GB771423A - Improvements in alkyl-n-sorbitylalkanamides - Google Patents
Improvements in alkyl-n-sorbitylalkanamidesInfo
- Publication number
- GB771423A GB771423A GB21832/55A GB2183255A GB771423A GB 771423 A GB771423 A GB 771423A GB 21832/55 A GB21832/55 A GB 21832/55A GB 2183255 A GB2183255 A GB 2183255A GB 771423 A GB771423 A GB 771423A
- Authority
- GB
- United Kingdom
- Prior art keywords
- alkyl
- tert
- methyl
- sorbityl
- tetradecyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C233/00—Carboxylic acid amides
- C07C233/01—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms
- C07C233/16—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
The invention comprises N-alkyl N-sorbityl amides of the formula: <FORM:0771423/IV(b)/1> wherein X is a hydrogen atom or a methyl group and R is an alkyl group of 1 to 20, preferably 1 to 18, carbon atoms, and their preparation by reacting an N-alkyl glucamine with a lower alkyl formate or acetate wherein the alkyl group contains from 1 to 4 carbon atoms, preferably at a temperature between 30 DEG C. and the reflux temperature of the reaction mixture. The products are used as surface-active agents and in some cases, e.g. N - methyl - N - sorbitylformamide, as therapeutic substances. Examples describe the reaction of alkyl formates and alkyl acetates with the appropriate N-alkyl glucamines to produce N-alkyl-N-sorbityl formamides and acetamides wherein the alkyl groups are chosen from methyl, butyl, octyl, isodecyl, dodecyl, tert.-tridecyl, tetradecyl, tert.-tetradecyl, hexadecyl, octadecyl, eicosyl and tert.-eicosyl groups.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US771423XA | 1954-08-19 | 1954-08-19 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB771423A true GB771423A (en) | 1957-04-03 |
Family
ID=22136316
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB21832/55A Expired GB771423A (en) | 1954-08-19 | 1955-07-28 | Improvements in alkyl-n-sorbitylalkanamides |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB771423A (en) |
Cited By (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1983004412A1 (en) * | 1982-06-11 | 1983-12-22 | National Research Development Corporation | Amphipathic compounds |
EP0220676A1 (en) * | 1985-10-29 | 1987-05-06 | Süddeutsche Zucker-Aktiengesellschaft | Fatty-acid amides of aminopolyols as non-ionogenic tensides |
US5174927A (en) * | 1990-09-28 | 1992-12-29 | The Procter & Gamble Company | Process for preparing brightener-containing liquid detergent compositions with polyhydroxy fatty acid amines |
US5194639A (en) * | 1990-09-28 | 1993-03-16 | The Procter & Gamble Company | Preparation of polyhydroxy fatty acid amides in the presence of solvents |
US5254281A (en) * | 1991-01-29 | 1993-10-19 | The Procter & Gamble Company | Soap bars with polyhydroxy fatty acid amides |
US5332528A (en) * | 1990-09-28 | 1994-07-26 | The Procter & Gamble Company | Polyhydroxy fatty acid amides in soil release agent-containing detergent compositions |
US5338487A (en) * | 1990-09-28 | 1994-08-16 | The Procter & Gamble Company | Catalyzed process for glucamide detergents |
US5338486A (en) * | 1990-09-28 | 1994-08-16 | The Procter & Gamble Company | High catalyst process for glucamide detergents |
US5354425A (en) * | 1993-12-13 | 1994-10-11 | The Procter & Gamble Company | Tissue paper treated with polyhydroxy fatty acid amide softener systems that are biodegradable |
US5380891A (en) * | 1990-09-28 | 1995-01-10 | The Procter & Gamble Company | Phase transfer assisted process for glucamide detergents |
US5449770A (en) * | 1992-01-14 | 1995-09-12 | The Procter & Gamble Company | Process for making N-alkylamino polyols |
US5454982A (en) * | 1990-09-28 | 1995-10-03 | The Procter & Gamble Company | Detergent composition containing polyhydroxy fatty acid amide and alkyl ester sulfonate surfactants |
US5625098A (en) * | 1991-07-26 | 1997-04-29 | The Procter & Gamble Company | Process for preparing N-alkyl polyhydroxyalkyl amines in aqueous/hydroxy solvents |
US5700771A (en) * | 1990-09-28 | 1997-12-23 | The Procter & Gamble Company | Polyhydroxy fatty acid amide surfactants in percarbonate bleach-containing compositions |
US5723673A (en) * | 1995-06-07 | 1998-03-03 | The Procter & Gamble Company | Process for preparing amides of N-alkyl polyhydroxyalkyls |
US5777165A (en) * | 1995-06-07 | 1998-07-07 | The Procter & Gamble Company | Process for preparing amides of N-alkyl polyhydroxyalkyl amines |
PL422564A1 (en) * | 2017-08-17 | 2019-02-25 | Zachodniopomorski Uniwersytet Technologiczny W Szczecinie | Method for obtaining surface active compounds from the group of N-alkanoyl-N-methylglucamines |
-
1955
- 1955-07-28 GB GB21832/55A patent/GB771423A/en not_active Expired
Cited By (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1983004412A1 (en) * | 1982-06-11 | 1983-12-22 | National Research Development Corporation | Amphipathic compounds |
EP0220676A1 (en) * | 1985-10-29 | 1987-05-06 | Süddeutsche Zucker-Aktiengesellschaft | Fatty-acid amides of aminopolyols as non-ionogenic tensides |
US5454982A (en) * | 1990-09-28 | 1995-10-03 | The Procter & Gamble Company | Detergent composition containing polyhydroxy fatty acid amide and alkyl ester sulfonate surfactants |
US5174927A (en) * | 1990-09-28 | 1992-12-29 | The Procter & Gamble Company | Process for preparing brightener-containing liquid detergent compositions with polyhydroxy fatty acid amines |
US5194639A (en) * | 1990-09-28 | 1993-03-16 | The Procter & Gamble Company | Preparation of polyhydroxy fatty acid amides in the presence of solvents |
US5332528A (en) * | 1990-09-28 | 1994-07-26 | The Procter & Gamble Company | Polyhydroxy fatty acid amides in soil release agent-containing detergent compositions |
US5338487A (en) * | 1990-09-28 | 1994-08-16 | The Procter & Gamble Company | Catalyzed process for glucamide detergents |
US5338486A (en) * | 1990-09-28 | 1994-08-16 | The Procter & Gamble Company | High catalyst process for glucamide detergents |
US5700771A (en) * | 1990-09-28 | 1997-12-23 | The Procter & Gamble Company | Polyhydroxy fatty acid amide surfactants in percarbonate bleach-containing compositions |
US5380891A (en) * | 1990-09-28 | 1995-01-10 | The Procter & Gamble Company | Phase transfer assisted process for glucamide detergents |
US5254281A (en) * | 1991-01-29 | 1993-10-19 | The Procter & Gamble Company | Soap bars with polyhydroxy fatty acid amides |
US5625098A (en) * | 1991-07-26 | 1997-04-29 | The Procter & Gamble Company | Process for preparing N-alkyl polyhydroxyalkyl amines in aqueous/hydroxy solvents |
US5449770A (en) * | 1992-01-14 | 1995-09-12 | The Procter & Gamble Company | Process for making N-alkylamino polyols |
US5354425A (en) * | 1993-12-13 | 1994-10-11 | The Procter & Gamble Company | Tissue paper treated with polyhydroxy fatty acid amide softener systems that are biodegradable |
US5723673A (en) * | 1995-06-07 | 1998-03-03 | The Procter & Gamble Company | Process for preparing amides of N-alkyl polyhydroxyalkyls |
US5777165A (en) * | 1995-06-07 | 1998-07-07 | The Procter & Gamble Company | Process for preparing amides of N-alkyl polyhydroxyalkyl amines |
PL422564A1 (en) * | 2017-08-17 | 2019-02-25 | Zachodniopomorski Uniwersytet Technologiczny W Szczecinie | Method for obtaining surface active compounds from the group of N-alkanoyl-N-methylglucamines |
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