GB738665A - Emulsifiable hydrocarbon oils and emulsions thereof - Google Patents

Emulsifiable hydrocarbon oils and emulsions thereof

Info

Publication number
GB738665A
GB738665A GB29660/52A GB2966052A GB738665A GB 738665 A GB738665 A GB 738665A GB 29660/52 A GB29660/52 A GB 29660/52A GB 2966052 A GB2966052 A GB 2966052A GB 738665 A GB738665 A GB 738665A
Authority
GB
United Kingdom
Prior art keywords
acid
ethylene oxide
esters
oleic
carbon atoms
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB29660/52A
Inventor
Maurice Elton
Philip Alan Winsor
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Refining and Marketing Co Ltd
Original Assignee
Shell Refining and Marketing Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Refining and Marketing Co Ltd filed Critical Shell Refining and Marketing Co Ltd
Priority to GB29660/52A priority Critical patent/GB738665A/en
Publication of GB738665A publication Critical patent/GB738665A/en
Expired legal-status Critical Current

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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M7/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made of other substances with subsequent freeing of the treated goods from the treating medium, e.g. swelling, e.g. polyolefins
    • C—CHEMISTRY; METALLURGY
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    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/02—Water
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    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C—CHEMISTRY; METALLURGY
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    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/102—Aliphatic fractions
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    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/104—Aromatic fractions
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    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/106—Naphthenic fractions
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    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/108—Residual fractions, e.g. bright stocks
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    • C10M2207/128—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids containing hydroxy groups; Ethers thereof
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/042—Metal salts thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/12—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions obtained by phosphorisation of organic compounds, e.g. with PxSy, PxSyHal or PxOy
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/46—Textile oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2070/00—Specific manufacturing methods for lubricant compositions
    • C10N2070/02—Concentrating of additives
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/40—Reduced friction resistance, lubricant properties; Sizing compositions

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical And Physical Treatments For Wood And The Like (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

Emulsifiable oil compositions comprise a major proportion of a mineral lubricating oil and minor proportions of an oil-soluble naphthasulphonate, a fatty acid containing at least 10 carbon atoms and a water-soluble non-ionogenic emulsifier. The fatty acid may be saturated or unsaturated and may be substituted by hydroxyl groups or halogen atoms; examples are oleic acid, oleines containing oleic, palmitic, stearic and linoleic acids, and mixtures of fatty acids with abietic acid and its hydrogenated derivatives such as are found in tall oil. The non-ionogenic emulsifier may be a compound obtained by reacting a water-insoluble compound containing an amino, hydroxyl or carboxylic acid group with polyethylene glycols or ethylene oxide and/or the corresponding propylene compounds. Examples are the polyoxyethylene esters of oleic, stearic or naphthenic acid containing 6-15 ethenoxy groups; the condensation product of oleyl alcohol with 6-15 molecules of ethylene oxide; condensation products of alkyl phenols containing at least 4 carbon atoms in the alkyl group with alkylene oxides or polyethylene glycols, for example the condensation product of p-isooctyl phenol with 10 moles ethylene oxide or of isohexyl phenol with 7 moles ethylene oxide; water-soluble partial esters of polyhydric alcohols such as the laurates, oleates, palmitates and stearates of anhydrosorbitols and ethylene oxide derivatives thereof, and the higher fatty acid partial esters of glycerol polyethers obtained by polymerizing glycerol; and compounds known under the names of Cithrol, Estax and Lissapol. Optional ingredients of the composition comprise solvents such as monohydric alcohols, e.g. butyl and amyl alcohols, cyclohexanol, diacetone alcohol, phenols, glycols, e.g. hexylene glycol and polyethylene glycol, and glycol monoethers such as ethylene glycol ethyl or butyl ether; additional surface-active agents such as glyceryl mono- or di-oleate, glyceryl mono- or di-stearate, diglycol laurate, alkali metal salts of sulphuric acid esters of higher primary and secondary alcohols and alkali metal salts of alkyl aryl sulphonates; anti-oxidants such as alpha- and beta-naphthylamine, 2,4-dimethyl-6-tertiary butyl phenol, N-butyl p-phenylene diamine, tetramethyl diaminodiphenyl methane and petroleum alkyl phenols; anti-foaming agents such as silicones and dispersions of N,N1-distearyl ethylene diamine or N,N1-distearyl hexamethylene diamine in mineral oil; corrosion inhibitors such as primary amines containing 6-18 carbon atoms, e.g. octylamine and octadecylamine and heterocyclic nitrogen compounds such as alkyl substituted oxazolines and fatty acid salts thereof; extreme pressure agents such as phosphorus esters, neutral aromatic sulphur or selenium compounds, sulphurized fatty oils, sulphurized esters, sulphurized long chain olefins, sulphurized phosphorized fatty oils, acids or esters and chlorinated hydrocarbons; and pesticides such as salicylanilide, 4,41-dichlorodiphenyl-1,1,11-trichloroethane, the gamma isomer of benzene hexachloride, dinitrophenols such as 2,4-dinitro-orthocresol, diphenyl sulphone, pyrethrins, alpha-naphthalene acetic acid, 2,4-dichlorophenoxy acetic acid, 2,4,5-trichlorophenoxy acetic acid, pentachlorophenol, isopropyl n-phenyl carbamate, aliphatic amines containing at least 8 carbon atoms, amines derived from paraffin wax and naphthenylamines, and products sold under the Trade names Toxaphene, Aldrin and Dieldrin; and polyethylene glycol as a stabilizer. Proscouring agents for textile oils such as the alkylolamines, such as the ethanolamines and propanolamines, trimethylolaminomethane and diglycerylamine may also be added, either as the free bases or as the salt with acids such as phosphoric, acetic, oleic, palmitic or stearic acids. The words "Estox" and "Lissapol" are Registered Trade Marks.ALSO:Emulsifiable oil compositions which, as aqueous emulsions, may be used as horticultural oils comprise a major proportion of a mineral lubricating oil and minor proportions of an oil-soluble naphthasulphonate, a fatty acid containing at least 10 carbon atoms and a water-soluble non-ionogenic emulsifier. The fatty acid may be saturated or unsaturated and may be substituted by hydroxyl groups or halogen atoms; examples are oleic acid, oleines containing oleic, palmitic, stearic and linoleic acids, and mixtures of fatty acids with abietic acid and its hydrogenated derivatives such as are found in tall oil. The non-ionogenic emulsifier may be a compound obtained by reacting a water-insoluble compound containing an amino, hydroxyl or carboxylic acid group with polyethylene glycols or ethylene oxide and/or the corresponding propylene compounds. Examples are the polyoxyethylene esters of oleic, stearic or naphthenic acid containing 6-15 ethenoxy groups; the condensation product of oleyl alcohol with 6-15 molecules of ethylene oxide; condensation products of alkyl phenols containing at least 4 carbon atoms in the alkyl group with alkylene oxides or polyethylene glycols, for example the condensation product of p-isooctyl phenol with 10 moles ethylene oxide or of isohexyl phenol with 7 moles ethylene oxide; water-soluble partial esters of polyhydric alcohols such as the laurates, oleates, palmitates and stearates of anhydrosorbitols and ethylene oxide derivatives thereof, and the higher fatty acid partial esters of glycerol polyethers obtained by polymerizing glycerol. Optional ingredients of the composition comprise solvents such as monohydric alcohols, e.g. butyl and amyl alcohols, cyclohexanol, diacetone alcohol, phenols, glycols, e.g. hexylene glycol and polyethylene glycol, and glycol monoethers such as ethylene glycol ethyl or butyl ether; additional surface-active agents such as glyceryl mono or dioleate, glyceryl mono or di-stearate, diglycol laurate, alkali metal salts of sulphuric acid esters of higher primary and secondary alcohols and alkali metal salts of alkyl aryl sulphonates; and pesticides such as salicylanilide, 4,41 - dichlorodiphenyl, 1,1,1 - trichloroethane, the gamma isomer of benzene hexachloride, dinitrophenols such as 2,4-dinitro-orthocresol, diphenyl sulphone, pyrethrins, alpha-naphthalene acetic acid, 2,4-dichloro-phenoxy acetic acid, 2,4,5-trichlorophenoxy acetic acid, pentachlorophenol, isopropyl n-phenyl carbamate, aliphatic amines containing at least 8 carbon atoms, amines derived from paraffin wax and naphthenylamines, and products sold under the Trade names " Toxaphene, " " Aldrin, " and " Dieldrin "; and polyethylene glycol as a stabilizer.
GB29660/52A 1952-11-24 1952-11-24 Emulsifiable hydrocarbon oils and emulsions thereof Expired GB738665A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB29660/52A GB738665A (en) 1952-11-24 1952-11-24 Emulsifiable hydrocarbon oils and emulsions thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB29660/52A GB738665A (en) 1952-11-24 1952-11-24 Emulsifiable hydrocarbon oils and emulsions thereof

Publications (1)

Publication Number Publication Date
GB738665A true GB738665A (en) 1955-10-19

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
GB29660/52A Expired GB738665A (en) 1952-11-24 1952-11-24 Emulsifiable hydrocarbon oils and emulsions thereof

Country Status (1)

Country Link
GB (1) GB738665A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0357957A2 (en) * 1988-08-10 1990-03-14 Teijin Limited Treatment of fibres with acaricides
CN108914104A (en) * 2018-06-25 2018-11-30 杨飞 A kind of octadecylamine shutdown protection solution and preparation method thereof
CN109985565A (en) * 2017-12-29 2019-07-09 中国石油化工股份有限公司 The mixed system and preparation method thereof of fatty acid type surfactant

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0357957A2 (en) * 1988-08-10 1990-03-14 Teijin Limited Treatment of fibres with acaricides
EP0357957A3 (en) * 1988-08-10 1992-01-02 Teijin Limited Treatment of fibres with acaricides
US5312688A (en) * 1988-08-10 1994-05-17 Teijin Limited Acaricide fiber material and process for producing same
CN109985565A (en) * 2017-12-29 2019-07-09 中国石油化工股份有限公司 The mixed system and preparation method thereof of fatty acid type surfactant
CN109985565B (en) * 2017-12-29 2021-07-02 中国石油化工股份有限公司 Mixed system containing fatty acid type surfactant and preparation method thereof
CN108914104A (en) * 2018-06-25 2018-11-30 杨飞 A kind of octadecylamine shutdown protection solution and preparation method thereof

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