals, e.g. wires, and for impregnating paper, felt, and cloth and may be used alone, in aqueous emulsion or diluted with thinners. As emulsifying agent triethanolamine is specified, and thinners mentioned include volatile solvents, hydrocarbon thinners and coal tar solvents. The products may be modified by heating with a drying or semidrying oil, e.g. linseed, oiticica, tung or perilla oils which has preferably been pre-heated and are compatible with cellulose esters, e.g. nitrate or ethyl ester. Printing inks may be obtained by modifying the ester products with oil with the addition of pigments such as carbon black or Prussian blue. In examples, a resinous ester product was obtained by heating the maleic anhydride-cyclopentadiene adduct with glycerol and (1) linseed monobasic fatty acids, (2) blown linseed or soya bean oil or (4) linseed and soya bean fatty acids. In (5) the cyclopentadiene maleic anhydride adduct was heated with pentaerythritol and soya bean fatty acids and diluted with xylol with the addition of driers, an enamel being obtained from the varnish by adding titanium oxide, zinc oxide and petroleum thinner, and a lacquer by addition of nitrocellulose and xylol. (6) An oilsoluble resin obtained from p-hydroxy benzoic acid and formaldehyde in the presence of oxalic acid was heated with abietic acid, glycerol, the adduct and linseed and soya bean fatty acids (part of the glycerol could be replaced by polyvinyl alcohol). In (7) linseed oil monoglyceride was obtained by heating linseed oil and glycerol in the presence of litharge; the product was heated with glycerol, and the adduct to form a varnish. A varnish was obtained by diluting the resinous product of (4) with (8) xylol and driers and (9) an enamel by using the product of (4) but made from linseed fatty acids only mixed with coal tar solvent, tung oil and a resin made from p-phenyl phenol and formaldehyde. A wire enamel was made by heating the cyclopentadiene adduct of maleic acid with china wood oil fatty acids and pentaerythritol and adding thinner. Resinous ester products were heated with (11) linseed oil, to give (12) a binder suitable for brake linings ; (13) ester gum and perilla oil or Cumar or Congo resin or rosin ; these modified products could be further diluted to obtain varnishes. Specification 468,542 is referred to.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US552644XA | 1940-08-03 | 1940-08-03 | |
US351235A US2397240A (en) | 1940-08-03 | 1940-08-03 | Ester resin compositions |
Publications (1)
Publication Number | Publication Date |
---|---|
GB552644A true GB552644A (en) | 1943-04-19 |
Family
ID=26734038
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB9825/41A Expired GB552644A (en) | 1940-08-03 | 1941-08-01 | Improvements in or relating to resinous ester products |
Country Status (2)
Country | Link |
---|---|
US (1) | US2397240A (en) |
GB (1) | GB552644A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2518495A (en) * | 1946-03-15 | 1950-08-15 | Montelair Res Corp | Rosin ester reaction products and the process of making same |
Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2452992A (en) * | 1948-11-02 | Coating composition of fatty drying | ||
US2551386A (en) * | 1946-04-04 | 1951-05-01 | Pittsburgh Plate Glass Co | Wrinkle finish composition |
US2600457A (en) * | 1950-02-28 | 1952-06-17 | Union Carbide & Carbon Corp | Copolymers of fatty oil modified polyesters and vinyl monomers |
US2881144A (en) * | 1955-08-23 | 1959-04-07 | Exxon Research Engineering Co | Alkyd resins from dicyclopentadiene dicarboxylic acids and polyhydric alcohols |
US2860112A (en) * | 1955-10-31 | 1958-11-11 | Exxon Research Engineering Co | Alkyd resins produced from tricarboxylic acids and dibasic alcohols |
US3088927A (en) * | 1959-09-10 | 1963-05-07 | Velsicol Chemical Corp | Oil modified alkyl resins modified with a thermal polymer of dicyclopentadiene |
US3448066A (en) * | 1966-11-17 | 1969-06-03 | Ppg Industries Inc | Air-drying unsaturated polyester resins prepared from a polyol and an adduct of cyclopentadiene and a dicarboxylic acid |
DE2618629C3 (en) * | 1976-04-28 | 1982-04-22 | Hoechst Ag, 6000 Frankfurt | Modified air-drying alkyd resins |
US4439623A (en) * | 1981-10-05 | 1984-03-27 | Merck & Co., Inc. | Process for the preparation of monochloroacetone |
WO2010141907A1 (en) | 2009-06-04 | 2010-12-09 | Rotation Medical, Inc. | Apparatus having bowstring-like staple delivery to a target tissue |
CA2965853A1 (en) | 2014-11-04 | 2016-05-12 | Rotation Medical, Inc. | Medical implant delivery system and related methods |
AU2015343273B2 (en) | 2014-11-04 | 2017-12-14 | Rotation Medical, Inc. | Medical implant delivery system and related methods |
US10123796B2 (en) | 2014-11-04 | 2018-11-13 | Rotation Medical, Inc. | Medical implant delivery system and related methods |
WO2017117437A1 (en) | 2015-12-31 | 2017-07-06 | Rotation Medical, Inc. | Fastener delivery system and related methods |
-
1940
- 1940-08-03 US US351235A patent/US2397240A/en not_active Expired - Lifetime
-
1941
- 1941-08-01 GB GB9825/41A patent/GB552644A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2518495A (en) * | 1946-03-15 | 1950-08-15 | Montelair Res Corp | Rosin ester reaction products and the process of making same |
Also Published As
Publication number | Publication date |
---|---|
US2397240A (en) | 1946-03-26 |
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