GB696404A - Improved process for the vulcanisation of natural rubber latices - Google Patents

Improved process for the vulcanisation of natural rubber latices

Info

Publication number
GB696404A
GB696404A GB26813/51A GB2681351A GB696404A GB 696404 A GB696404 A GB 696404A GB 26813/51 A GB26813/51 A GB 26813/51A GB 2681351 A GB2681351 A GB 2681351A GB 696404 A GB696404 A GB 696404A
Authority
GB
United Kingdom
Prior art keywords
zinc
dithiocarbamate
vulcanizing
latex
vulcanizing agents
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB26813/51A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GEA Group AG
Original Assignee
Metallgesellschaft AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Metallgesellschaft AG filed Critical Metallgesellschaft AG
Publication of GB696404A publication Critical patent/GB696404A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00Processes of treating or compounding macromolecular substances
    • C08J3/24Crosslinking, e.g. vulcanising, of macromolecules
    • C08J3/26Crosslinking, e.g. vulcanising, of macromolecules of latex
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2307/00Characterised by the use of natural rubber
    • C08J2307/02Latex

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)

Abstract

Natural rubber latex is vulcanized by adding to it vulcanizing agents in a quantity less than 1 per cent. by weight of the dry rubber content of the latex, and then vulcanizing. The vulcanizing agents may comprise sulphur, in the elementary form, or combined as polysulphides or dithiocarbamates and zinc oxide or similarly acting zinc compounds. After vulcanization, the latex may be used in the manufacture of balloons which may be printed by a stamping process. In Examples, the vulcanizing agent comprises two or more substances from colloidal sulphur, zinc dibutyl dithiocarbamate, the sodium salt of the condensation product of b -naphthalene sulphonic acid with formaldehyde; zinc oxide, tetramethyl thiuram disulphide, o-tolyl biguanide, zinc dimethyl dithiocarbamate, cyclohexylethylamine salt of cyclohexylethyl dithiocarbamic acid, zinc phenylethyl dithiocarbamate, piperidine salt of pentamethylene dithiocarbamic acid, zinc diethyl dithiocarbamate, dibutylamine, mercaptobenzthiazole and diorthotolylguanidine. After vulcanization, which may be effected at air temperature for some days, or at temperatures of 50 to 75 DEG C., unused vulcanizing agents may be removed by a centrifuge.
GB26813/51A 1950-11-25 1951-11-15 Improved process for the vulcanisation of natural rubber latices Expired GB696404A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEM7633A DE861924C (en) 1950-11-25 1950-11-25 Process for improving the properties of masses produced from vulcanized rubber milk

Publications (1)

Publication Number Publication Date
GB696404A true GB696404A (en) 1953-08-26

Family

ID=7293828

Family Applications (1)

Application Number Title Priority Date Filing Date
GB26813/51A Expired GB696404A (en) 1950-11-25 1951-11-15 Improved process for the vulcanisation of natural rubber latices

Country Status (2)

Country Link
DE (1) DE861924C (en)
GB (1) GB696404A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0514560A1 (en) * 1990-03-30 1992-11-25 Semperit Aktiengesellschaft Holding Process for prevulcanising naturel and synthetic rubber and process for producing rubber articles
CN115671401A (en) * 2022-10-31 2023-02-03 深圳市慧极创新医疗科技有限公司 Medical latex balloon

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0514560A1 (en) * 1990-03-30 1992-11-25 Semperit Aktiengesellschaft Holding Process for prevulcanising naturel and synthetic rubber and process for producing rubber articles
CN115671401A (en) * 2022-10-31 2023-02-03 深圳市慧极创新医疗科技有限公司 Medical latex balloon

Also Published As

Publication number Publication date
DE861924C (en) 1953-01-08

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