GB749456A - Improvements in or relating to synthetic fibres - Google Patents

Improvements in or relating to synthetic fibres

Info

Publication number
GB749456A
GB749456A GB1410653A GB1410653A GB749456A GB 749456 A GB749456 A GB 749456A GB 1410653 A GB1410653 A GB 1410653A GB 1410653 A GB1410653 A GB 1410653A GB 749456 A GB749456 A GB 749456A
Authority
GB
United Kingdom
Prior art keywords
sulphur trioxide
secs
vapour
aqueous solution
dyed
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1410653A
Inventor
Henry Malcolm Hutchinson
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Distillers Co Yeast Ltd
Distillers Co Ltd
Original Assignee
Distillers Co Yeast Ltd
Distillers Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Distillers Co Yeast Ltd, Distillers Co Ltd filed Critical Distillers Co Yeast Ltd
Priority to GB1410653A priority Critical patent/GB749456A/en
Priority to FR1100701D priority patent/FR1100701A/en
Priority to DED17793A priority patent/DE970581C/en
Publication of GB749456A publication Critical patent/GB749456A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/12—Chemical modification
    • C08J7/14—Chemical modification with acids, their salts or anhydrides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/51—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
    • D06M11/54—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with sulfur dioxide; with sulfurous acid or its salts
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/51—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
    • D06M11/55—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with sulfur trioxide; with sulfuric acid or thiosulfuric acid or their salts
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/673—Inorganic compounds
    • D06P1/67316—Acids
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/34—Material containing ester groups
    • D06P3/52—Polyesters
    • D06P3/522—Polyesters using basic dyes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/22—Effecting variation of dye affinity on textile material by chemical means that react with the fibre
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
    • C08J2367/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds

Landscapes

  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Coloring (AREA)

Abstract

Filaments, films and the like of aromatic linear polyesters are treated with the vapour of sulphuric acid, sulphur trioxide or chlorsulphonic acid. The treatment renders the material more hydrophilic, whereby its dyeing properties are improved and it becomes less liable to accumulate electrostatic charges. The treated material is particularly susceptible to basic dyes in aqueous solution, such as Malachite Green, Methylene Blue and Bismark Brown, and can also be dyed more readily with mordant dyes such as aluminium, iron and chromium mordant dyes. In an example a woven fabric of material sold under the Registered Trade Mark " Terylene " is exposed to the vapour of fuming sulphuric acid at a concentration equivalent to 0.11 gms. sulphur trioxide per litre for 30 secs. at 20-21 DEG C. and washed. After immersion in a 0.5 per cent aqueous solution of Methylene Blue for 10 mins. at 20 DEG C., the material is dyed deep blue, fast to boiling water. Further examples describe different concentrations of sulphur trioxide and different times and temperatures, but conditions preferred are 0.01 to 0.5 gms. sulphur trioxide per litre for 1-60 secs. at 15-25 DEG C.ALSO:Filaments and the like of aromatic linear polyesters are treated with the vapour of sulphuric acid, sulphur trioxide or chlorsulphonic acid. The treatment renders the material more hydrophilic, whereby its dyeing properties are improved and it becomes less liable to accumulate electrostatic charges. The treated material is particularly susceptible to basic dyes in aqueous solution, such as Malachite Green, Methylene Blue and Bismark Brown, and can also be dyed more readily with mordant dyes such as aluminium, iron and chromium mordant dyes. In an example a woven fabric of material sold under the Registered Trade Mark "Terylene" is exposed to the vapour of fuming sulphuric acid at a concentration equivalent to 0.11 gm.s sulphur trioxide per litre for 30 secs. at 20-21 DEG C. and washed. After immersion in a 0.5 per cent aqueous solution of Methylene Blue for 10 minutes at 20 DEG C. the material is dyed deep blue, fast to boiling water. Further examples describe different concentrations of sulphur trioxide and different times and temperatures, but conditions preferred are 0.01 to 0.5 gms. sulphur trioxide per litre for 1-60 secs. at 15-25 DEG C.
GB1410653A 1953-05-20 1953-05-20 Improvements in or relating to synthetic fibres Expired GB749456A (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
GB1410653A GB749456A (en) 1953-05-20 1953-05-20 Improvements in or relating to synthetic fibres
FR1100701D FR1100701A (en) 1953-05-20 1954-05-17 Improvements in synthetic fibers
DED17793A DE970581C (en) 1953-05-20 1954-05-20 Process for improving the hydrophilic properties of articles made of aromatic, unbranched polyesters

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB1410653A GB749456A (en) 1953-05-20 1953-05-20 Improvements in or relating to synthetic fibres

Publications (1)

Publication Number Publication Date
GB749456A true GB749456A (en) 1956-05-23

Family

ID=10035090

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1410653A Expired GB749456A (en) 1953-05-20 1953-05-20 Improvements in or relating to synthetic fibres

Country Status (3)

Country Link
DE (1) DE970581C (en)
FR (1) FR1100701A (en)
GB (1) GB749456A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3460896A (en) * 1964-10-14 1969-08-12 Eastman Kodak Co Polyester fibers having improved hydrophilicity as a result of modification with phosphoric acid,phosphorous acid or perchloric acid
CN104790201A (en) * 2015-04-14 2015-07-22 西南大学 Nitration reduction method capable of endowing dacron with high hydrophilia and reactive groups

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1068008B (en) * 1958-02-26 1959-10-29 Kalk &. Co. Aktiengesellschaft, Wiesbaden-Biebrich Process for increasing the adhesion of sheet-like structures made from polyterephthalic acid glycol esters
DE1794397C2 (en) * 1968-06-29 1978-03-30 Monsanto Co., St. Louis, Mo. (V.St.A.) Process for reducing the titer of segmented polyurethane elastomer threads while increasing their strength
US3684554A (en) * 1969-06-02 1972-08-15 Dow Chemical Co Method for the vapor phase surface sulfonation of plastic webs
DE2246107A1 (en) * 1972-09-20 1974-03-28 Bayer Ag SULPHIC ACID GROUP-CONTAINING POLYESTERS

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB683218A (en) * 1950-02-23 1952-11-26 Calico Printers Ass Ltd Improvements relating to the processing of linear polyester materials

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3460896A (en) * 1964-10-14 1969-08-12 Eastman Kodak Co Polyester fibers having improved hydrophilicity as a result of modification with phosphoric acid,phosphorous acid or perchloric acid
CN104790201A (en) * 2015-04-14 2015-07-22 西南大学 Nitration reduction method capable of endowing dacron with high hydrophilia and reactive groups
CN104790201B (en) * 2015-04-14 2017-03-01 西南大学 A kind of endowing terylene fabric high-hydrophilic and can reactive group nitrification method of reducing

Also Published As

Publication number Publication date
FR1100701A (en) 1955-09-23
DE970581C (en) 1958-10-09

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