GB696031A - Improvements in or relating to the preparation of detergent compositions - Google Patents
Improvements in or relating to the preparation of detergent compositionsInfo
- Publication number
- GB696031A GB696031A GB702150A GB702150A GB696031A GB 696031 A GB696031 A GB 696031A GB 702150 A GB702150 A GB 702150A GB 702150 A GB702150 A GB 702150A GB 696031 A GB696031 A GB 696031A
- Authority
- GB
- United Kingdom
- Prior art keywords
- sodium
- tetramethylbutyl
- mixed
- pyrophosphate
- builder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title abstract 7
- 239000003599 detergent Substances 0.000 title abstract 3
- 239000007859 condensation product Substances 0.000 abstract 5
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical group CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 abstract 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 abstract 3
- 235000019820 disodium diphosphate Nutrition 0.000 abstract 3
- GYQBBRRVRKFJRG-UHFFFAOYSA-L disodium pyrophosphate Chemical compound [Na+].[Na+].OP([O-])(=O)OP(O)([O-])=O GYQBBRRVRKFJRG-UHFFFAOYSA-L 0.000 abstract 3
- 150000003839 salts Chemical class 0.000 abstract 3
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 abstract 3
- PMZURENOXWZQFD-UHFFFAOYSA-L sodium sulphate Substances [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 abstract 3
- 235000019818 tetrasodium diphosphate Nutrition 0.000 abstract 3
- 229920000742 Cotton Polymers 0.000 abstract 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 2
- -1 alkyl sulphates Chemical class 0.000 abstract 2
- 125000006353 oxyethylene group Chemical group 0.000 abstract 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 abstract 2
- 210000002268 wool Anatomy 0.000 abstract 2
- QWBBPBRQALCEIZ-UHFFFAOYSA-N 2,3-dimethylphenol Chemical compound CC1=CC=CC(O)=C1C QWBBPBRQALCEIZ-UHFFFAOYSA-N 0.000 abstract 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 abstract 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical group OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract 1
- 239000004115 Sodium Silicate Substances 0.000 abstract 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 abstract 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 230000002152 alkylating effect Effects 0.000 abstract 1
- 239000007844 bleaching agent Substances 0.000 abstract 1
- 239000000872 buffer Substances 0.000 abstract 1
- 239000000337 buffer salt Substances 0.000 abstract 1
- 239000007853 buffer solution Substances 0.000 abstract 1
- 239000004202 carbamide Substances 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 239000001768 carboxy methyl cellulose Substances 0.000 abstract 1
- 229930003836 cresol Chemical group 0.000 abstract 1
- 230000001236 detergent effect Effects 0.000 abstract 1
- 239000003085 diluting agent Substances 0.000 abstract 1
- XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical compound [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 abstract 1
- 235000011180 diphosphates Nutrition 0.000 abstract 1
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 abstract 1
- 125000001033 ether group Chemical group 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 230000003287 optical effect Effects 0.000 abstract 1
- 239000007800 oxidant agent Substances 0.000 abstract 1
- 150000002989 phenols Chemical class 0.000 abstract 1
- 229920000151 polyglycol Polymers 0.000 abstract 1
- 239000010695 polyglycol Substances 0.000 abstract 1
- 239000000047 product Substances 0.000 abstract 1
- 239000011734 sodium Substances 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- WBHQBSYUUJJSRZ-UHFFFAOYSA-M sodium bisulfate Chemical compound [Na+].OS([O-])(=O)=O WBHQBSYUUJJSRZ-UHFFFAOYSA-M 0.000 abstract 1
- 229910000029 sodium carbonate Inorganic materials 0.000 abstract 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 abstract 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 abstract 1
- 239000011780 sodium chloride Substances 0.000 abstract 1
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 abstract 1
- 229960001922 sodium perborate Drugs 0.000 abstract 1
- 229940045872 sodium percarbonate Drugs 0.000 abstract 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 abstract 1
- 229910052911 sodium silicate Inorganic materials 0.000 abstract 1
- 229910052938 sodium sulfate Inorganic materials 0.000 abstract 1
- 235000011152 sodium sulphate Nutrition 0.000 abstract 1
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 abstract 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
- 150000003739 xylenols Chemical group 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/06—Phosphates, including polyphosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
The condensation product of ethylene oxide with a phenol, cresol or xylenol substituted in the nucleus by one or more higher alkyl groups of at least 8 carbon atoms, the condensation product containing 8-16 oxyethylene groups, is mixed with 25-300 per cent of its own weight of disodium dihydrogen pyrophosphate and/or tetrasodium pyrophosphate and, if necessary, with an inorganic buffer, so that the final mixture has a pH of 6.5-8.5 on being diluted with 100 times its weight of water. The composition has detergent properties and may be used on cotton at or near the boil and on wool at 50 DEG C. Suitable phenols include p-1:1:3:3-tetramethylbutyl-o-cresol, 6-11:11:11:31-tetramethylbutyl-2:4 dimethylphenol, mixed p-tertiary-dodecylphenols, mixed p-tertiary-undecylphenols, mixed secondary-dodecyl cresylic acids, kerylphenol and 4:6-di-(11:11:31:31-tetramethylbutyl) -o-cresol. The builder preferably comprises substantially equal parts of tetrasodium pyrophosphate and disodium dihydrogen pyrophosphate. If the builder is alkaline, an acid buffer salt may be necessary in the composition, and may be chosen from salts such as sodium hydrogen sulphate, sodium dihydrogen orthophosphate and the corresponding water-soluble salts of metals other than sodium. When the builder is acid, alkaline buffer salts such as sodium orthophosphate, sodium carbonate and sodium silicate may be employed. Inert water-soluble diluents such as sodium sulphate, sodium chloride and urea may also be present. Other additional ingredients include secondary longchain alkyl sulphates and alkyl aryl sulphonates to improve the lathering properties, mild oxidising agents such as sodium percarbonate and sodium perborate, an "optical bleach" and sodium carboxymethyl cellulose. In the example the detergent effects on cotton at 90 DEG C and wool at 50 DEG C of ethylene oxide condensation products having differing numbers of polyglycol ether groups with and without the pyrophosphate builder are compared. The condensation products are prepared by alkylating ortho-rich cresylic acid with commercial isobutylene to produce tetramethylbutyl cresylic acid mixed with a little di-(tetramethylbutyl) cresylic acid, and this mixture is condensed with ethylene oxide to give products containing 6-18 oxyethylene groups. The detergent composition comprises 0.04 per cent by weight of the condensation product with and without the addition of 200 per cent by weight of the condensate of a 1:1 mixture of tetrasodium pyrophosphate and disodium dihydrogen pyrophosphate. Specification 696,032 is referred to.
Priority Applications (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| BE501441D BE501441A (en) | 1950-03-21 | ||
| BE501442D BE501442A (en) | 1950-03-21 | ||
| GB702250A GB696032A (en) | 1950-03-21 | 1950-03-21 | Improvements in or relating to detergent compositions |
| GB702150A GB696031A (en) | 1950-03-21 | 1950-03-21 | Improvements in or relating to the preparation of detergent compositions |
| FR1042742D FR1042742A (en) | 1950-03-21 | 1951-02-17 | Advanced detergent compositions |
| FR1033668D FR1033668A (en) | 1950-03-21 | 1951-02-17 | Improvements relating to the preparation of detergent compositions |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB702150A GB696031A (en) | 1950-03-21 | 1950-03-21 | Improvements in or relating to the preparation of detergent compositions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB696031A true GB696031A (en) | 1953-08-19 |
Family
ID=9825139
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB702250A Expired GB696032A (en) | 1950-03-21 | 1950-03-21 | Improvements in or relating to detergent compositions |
| GB702150A Expired GB696031A (en) | 1950-03-21 | 1950-03-21 | Improvements in or relating to the preparation of detergent compositions |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB702250A Expired GB696032A (en) | 1950-03-21 | 1950-03-21 | Improvements in or relating to detergent compositions |
Country Status (3)
| Country | Link |
|---|---|
| BE (2) | BE501442A (en) |
| FR (2) | FR1042742A (en) |
| GB (2) | GB696032A (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2182051A (en) * | 1985-09-10 | 1987-05-07 | Interox Chemicals Ltd | Stabilisation of peroxyacids in detergent compositions containing nonionic surfactant |
-
0
- BE BE501441D patent/BE501441A/xx unknown
- BE BE501442D patent/BE501442A/xx unknown
-
1950
- 1950-03-21 GB GB702250A patent/GB696032A/en not_active Expired
- 1950-03-21 GB GB702150A patent/GB696031A/en not_active Expired
-
1951
- 1951-02-17 FR FR1042742D patent/FR1042742A/en not_active Expired
- 1951-02-17 FR FR1033668D patent/FR1033668A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| BE501442A (en) | |
| BE501441A (en) | |
| FR1042742A (en) | 1953-11-03 |
| GB696032A (en) | 1953-08-19 |
| FR1033668A (en) | 1953-07-15 |
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