GB709684A - Improvements in or relating to the oxidation of cellulose - Google Patents

Improvements in or relating to the oxidation of cellulose

Info

Publication number
GB709684A
GB709684A GB21787/52A GB2178752A GB709684A GB 709684 A GB709684 A GB 709684A GB 21787/52 A GB21787/52 A GB 21787/52A GB 2178752 A GB2178752 A GB 2178752A GB 709684 A GB709684 A GB 709684A
Authority
GB
United Kingdom
Prior art keywords
cellulose
mixture
acid
employed
per cent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB21787/52A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nyma Kunstzijdespinnerij Nv
Original Assignee
Nyma Kunstzijdespinnerij Nv
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nyma Kunstzijdespinnerij Nv filed Critical Nyma Kunstzijdespinnerij Nv
Publication of GB709684A publication Critical patent/GB709684A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08BPOLYSACCHARIDES; DERIVATIVES THEREOF
    • C08B15/00Preparation of other cellulose derivatives or modified cellulose, e.g. complexes
    • C08B15/02Oxycellulose; Hydrocellulose; Cellulosehydrate, e.g. microcrystalline cellulose
    • C08B15/04Carboxycellulose, e.g. prepared by oxidation with nitrogen dioxide

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Biochemistry (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polysaccharides And Polysaccharide Derivatives (AREA)

Abstract

Oxidation products of cellulose containing carboxyl groups are obtained by treating cellulose with a mixture containing aqueous nitric acid of a strength of 50-70 per cent. by weight and 3 to 25 per cent. by volume of concentrated sulphuric acid, the mixture also containing an alkali-metal nitrite. The cellulose, e.g. cotton linters, wood-cellulose, regenerated cellulose, cotton fibres, threads or fabrics, linen or paper, is impregnated, sprayed or kneaded with the mixture at room temperature up to 40 DEG C., the product being finally freed from acid, washed and dried, e.g. at 50 DEG -60 DEG C. The product is soluble in dilute alkaline liquids, and may be employed as a dispersing agent, an absorbable surgical dressing or an ion-exchange material, and in the form of a salt it may be employed to increase the dirt-carrying capacity of fatty acid soaps and synthetic washing agents. The products have a great affinity for basic dyestuffs.
GB21787/52A 1951-09-21 1952-08-29 Improvements in or relating to the oxidation of cellulose Expired GB709684A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
NL709684X 1951-09-21

Publications (1)

Publication Number Publication Date
GB709684A true GB709684A (en) 1954-06-02

Family

ID=19812168

Family Applications (1)

Application Number Title Priority Date Filing Date
GB21787/52A Expired GB709684A (en) 1951-09-21 1952-08-29 Improvements in or relating to the oxidation of cellulose

Country Status (1)

Country Link
GB (1) GB709684A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL9301172A (en) * 1993-07-05 1995-02-01 Tno Method for oxidizing carbohydrates.
US6372718B2 (en) 1997-01-30 2002-04-16 Alpenstock Holdings Limited Composition containing stable microdispersed polyanhydroglucuronic acids and salts thereof
EP1251140A1 (en) * 2001-04-20 2002-10-23 SCA Hygiene Products Zeist B.V. Process for oxidising primary hydroxyls in carbohydrates
CZ301410B6 (en) * 1998-07-21 2010-02-17 Alpenstock Holdings Limited Biocompatible, intermolecular polymer complex, compositions and preparations containing thereof
WO2010086616A1 (en) 2009-01-30 2010-08-05 Hemcon Medical Technologies (Ip) Ltd Micronized oxidized cellulose salt
US8445671B2 (en) 2005-09-02 2013-05-21 Alltracel Development Services Limited Method for preparing polyanhydroglucuronic acid and/or salts thereof

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL9301172A (en) * 1993-07-05 1995-02-01 Tno Method for oxidizing carbohydrates.
US6372718B2 (en) 1997-01-30 2002-04-16 Alpenstock Holdings Limited Composition containing stable microdispersed polyanhydroglucuronic acids and salts thereof
CZ301410B6 (en) * 1998-07-21 2010-02-17 Alpenstock Holdings Limited Biocompatible, intermolecular polymer complex, compositions and preparations containing thereof
EP1251140A1 (en) * 2001-04-20 2002-10-23 SCA Hygiene Products Zeist B.V. Process for oxidising primary hydroxyls in carbohydrates
US8445671B2 (en) 2005-09-02 2013-05-21 Alltracel Development Services Limited Method for preparing polyanhydroglucuronic acid and/or salts thereof
WO2010086616A1 (en) 2009-01-30 2010-08-05 Hemcon Medical Technologies (Ip) Ltd Micronized oxidized cellulose salt

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