GB600113A - Improvements relating to processes for spinning artificial silk from viscose in an acid spinning bath - Google Patents
Improvements relating to processes for spinning artificial silk from viscose in an acid spinning bathInfo
- Publication number
- GB600113A GB600113A GB26027/45A GB2602745A GB600113A GB 600113 A GB600113 A GB 600113A GB 26027/45 A GB26027/45 A GB 26027/45A GB 2602745 A GB2602745 A GB 2602745A GB 600113 A GB600113 A GB 600113A
- Authority
- GB
- United Kingdom
- Prior art keywords
- spinning
- pyridine
- compounds
- prepared
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F2/00—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
- D01F2/06—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof from viscose
- D01F2/08—Composition of the spinning solution or the bath
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F2/00—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
- D01F2/06—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof from viscose
- D01F2/08—Composition of the spinning solution or the bath
- D01F2/10—Addition to the spinning solution or spinning bath of substances which exert their effect equally well in either
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Artificial Filaments (AREA)
Abstract
In the production of filaments, fibres, threads and the like from viscose by extrusion into an acid spinning bath a small amount of a compound of general formula <PICT:0600113/IV(a)/1> wherein R and R1 may be aliphatic or aromatic radicles, the chain of which excluding aromatic or other nucleus has a length of at most 6 C-atoms, or R1 may be hydrogen, X may be OH or a monovalent acid radicle and the pyridine may be substituted or may be a homologue of pyridine is added to the spinning bath or spinning solution, to prevent blocking of the spinning nozzles. These compounds are stable in both acid and alkaline solutions and will not cause foam-formation on concentration of the bath by evaporation since they are not surface-active. In an example 0.1 per cent of N(a -furyl-21; hydroxy-21; phenyl-11; ethyl)-1 pyridinium bromide is dissolved in a spinning bath containing 50 g. zinc sulphate per litre in addition to the normal quantities of sodium sulphate and sulphuric acid. After spinning for 1 hour 80 per cent of the orifices were unblocked, whereas when spinning under the conditions without the addition all orifices were blocked. In a further example 0.1 per cent of N(phenyl-21; hydroxy-21; vinyl-11; ethyl(-1-pyridinium) bromide was added to viscose which was then spun into a bath containing usual amounts of sodium sulphate and sulphuric acid and 50 g. of zinc sulphate per litre. As in the previous example, 80 per cent of the orifices were clear after spinning for 1 hour. Preparation of additives.-These compounds may be prepared from pyridine or one of its homologues or derivatives, an alkyl halide and an aldehyde. For example, N(a -furyl-21; hydroxy-21; phenyl-11; ethyl)-1-pyridinium bromide is prepared by adding an equivalent amount of furfural to benzyl-pyridinium bromide in ethanol. 10N sodium lye is added and the mixture left at 0 DEG C. for 5 days, the separated product being then washed with alcohol, purified with decolorising carbon and recrystallized from water. The compounds may also be prepared by reacting styrene bromohydrin with homologues or derivatives of pyridine.ALSO:Compounds of general formula <FORM:0600113/IV(b)/1> wherein R and R1 may be aliphatic or aromatic radicles, the chain of which excluding aromatic or other nucleus has a length of at most 6 C-atoms, or R1 may be hydrogen, X may be OH or a monovalent acid radicle and the pyridine may be substituted or may be a homologue of pyridine are added to viscose spinning solutions. These compounds may be prepared from pyridine or one of its homologues or derivatives, an alkyl halide and an aldehyde. For example, N(-furyl-21; hydroxy-21; phenyl-11; ethyl)-1-pyridinium bromide is prepared by adding an equivalent amount of furfural to benzylpyridinium bromide in ethanol. IO N sodium lye is added and the mixture left at 0 DEG C. for 5 days, the separated product being then washed with alcohol, purified with decolorising carbon and recrystallised from water. The compounds may also be prepared by reacting styrene bromohydrin with homologues or derivatives of pyridine.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL111999A NL59713C (en) | 1943-06-29 | 1943-06-29 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB600113A true GB600113A (en) | 1948-03-31 |
Family
ID=19750357
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB26027/45A Expired GB600113A (en) | 1943-06-29 | 1945-10-05 | Improvements relating to processes for spinning artificial silk from viscose in an acid spinning bath |
Country Status (6)
Country | Link |
---|---|
US (1) | US2451148A (en) |
BE (1) | BE456065A (en) |
CH (3) | CH260019A (en) |
FR (1) | FR904273A (en) |
GB (1) | GB600113A (en) |
NL (1) | NL59713C (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3252816A (en) * | 1962-05-28 | 1966-05-24 | Allied Chem | Pigmented extrudable viscose solutions |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE641271C (en) * | 1934-01-26 | 1937-01-26 | Fritz Kroehnke Dr | Process for the preparation of aromatically substituted pyridinium ethanols |
DE641270C (en) * | 1934-01-26 | 1937-01-26 | Fritz Kroehnke Dr | Process for the preparation of pyridinium ethanols substituted by heterocyclic radicals |
BE419429A (en) * | 1935-02-16 | 1900-01-01 |
-
0
- BE BE456065D patent/BE456065A/xx unknown
-
1943
- 1943-06-29 NL NL111999A patent/NL59713C/xx active
-
1944
- 1944-05-03 CH CH260019D patent/CH260019A/en unknown
- 1944-05-03 CH CH251094D patent/CH251094A/en unknown
- 1944-05-03 CH CH260020D patent/CH260020A/en unknown
- 1944-05-15 FR FR904273D patent/FR904273A/en not_active Expired
-
1945
- 1945-10-05 GB GB26027/45A patent/GB600113A/en not_active Expired
-
1946
- 1946-01-30 US US644440A patent/US2451148A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
CH260019A (en) | 1949-02-15 |
BE456065A (en) | |
FR904273A (en) | 1945-10-31 |
US2451148A (en) | 1948-10-12 |
CH260020A (en) | 1949-02-15 |
CH251094A (en) | 1947-10-15 |
NL59713C (en) | 1947-07-15 |
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