GB765607A - Benzilic acid esters and the preparation thereof - Google Patents
Benzilic acid esters and the preparation thereofInfo
- Publication number
- GB765607A GB765607A GB3512954A GB3512954A GB765607A GB 765607 A GB765607 A GB 765607A GB 3512954 A GB3512954 A GB 3512954A GB 3512954 A GB3512954 A GB 3512954A GB 765607 A GB765607 A GB 765607A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acids
- benzilic acid
- preparation
- acid esters
- salts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
- C07D211/04—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D211/06—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members
- C07D211/36—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D211/40—Oxygen atoms
- C07D211/44—Oxygen atoms attached in position 4
- C07D211/46—Oxygen atoms attached in position 4 having a hydrogen atom as the second substituent in position 4
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Hydrogenated Pyridines (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
The invention comprises benzilic acid esters of the general formula: <FORM:0765607/IV(b)/1> and acid addition salts thereof, where R represents an alkyl radical containing up to 4 carbon atoms, and the preparation thereof by reacting benzilic acid or a lower alkyl ester thereof with a compound of the formula: <FORM:0765607/IV(b)/2> wherein R has the above significance. Suitable acids from which the salts may be derived are inorganic acids such as hydrohalic, phosphoric, sulphuric and amidosulphonic acids, and organic acids such as oxalic, acetic, lactic, succinic, maleic, malic, tartaric, salicylic, citric, 2-hydroxyethane sulphonic, aceturic and ethylene diamine tetra-acetic acids. In the examples the N-methyl- and N-ethyl-piperidyl-(4) ester of benzilic acid and the hydrochloride salts thereof are prepared.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB3512954A GB765607A (en) | 1954-12-03 | 1954-12-03 | Benzilic acid esters and the preparation thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB3512954A GB765607A (en) | 1954-12-03 | 1954-12-03 | Benzilic acid esters and the preparation thereof |
Publications (1)
Publication Number | Publication Date |
---|---|
GB765607A true GB765607A (en) | 1957-01-09 |
Family
ID=10374174
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB3512954A Expired GB765607A (en) | 1954-12-03 | 1954-12-03 | Benzilic acid esters and the preparation thereof |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB765607A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3051726A (en) * | 1959-09-15 | 1962-08-28 | Lakeside Lab Inc | Glycolic acid esters of n-substituted-2-pyrrolidylcarbinols |
-
1954
- 1954-12-03 GB GB3512954A patent/GB765607A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3051726A (en) * | 1959-09-15 | 1962-08-28 | Lakeside Lab Inc | Glycolic acid esters of n-substituted-2-pyrrolidylcarbinols |
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