GB736886A - Improvements in and relating to thickened lubricating oil compositions - Google Patents

Improvements in and relating to thickened lubricating oil compositions

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Publication number
GB736886A
GB736886A GB5755/53A GB575553A GB736886A GB 736886 A GB736886 A GB 736886A GB 5755/53 A GB5755/53 A GB 5755/53A GB 575553 A GB575553 A GB 575553A GB 736886 A GB736886 A GB 736886A
Authority
GB
United Kingdom
Prior art keywords
lubricating oil
mixtures
lubricating
ethyl
ethers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB5755/53A
Inventor
John Bryant Matthews
Sydney Dawtrey
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Refining and Marketing Co Ltd
Original Assignee
Shell Refining and Marketing Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to BE526855D priority Critical patent/BE526855A/xx
Application filed by Shell Refining and Marketing Co Ltd filed Critical Shell Refining and Marketing Co Ltd
Priority to GB5755/53A priority patent/GB736886A/en
Priority to DES37897A priority patent/DE947729C/en
Priority to FR1096775D priority patent/FR1096775A/en
Publication of GB736886A publication Critical patent/GB736886A/en
Expired legal-status Critical Current

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    • C10M5/00Solid or semi-solid compositions containing as the essential lubricating ingredient mineral lubricating oils or fatty oils and their use
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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

A lubricating grease or thickened lubricating oil is prepared by mixing a hydrogel of an inorganic colloid with a lubricating oil and such a quantity of a mutual solvent for the lubricating oil and water that a homogeneous liquid phase can be obtained when the mixture is heated, if necessary under pressure, subjecting the mixture to such conditions of temperature and pressure that a homogeneous liquid phase is obtained and distilling off the water and, if desired, the mutual solvent, while maintaining the liquid phase homogeneous. Suitable inorganic colloids are natural or synthetic clays, particularly montmorillonites such as hectorite or Wyoming bentonite, and various metallic oxides, hydroxides, sulphides, silicates, sulphates and chlorides or mixtures of these. Silica or alkaline earth metal hydroxides or mixtures of these may be employed. The lubricating oil may be mineral oil, particularly bright stock, or other lubricating oils, or mixtures of these. Synthetic lubricating oils mentioned are esters of phosphorus acids (e.g. trioctyl phosphate), di(2-ethylhexyl)hexane-phosphonate and bis - 1,3 - (dioctyl(phosphono)butane), esters of aliphatic dicarboxylic acids (e.g. bis(2-ethyl-hexyl)sebacate and bis (iso-octyl) adipate), polymeric oxyalkylene compounds (e.g. polypropylene oxide and copolymers of propylene oxide with ethylene oxide), polymers of glycols (e.g. polymers of trimethylene glycol) and organo-silicon compounds (e.g. liquid polymethylphenyl siloxanes and polymethyl siloxanes). Examples of mutual solvents are alcohols (e.g. ethyl, propyl, butyl and amyl alcohols, diacetone alcohol, cyclohexanol and methylcyclohexanol), ketones (e.g. diethyl, methyl ethyl, methyl isobutyl, di-isobutyl and dihexyl ketones), ethers (e.g. di-isopropyl, methyl tert.-butyl, methyl tert.-amyl, dihexyl, dioctyl and diphenyl ethers and dioxane), esters (e.g. ethyl acetate, isobutyrate and acetoacetate and methyl propionate), diols (e.g. propylene, butylene and hexylene glycols, and diglycols such as dipropylene and dibutylene glycols), glycol monoalkyl ethers, glycerol mono- or di-alkyl ethers, phenol, cresols, amines (e.g. alkanolamines) and heterocyclic bases (e.g. pyridine and morpholine). Mixtures of mutual solvents may be employed. The lubricating oil composition may contain a surface-active agent introduced at any desired stage of the process and examples of suitable anionic and cationic surface-active agents are given. When distilling off the water, not all of the water need be removed. The final product may be milled or sheared to impart a lubricating grease structure. In the examples the hydrogel is silica, alumina, or silica-magnesia; the lubricating oil is di-(2-ethylhexyl) sebacate or medicinal paraffin; the mutual solvent is isopropyl alcohol; and the surface-active agent employed in one case is made by condensing epichlorhydrin with aqueous ammonia and converting the product into a partial amide by reaction with an amount of commercial stearic acid equivallent to one third of its basicity. Phenyl-betanaphthylamine is added in one example to act as antioxidant.
GB5755/53A 1953-03-02 1953-03-02 Improvements in and relating to thickened lubricating oil compositions Expired GB736886A (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
BE526855D BE526855A (en) 1953-03-02
GB5755/53A GB736886A (en) 1953-03-02 1953-03-02 Improvements in and relating to thickened lubricating oil compositions
DES37897A DE947729C (en) 1953-03-02 1954-02-28 Process for the production of thickened lubricating oils and greases
FR1096775D FR1096775A (en) 1953-03-02 1954-03-01 Thickened lubricating oil composition

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB5755/53A GB736886A (en) 1953-03-02 1953-03-02 Improvements in and relating to thickened lubricating oil compositions

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GB736886A true GB736886A (en) 1955-09-14

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GB5755/53A Expired GB736886A (en) 1953-03-02 1953-03-02 Improvements in and relating to thickened lubricating oil compositions

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BE (1) BE526855A (en)
DE (1) DE947729C (en)
FR (1) FR1096775A (en)
GB (1) GB736886A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9149785B2 (en) 2009-07-23 2015-10-06 Clariant Production (France) S.A.S. Hydrated humidity control substance and process for its preparation

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE553337A (en) * 1955-12-12
NL239497A (en) * 1958-05-27
NL133424C (en) * 1960-05-12
JPS61272291A (en) * 1985-05-28 1986-12-02 Japan Atom Energy Res Inst Radiation-resistant grease

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Publication number Priority date Publication date Assignee Title
GB672651A (en) * 1947-10-28 1952-05-21 Bataafsche Petroleum Improvements in or relating to thickened oleaginous compositions
US2599683A (en) * 1949-05-03 1952-06-10 Shell Dev Grease composition
BE500080A (en) * 1949-12-19
IT480975A (en) * 1950-06-24

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9149785B2 (en) 2009-07-23 2015-10-06 Clariant Production (France) S.A.S. Hydrated humidity control substance and process for its preparation

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DE947729C (en) 1956-08-23
BE526855A (en)
FR1096775A (en) 1955-06-24

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