GB709684A - Improvements in or relating to the oxidation of cellulose - Google Patents
Improvements in or relating to the oxidation of celluloseInfo
- Publication number
- GB709684A GB709684A GB21787/52A GB2178752A GB709684A GB 709684 A GB709684 A GB 709684A GB 21787/52 A GB21787/52 A GB 21787/52A GB 2178752 A GB2178752 A GB 2178752A GB 709684 A GB709684 A GB 709684A
- Authority
- GB
- United Kingdom
- Prior art keywords
- cellulose
- mixture
- acid
- employed
- per cent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B15/00—Preparation of other cellulose derivatives or modified cellulose, e.g. complexes
- C08B15/02—Oxycellulose; Hydrocellulose; Cellulosehydrate, e.g. microcrystalline cellulose
- C08B15/04—Carboxycellulose, e.g. prepared by oxidation with nitrogen dioxide
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Biochemistry (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
Abstract
Oxidation products of cellulose containing carboxyl groups are obtained by treating cellulose with a mixture containing aqueous nitric acid of a strength of 50-70 per cent. by weight and 3 to 25 per cent. by volume of concentrated sulphuric acid, the mixture also containing an alkali-metal nitrite. The cellulose, e.g. cotton linters, wood-cellulose, regenerated cellulose, cotton fibres, threads or fabrics, linen or paper, is impregnated, sprayed or kneaded with the mixture at room temperature up to 40 DEG C., the product being finally freed from acid, washed and dried, e.g. at 50 DEG -60 DEG C. The product is soluble in dilute alkaline liquids, and may be employed as a dispersing agent, an absorbable surgical dressing or an ion-exchange material, and in the form of a salt it may be employed to increase the dirt-carrying capacity of fatty acid soaps and synthetic washing agents. The products have a great affinity for basic dyestuffs.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL709684X | 1951-09-21 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB709684A true GB709684A (en) | 1954-06-02 |
Family
ID=19812168
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB21787/52A Expired GB709684A (en) | 1951-09-21 | 1952-08-29 | Improvements in or relating to the oxidation of cellulose |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB709684A (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL9301172A (en) * | 1993-07-05 | 1995-02-01 | Tno | Method for oxidizing carbohydrates. |
US6372718B2 (en) | 1997-01-30 | 2002-04-16 | Alpenstock Holdings Limited | Composition containing stable microdispersed polyanhydroglucuronic acids and salts thereof |
EP1251140A1 (en) * | 2001-04-20 | 2002-10-23 | SCA Hygiene Products Zeist B.V. | Process for oxidising primary hydroxyls in carbohydrates |
CZ301410B6 (en) * | 1998-07-21 | 2010-02-17 | Alpenstock Holdings Limited | Biocompatible, intermolecular polymer complex, compositions and preparations containing thereof |
WO2010086616A1 (en) | 2009-01-30 | 2010-08-05 | Hemcon Medical Technologies (Ip) Ltd | Micronized oxidized cellulose salt |
US8445671B2 (en) | 2005-09-02 | 2013-05-21 | Alltracel Development Services Limited | Method for preparing polyanhydroglucuronic acid and/or salts thereof |
-
1952
- 1952-08-29 GB GB21787/52A patent/GB709684A/en not_active Expired
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL9301172A (en) * | 1993-07-05 | 1995-02-01 | Tno | Method for oxidizing carbohydrates. |
US6372718B2 (en) | 1997-01-30 | 2002-04-16 | Alpenstock Holdings Limited | Composition containing stable microdispersed polyanhydroglucuronic acids and salts thereof |
CZ301410B6 (en) * | 1998-07-21 | 2010-02-17 | Alpenstock Holdings Limited | Biocompatible, intermolecular polymer complex, compositions and preparations containing thereof |
EP1251140A1 (en) * | 2001-04-20 | 2002-10-23 | SCA Hygiene Products Zeist B.V. | Process for oxidising primary hydroxyls in carbohydrates |
US8445671B2 (en) | 2005-09-02 | 2013-05-21 | Alltracel Development Services Limited | Method for preparing polyanhydroglucuronic acid and/or salts thereof |
WO2010086616A1 (en) | 2009-01-30 | 2010-08-05 | Hemcon Medical Technologies (Ip) Ltd | Micronized oxidized cellulose salt |
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