GB561294A - Improvements in detergent compositions and methods of producing the same - Google Patents
Improvements in detergent compositions and methods of producing the sameInfo
- Publication number
- GB561294A GB561294A GB7613/42A GB761342A GB561294A GB 561294 A GB561294 A GB 561294A GB 7613/42 A GB7613/42 A GB 7613/42A GB 761342 A GB761342 A GB 761342A GB 561294 A GB561294 A GB 561294A
- Authority
- GB
- United Kingdom
- Prior art keywords
- sodium
- borate material
- borate
- naoh
- compositions
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title abstract 8
- 239000003599 detergent Substances 0.000 title abstract 3
- 239000000463 material Substances 0.000 abstract 13
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract 12
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 abstract 11
- 239000004615 ingredient Substances 0.000 abstract 4
- 229910021538 borax Inorganic materials 0.000 abstract 3
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 abstract 3
- 239000004328 sodium tetraborate Substances 0.000 abstract 3
- 235000010339 sodium tetraborate Nutrition 0.000 abstract 3
- 239000004094 surface-active agent Substances 0.000 abstract 3
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 abstract 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 abstract 2
- -1 ceryl benzene sulphonate Chemical class 0.000 abstract 2
- 239000000344 soap Substances 0.000 abstract 2
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 abstract 2
- MOMKYJPSVWEWPM-UHFFFAOYSA-N 4-(chloromethyl)-2-(4-methylphenyl)-1,3-thiazole Chemical compound C1=CC(C)=CC=C1C1=NC(CCl)=CS1 MOMKYJPSVWEWPM-UHFFFAOYSA-N 0.000 abstract 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 abstract 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 abstract 1
- 229920001353 Dextrin Polymers 0.000 abstract 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract 1
- 239000004115 Sodium Silicate Substances 0.000 abstract 1
- 239000003513 alkali Substances 0.000 abstract 1
- 125000000129 anionic group Chemical group 0.000 abstract 1
- 239000011324 bead Substances 0.000 abstract 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 abstract 1
- 239000004327 boric acid Substances 0.000 abstract 1
- 229910052796 boron Inorganic materials 0.000 abstract 1
- 239000011575 calcium Substances 0.000 abstract 1
- 229910052791 calcium Inorganic materials 0.000 abstract 1
- 239000005018 casein Substances 0.000 abstract 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 abstract 1
- 235000021240 caseins Nutrition 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- FYGDTMLNYKFZSV-MRCIVHHJSA-N dextrin Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)OC1O[C@@H]1[C@@H](CO)OC(O[C@@H]2[C@H](O[C@H](O)[C@H](O)[C@H]2O)CO)[C@H](O)[C@H]1O FYGDTMLNYKFZSV-MRCIVHHJSA-N 0.000 abstract 1
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 abstract 1
- 238000001704 evaporation Methods 0.000 abstract 1
- 239000008187 granular material Substances 0.000 abstract 1
- 239000011777 magnesium Substances 0.000 abstract 1
- 229910052749 magnesium Inorganic materials 0.000 abstract 1
- 230000007935 neutral effect Effects 0.000 abstract 1
- 239000000843 powder Substances 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 230000009919 sequestration Effects 0.000 abstract 1
- 239000011734 sodium Substances 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- 239000011780 sodium chloride Substances 0.000 abstract 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 abstract 1
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 abstract 1
- 235000019982 sodium hexametaphosphate Nutrition 0.000 abstract 1
- NVIFVTYDZMXWGX-UHFFFAOYSA-N sodium metaborate Chemical compound [Na+].[O-]B=O NVIFVTYDZMXWGX-UHFFFAOYSA-N 0.000 abstract 1
- 235000019983 sodium metaphosphate Nutrition 0.000 abstract 1
- 235000019795 sodium metasilicate Nutrition 0.000 abstract 1
- 229910001948 sodium oxide Inorganic materials 0.000 abstract 1
- 159000000000 sodium salts Chemical class 0.000 abstract 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 abstract 1
- 229910052911 sodium silicate Inorganic materials 0.000 abstract 1
- 229910052938 sodium sulfate Inorganic materials 0.000 abstract 1
- 235000011152 sodium sulphate Nutrition 0.000 abstract 1
- 235000019832 sodium triphosphate Nutrition 0.000 abstract 1
- ITCAUAYQCALGGV-XTICBAGASA-M sodium;(1r,4ar,4br,10ar)-1,4a-dimethyl-7-propan-2-yl-2,3,4,4b,5,6,10,10a-octahydrophenanthrene-1-carboxylate Chemical compound [Na+].C([C@@H]12)CC(C(C)C)=CC1=CC[C@@H]1[C@]2(C)CCC[C@@]1(C)C([O-])=O ITCAUAYQCALGGV-XTICBAGASA-M 0.000 abstract 1
- IZWPGJFSBABFGL-GMFCBQQYSA-M sodium;2-[methyl-[(z)-octadec-9-enoyl]amino]ethanesulfonate Chemical compound [Na+].CCCCCCCC\C=C/CCCCCCCC(=O)N(C)CCS([O-])(=O)=O IZWPGJFSBABFGL-GMFCBQQYSA-M 0.000 abstract 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 abstract 1
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 abstract 1
- 239000003232 water-soluble binding agent Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/06—Inorganic compounds
- C11D9/08—Water-soluble compounds
- C11D9/10—Salts
- C11D9/16—Borates
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
561,294. Detergent compositions. SNELL, F. D. June 4, 1942, No. 7613. Convention date, Dec. 30, 1941. [Class 91] A detergent composition comprises a mixture of a water-soluble ionisable anionic active surface-active compound and a borate material containing sodium oxide and boron trioxide, fully combined with each other or not, in the proportion of 1 to 3 mols of Na2O to 1 mol of B2O3, the borate material being present in the proportion of at least approximately 1 part to 1 part of the surface-active compound. The surface-active compounds specified comprise soap, including sodium abietate, sodium, lauryl sulphate, the sodium salts of ceryl benzene sulphonate, succinic ester sulphonates, and the material known under the Registered Trade Mark " Igepon T." The borate material may be sodium metaborate. 1 to 5 parts of the borate material are mixed with each part of the surface-active agent. The borate material may be prepared by mixing at least 2 mols of NaOH for each mol of borax, the proportion of NaOH being increased to prepare the more basic borate material, and then evaporating the solution, the residue being finally heated and milled as desired, the mixture content of the borate material should not exceed 50 per cent. Crude borate ore may be used instead of borax, provided the proper ratio of alkali to boron obtained and insoluble matter is filtered out. Other ingredients may be added to the compositions, in particular a calcium and magnesium sequestration agent such as sodium tripolyphosphate, sodium metaphosphate, tetrasodium pyrophosphate, and sodium hexametaphosphate; an additional alkaline material such as sodium metasilicate ; neutral salts such as sodium chloride and sodium sulphate ; or a water-soluble binder when the compositions are made in block form such as dextrine and casein. The products may be prepared in powder, granular, bead, cake or bar form and in particular in a granular form wherein one of the ingredients, such as the borate material, is' coated with the other ingredient by tumbling the former in a moist granular condition with the latter in a dry condition in a rotated drum. In preparing this form of the compositions, the initial materials for preparing the borate material, viz : NaOH and borax or boric acid may be used, the NaOH being in moist granules which is more or less converted to the borate material which is then coated with the other ingredient such as soap. Specifications 27572/12, 180,957, and 319,807 [all in Class 91], are referred to.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US424919A US2376096A (en) | 1941-12-30 | 1941-12-30 | Detergent composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB561294A true GB561294A (en) | 1944-05-15 |
Family
ID=23684434
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB7613/42A Expired GB561294A (en) | 1941-12-30 | 1942-06-04 | Improvements in detergent compositions and methods of producing the same |
Country Status (2)
| Country | Link |
|---|---|
| US (1) | US2376096A (en) |
| GB (1) | GB561294A (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2579380A (en) * | 1951-12-18 | nazsox | ||
| US2530837A (en) * | 1943-08-02 | 1950-11-21 | Gilron Products Company | Lubricant composition composed of high-titre soap, borax, and an inorganic compound |
| US2662810A (en) * | 1949-09-26 | 1953-12-15 | Borax Cons Ltd | Stabilization of borax supersaturation in solutions |
| US2595300A (en) * | 1950-12-23 | 1952-05-06 | Wilson & Co Inc | Soap compositions and soap flakes |
| US3394653A (en) * | 1965-10-12 | 1968-07-30 | Robert E. Riesberg | Novel method of cleaning paper planographic plates |
| US4297229A (en) * | 1979-10-23 | 1981-10-27 | United States Borax & Chemical Corporation | Particulate borate-soap compositions |
-
1941
- 1941-12-30 US US424919A patent/US2376096A/en not_active Expired - Lifetime
-
1942
- 1942-06-04 GB GB7613/42A patent/GB561294A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| US2376096A (en) | 1945-05-15 |
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