GB595777A - Improvements in or relating to the preparation of arylsulphonylthioureas - Google Patents

Improvements in or relating to the preparation of arylsulphonylthioureas

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Publication number
GB595777A
GB595777A GB12488/45A GB1248845A GB595777A GB 595777 A GB595777 A GB 595777A GB 12488/45 A GB12488/45 A GB 12488/45A GB 1248845 A GB1248845 A GB 1248845A GB 595777 A GB595777 A GB 595777A
Authority
GB
United Kingdom
Prior art keywords
sulphur
sodium
anhydrous
hydrogen
ammonia
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB12488/45A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rhone Poulenc SA
Original Assignee
Rhone Poulenc SA
Societe des Usines Chimiques Rhone Poulenc SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rhone Poulenc SA, Societe des Usines Chimiques Rhone Poulenc SA filed Critical Rhone Poulenc SA
Publication of GB595777A publication Critical patent/GB595777A/en
Expired legal-status Critical Current

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  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

The process of obtaining nuclearly substituted or unsubstituted N - arylsulphonylthioureas which is described in Specification 595,771 and which comprises the addition of hydrogen sulphide to the corresponding arylsulphonylcyanamides, is carried out in an anhydrous medium and in the presence of anhydrous ammonia or of an anhydrous organic base or of a substance capable of generating nacent sulphur under the conditions of the reaction. Specified substances for this purpose are flowers of sulphur, sodium polysulphide, sodium thioantimonate, the disulphide of tetramethylthiouram, thionyl chloride and the peroxides such as hydrogen, sodium or benzoyl peroxides. In examples: (1) an absolute alcoholic solution of diethylamine, p - aminobenzenesulphonyl - cyanide and the disulphide of tetramethylthiouram is saturated with hydrogen sulphide to form N-(p-aminobenzenesulphonyl)-thiourea; (2) as in example (1), but using ammonia as the base and thionyl chloride as the sulphur yielding compound. A sample has been furnished under Sect. 2 (5) prepared by saturating with H2S an alcohol solution of p-aminobenzenesulphonylcyanamide containing anhydrous ammonia and hydrogen peroxide. The product is worked up as in example (1).
GB12488/45A 1943-10-19 1945-05-17 Improvements in or relating to the preparation of arylsulphonylthioureas Expired GB595777A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR595777X 1943-10-19

Publications (1)

Publication Number Publication Date
GB595777A true GB595777A (en) 1947-12-16

Family

ID=8967095

Family Applications (1)

Application Number Title Priority Date Filing Date
GB12488/45A Expired GB595777A (en) 1943-10-19 1945-05-17 Improvements in or relating to the preparation of arylsulphonylthioureas

Country Status (1)

Country Link
GB (1) GB595777A (en)

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