GB651965A - Method of producing oxonium derivatives having catalytic and biocatalytic properties - Google Patents

Method of producing oxonium derivatives having catalytic and biocatalytic properties

Info

Publication number
GB651965A
GB651965A GB17747A GB17747A GB651965A GB 651965 A GB651965 A GB 651965A GB 17747 A GB17747 A GB 17747A GB 17747 A GB17747 A GB 17747A GB 651965 A GB651965 A GB 651965A
Authority
GB
United Kingdom
Prior art keywords
flame
gas
oxygen
excess
directing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB17747A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
RENE LEON JACQUIER
Original Assignee
RENE LEON JACQUIER
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by RENE LEON JACQUIER filed Critical RENE LEON JACQUIER
Priority to GB17747A priority Critical patent/GB651965A/en
Publication of GB651965A publication Critical patent/GB651965A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C409/00—Peroxy compounds
    • C07C409/02—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides
    • C07C409/14—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides the carbon atom belonging to a ring other than a six-membered aromatic ring

Abstract

Organic compounds containing a double or triple bond are polymerized by treating them with an "oxonium derivative" obtained by directing into a gas flame a gaseous current containing free oxygen in excess of that required for complete combustion of the gas providing the flame, so as to cool the flame to 45-150 DEG C. (see Group IV (b)). In an example, air charged with turpentine vapours is directed on to a hydrogen flame, and the issuing gases are bubbled through a solution of vinyl acetate in benzene. Reference is also made to the polymerization of styrene, propenyl methyl ketone and butadiene.ALSO:Organic compounds described as oxonium derivatives are manufactured by directing into a gas flame a gaseous current containing free oxygen in excess of that required for complete combustion of the gas providing the flame, so as to cool the flame to 45-150 DEG C., an organic compound being vaporized or atomized into the gaseous current before or after it passes the flame. Advantageously the flame is vibrated by means of vibrating devices applied to the oxygen-containing gas, the fuel gas or the flame itself, e.g. by variation of gas supply or by means of plunger machines or valve systems. Suitable types of apparatus are described with drawings. In examples: (1) air charged with turpentine vapours is directed on to a hydrogen flame; (2) hydrogen and excess of air are passed into a burner, and into the gas issuing from the flame is atomized turpentine oil or other (preferably unsaturated) organic compounds, e.g. terpenes, fulrenes, indenes, carotenes or other unsaturated hydrocarbons, or chaulmorgra oil. The Specification as open to inspection under Sect. 91, in which the products are described as nascent peroxides, comprises generally directing a gaseous current containing oxygen, in unspecified amount, into a gas flame to effect cooling thereof to an unspecified extent. This subject-matter does not appear in the Specification as accepted.ALSO:A form of oxygen described as oxonium dioxide, O=O=O, is stated to be formed by directing into a gas flame (preferably vibrating) a gaseous current containing free oxygen in excess of that required for complete combustion of the gas providing the flame, so as to cool the flame to 45-150 DEG C. Suitable types of apparatus are described with drawings, and examples are given.
GB17747A 1947-01-02 1947-01-02 Method of producing oxonium derivatives having catalytic and biocatalytic properties Expired GB651965A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB17747A GB651965A (en) 1947-01-02 1947-01-02 Method of producing oxonium derivatives having catalytic and biocatalytic properties

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB17747A GB651965A (en) 1947-01-02 1947-01-02 Method of producing oxonium derivatives having catalytic and biocatalytic properties

Publications (1)

Publication Number Publication Date
GB651965A true GB651965A (en) 1951-04-11

Family

ID=9699767

Family Applications (1)

Application Number Title Priority Date Filing Date
GB17747A Expired GB651965A (en) 1947-01-02 1947-01-02 Method of producing oxonium derivatives having catalytic and biocatalytic properties

Country Status (1)

Country Link
GB (1) GB651965A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0346552A1 (en) * 1986-12-29 1989-12-20 Leneveu-Delanef, Marie-Laure Process for the preparation of organic oxonium derivatives, particularly of peroxides of terpene oxonium

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0346552A1 (en) * 1986-12-29 1989-12-20 Leneveu-Delanef, Marie-Laure Process for the preparation of organic oxonium derivatives, particularly of peroxides of terpene oxonium

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