GB684697A - Lubricating grease containing soaps of tall oil - Google Patents

Lubricating grease containing soaps of tall oil

Info

Publication number
GB684697A
GB684697A GB7576/50A GB757650A GB684697A GB 684697 A GB684697 A GB 684697A GB 7576/50 A GB7576/50 A GB 7576/50A GB 757650 A GB757650 A GB 757650A GB 684697 A GB684697 A GB 684697A
Authority
GB
United Kingdom
Prior art keywords
per cent
added
salt
tall oil
oil
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB7576/50A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Standard Oil Development Co
Original Assignee
Standard Oil Development Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US57565A external-priority patent/US2516136A/en
Application filed by Standard Oil Development Co filed Critical Standard Oil Development Co
Publication of GB684697A publication Critical patent/GB684697A/en
Expired legal-status Critical Current

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    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
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    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/104Aromatic fractions
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    • C10M2211/044Acids; Salts or esters thereof
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    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/08Resistance to extreme temperature
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    • C10N2040/02Bearings
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    • C10N2050/00Form in which the lubricant is applied to the material being lubricated
    • C10N2050/10Semi-solids; greasy
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    • C10N2070/00Specific manufacturing methods for lubricant compositions

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

The process for manufacturing lubricating grease according to the parent Specification (in which lubricating oil is thickened with a metal saop of a fatty acid having from 12 to 22 carbon atoms in the molecule and there is added from 2 to 20 per cent by weight of the total composition of a metal salt of a heterocyclic carboxylic acid) is modified by the complete or partial substitution of tall oil acids for the C12-C22 fatty acid. Suitable heterocyclic carboxylic acids are furoic acid and thiophene carboxylic acid. The salt of the heterocyclic carboxylic acid may be prepared as in the parent Specification by the Cannizzaro reaction on the corresponding aldehyde. In the case of sodium furoate (which is the preferred salt) the furfural may be added to the tall oil and the soap and salt prepared together in situ by the action of sodium hydroxide, or the furfural may be present as an impurity in commercial tall oil. In this latter case the amount may be adjusted to form the requisite proportion of sodium furoate. Preferred proportions are 2-10 per cent, particularly 3 to 7 per cent of salt and 8 to 15 per cent of soap. The lubricating oil may be a mineral oil of viscosity from 35 to 150 S.U.S. at 210 DEG F or 50 to 1,000 S.U.S. at 100 DEG F. Synthetic oils may also be used. Antioxidants, oiliness agents, corrosion inhibitors and extreme pressure compounds may also be added. In an example (all parts by weight) 10 per cent of furfural and 30 per cent of mineral oil of viscosity S.U.S. at 210 DEG F are charged into a grease kettle and 3.18 per cent of caustic soda added as a 33.4 per cent aqueous solution. After completion of reaction, 15 per cent of tall oil (acid No. 183.2 and saponification No. 185.2) is added and neutralized with 2 per cent of caustic soda added as a 40 per cent aqueous solution. The mixture is heated to 400 DEG F and 38.82 per cent of the same mineral oil added in small portions. Finally 1 per cent of phenyl alpha naphthylamine is added and the grease allowed to cool.
GB7576/50A 1948-10-30 1950-03-27 Lubricating grease containing soaps of tall oil Expired GB684697A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US57565A US2516136A (en) 1948-10-30 1948-10-30 Lubricating grease compositions
US86586A US2576031A (en) 1948-10-30 1949-04-09 Lubricating grease containing soaps of tall oil

Publications (1)

Publication Number Publication Date
GB684697A true GB684697A (en) 1952-12-24

Family

ID=26736629

Family Applications (2)

Application Number Title Priority Date Filing Date
GB24741/49A Expired GB669947A (en) 1948-10-30 1949-09-27 Improvements in or relating to lubricating grease compositions
GB7576/50A Expired GB684697A (en) 1948-10-30 1950-03-27 Lubricating grease containing soaps of tall oil

Family Applications Before (1)

Application Number Title Priority Date Filing Date
GB24741/49A Expired GB669947A (en) 1948-10-30 1949-09-27 Improvements in or relating to lubricating grease compositions

Country Status (5)

Country Link
US (1) US2576031A (en)
DE (1) DE845228C (en)
FR (1) FR998260A (en)
GB (2) GB669947A (en)
NL (3) NL73227C (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2790770A (en) * 1957-04-30 Grease composition
US2801974A (en) * 1952-12-22 1957-08-06 Exxon Research Engineering Co Grease process utilizing the alkali fusion products of cyclic alcohols
US2834732A (en) * 1954-11-29 1958-05-13 Standard Oil Co Extreme pressure lubricant
US2946748A (en) * 1956-05-08 1960-07-26 Swift & Co Liquid hydrocarbon gels and uses thereof
US3252906A (en) * 1963-06-07 1966-05-24 Standard Oil Co Grease
US11760952B2 (en) 2021-01-12 2023-09-19 Ingevity South Carolina, Llc Lubricant thickener systems from modified tall oil fatty acids, lubricating compositions, and associated methods

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2182137A (en) * 1937-02-01 1939-12-05 Shell Dev Soda soap grease
GB583303A (en) * 1944-10-17 1946-12-13 Bataafsche Petroleum Improvements in or relating to the manufacture of lithium base greases
US2514286A (en) * 1947-12-31 1950-07-04 Standard Oil Dev Co Lubricating grease and method of preparing same
US2516136A (en) * 1948-10-30 1950-07-25 Standard Oil Dev Co Lubricating grease compositions
US2516137A (en) * 1948-10-30 1950-07-25 Standard Oil Dev Co High-temperature lubricating greases

Also Published As

Publication number Publication date
NL149599C (en)
US2576031A (en) 1951-11-20
DE845228C (en) 1952-07-31
FR998260A (en) 1952-01-16
GB669947A (en) 1952-04-09
NL73227C (en)
NL75829C (en)

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