GB743463A - Process for producing isopropyl esters - Google Patents
Process for producing isopropyl estersInfo
- Publication number
- GB743463A GB743463A GB33663/53A GB3366353A GB743463A GB 743463 A GB743463 A GB 743463A GB 33663/53 A GB33663/53 A GB 33663/53A GB 3366353 A GB3366353 A GB 3366353A GB 743463 A GB743463 A GB 743463A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acid
- reaction mixture
- per cent
- weight
- isopropyl ester
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 239000002253 acid Substances 0.000 abstract 8
- 125000001931 aliphatic group Chemical group 0.000 abstract 5
- 239000011541 reaction mixture Substances 0.000 abstract 5
- -1 isopropyl ester Chemical class 0.000 abstract 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 abstract 3
- 229910052500 inorganic mineral Inorganic materials 0.000 abstract 3
- 239000011707 mineral Substances 0.000 abstract 3
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 abstract 2
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 abstract 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract 1
- OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 238000010924 continuous production Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000001117 sulphuric acid Substances 0.000 abstract 1
- 235000011149 sulphuric acid Nutrition 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
- C07C69/22—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen having three or more carbon atoms in the acid moiety
- C07C69/24—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen having three or more carbon atoms in the acid moiety esterified with monohydroxylic compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
- C07C69/22—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen having three or more carbon atoms in the acid moiety
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
An isopropyl ester of an aliphatic acid containing from 2 to 8 carbon atoms is produced by a continuous process comprising maintaining at a temperature of from 60 DEG to 80 DEG C. a reaction mixture having the following composition :-strong mineral acid 15-30 per cent by weight, aliphatic acid 5-30 per cent by weight, the isopropyl ester of the aliphatic acid 5-10 per cent by weight, water 0.5-11 per cent by weight, the remainder being an isopropyl ester of the mineral acid, feeding the reaction mixture with the aliphatic acid at a rate sufficient to maintain the proportion thereof within the range stated above, continuously passing a gas containing at least 30 per cent by volume of propylene through the reaction mixture at a rate of from 2 to 5 cubic metres of gas per hour per kilogram of the reaction mixture, thereby providing an excess of propylene-containing gas sufficient to remove from the reaction mixture the isopropyl ester of the aliphatic acid as rapidly as it is produced. The preferred mineral acid is sulphuric acid. In the examples the isopropyl esters of (a) acetic acid, (b) butyric acid, and (c) octanoic acid are prepared by the process of the invention. U.S.A. Specification 2,079,652 is referred to.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR1068204T | 1952-12-05 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB743463A true GB743463A (en) | 1956-01-18 |
Family
ID=9603580
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB33663/53A Expired GB743463A (en) | 1952-12-05 | 1953-12-03 | Process for producing isopropyl esters |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US2740800A (en) |
| BE (1) | BE524866A (en) |
| DE (1) | DE949823C (en) |
| FR (1) | FR1068204A (en) |
| GB (1) | GB743463A (en) |
| NL (1) | NL87452C (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5384426A (en) * | 1992-12-08 | 1995-01-24 | Daicel Chemical Industries, Ltd. | Process for the preparation of isopropyl acetate |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2079652A (en) * | 1934-03-09 | 1937-05-11 | Socony Vacuum Oil Co Inc | Manufacture of esters from olefines |
-
1952
- 1952-12-05 FR FR1068204D patent/FR1068204A/en not_active Expired
-
1953
- 1953-05-18 US US355724A patent/US2740800A/en not_active Expired - Lifetime
- 1953-11-10 DE DEU2477A patent/DE949823C/en not_active Expired
- 1953-12-03 GB GB33663/53A patent/GB743463A/en not_active Expired
- 1953-12-04 NL NL183348A patent/NL87452C/xx active
- 1953-12-05 BE BE524866A patent/BE524866A/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| BE524866A (en) | 1954-06-05 |
| FR1068204A (en) | 1954-06-23 |
| US2740800A (en) | 1956-04-03 |
| NL87452C (en) | 1958-02-15 |
| DE949823C (en) | 1956-09-27 |
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