GB592542A - The colouring of surfaces of vinyl chloride polymer compositions - Google Patents
The colouring of surfaces of vinyl chloride polymer compositionsInfo
- Publication number
- GB592542A GB592542A GB1123245A GB1123245A GB592542A GB 592542 A GB592542 A GB 592542A GB 1123245 A GB1123245 A GB 1123245A GB 1123245 A GB1123245 A GB 1123245A GB 592542 A GB592542 A GB 592542A
- Authority
- GB
- United Kingdom
- Prior art keywords
- polyvinyl chloride
- liquid
- compositions
- pressure
- solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title abstract 9
- 238000004040 coloring Methods 0.000 title abstract 3
- 229920000642 polymer Polymers 0.000 title abstract 2
- BZHJMEDXRYGGRV-UHFFFAOYSA-N vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 title abstract 2
- 239000007788 liquid Substances 0.000 abstract 10
- 229920000915 polyvinyl chloride Polymers 0.000 abstract 9
- 239000004800 polyvinyl chloride Substances 0.000 abstract 9
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 abstract 4
- 239000000975 dye Substances 0.000 abstract 4
- 239000000049 pigment Substances 0.000 abstract 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 abstract 4
- DOIRQSBPFJWKBE-UHFFFAOYSA-N Dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 abstract 3
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-dichloroethane Chemical class ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 abstract 2
- OZXIZRZFGJZWBF-UHFFFAOYSA-N 1,3,5-trimethyl-2-(2,4,6-trimethylphenoxy)benzene Chemical compound CC1=CC(C)=CC(C)=C1OC1=C(C)C=C(C)C=C1C OZXIZRZFGJZWBF-UHFFFAOYSA-N 0.000 abstract 2
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 abstract 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N 2-methyl-2-propenoic acid methyl ester Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 abstract 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N Chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 abstract 2
- 229920000742 Cotton Polymers 0.000 abstract 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N Cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 abstract 2
- BGTOWKSIORTVQH-UHFFFAOYSA-N Cyclopentanone Chemical compound O=C1CCCC1 BGTOWKSIORTVQH-UHFFFAOYSA-N 0.000 abstract 2
- 229960002380 Dibutyl Phthalate Drugs 0.000 abstract 2
- NIQCNGHVCWTJSM-UHFFFAOYSA-N Dimethyl phthalate Chemical compound COC(=O)C1=CC=CC=C1C(=O)OC NIQCNGHVCWTJSM-UHFFFAOYSA-N 0.000 abstract 2
- 210000001331 Nose Anatomy 0.000 abstract 2
- 230000001680 brushing Effects 0.000 abstract 2
- 229910000423 chromium oxide Inorganic materials 0.000 abstract 2
- PYGXAGIECVVIOZ-UHFFFAOYSA-N dibutyl decanedioate Chemical compound CCCCOC(=O)CCCCCCCCC(=O)OCCCC PYGXAGIECVVIOZ-UHFFFAOYSA-N 0.000 abstract 2
- 229940031954 dibutyl sebacate Drugs 0.000 abstract 2
- 229960001826 dimethylphthalate Drugs 0.000 abstract 2
- SNQXJPARXFUULZ-UHFFFAOYSA-N dioxolane Chemical compound C1COOC1 SNQXJPARXFUULZ-UHFFFAOYSA-N 0.000 abstract 2
- 230000000694 effects Effects 0.000 abstract 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 abstract 2
- 229910000460 iron oxide Inorganic materials 0.000 abstract 2
- 238000004519 manufacturing process Methods 0.000 abstract 2
- 239000000463 material Substances 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 abstract 2
- 239000012255 powdered metal Substances 0.000 abstract 2
- 239000000725 suspension Substances 0.000 abstract 2
- 150000007984 tetrahydrofuranes Chemical class 0.000 abstract 2
- 125000001412 tetrahydropyranyl group Chemical class 0.000 abstract 2
- WGLPBDUCMAPZCE-UHFFFAOYSA-N trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 abstract 2
- 239000011787 zinc oxide Substances 0.000 abstract 2
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- -1 e.g. Substances 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/651—Compounds without nitrogen
- D06P1/65106—Oxygen-containing compounds
- D06P1/65125—Compounds containing ester groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/004—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated using dispersed dyes
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Coloring (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Printing Methods (AREA)
Abstract
The surfaces of polyvinyl chloride compositions (see Group IV) are coloured by applying a solution or suspension of one or more colouring materials dissolved or suspended in a liquid with which the compositions are miscible and of b.p. less than 220 DEG C. at 5 mm. pressure, and allowing the liquid to penetrate the surface. Preferably the liquid has a b.p. between 200 DEG C. and 360 DEG C. at 760 mm. pressure, e.g., dimethyl phthalate, dibutyl phthalate and dibutyl sebacate; other suitable liquids are methylene and ethylene dichlorides, monochlorbenzene, monomeric methyl methacrylate, tetrahydrofuranes, tetrahydropyranes, dioxolane, dioxane, mesityl oxide, cyclopentanone, cyclohexanone, nitroparaffins and dimethyl formamide. Solutions of dyes may be used, but pigments, e.g., iron or chromium oxide or finely powdered metals, are best applied as a paste of base pigment, e.g., zinc oxide, with the liquid. The process is applicable to pigmented polyvinyl chloride compositions and is of particular use in the production of surgical prosotheses, e.g., noses and ears. Dye solutions may be applied by brushing or patterned effects may be obtained by means of a pad of cotton wool wetted with solution applied to a stencil covering a polyvinyl chloride sheet or they may be coated upon a printing plate and transferred to the polyvinyl chloride surface in the usual way. Specification 570,915, [Group IV], is referred to.ALSO:The surfaces of polyvinyl chloride compositions are coloured by applying a solution or suspension of one or more colouring materials dissolved or suspended in a liquid with which the compositions are miscible and of b.p. less than 220 DEG C. at 5 mms. pressure, and allowing the liquid to penetrate the surface. The polyvinyl chloride compositions comprise gelatinized mixtures of one or more polymers of vinyl chloride or interpolymers thereof with one or more ethylenically unsaturated compounds and one or more non-volatile plasticising agents, e.g. dibutyl phthalate or tricresyl phosphate. Preferably, the liquid has a b.p. between 200 DEG and 360 DEG C. at 760 mms. pressure, specified are dimethyl phthalate, dibutyl phthalate and dibutyl sebacate; other liquids suitable are methylene and ethylene dichlorides, monochlorbenzene, monomeric methyl methacrylate, tetrahydrofuranes, tetrahydropyranes, dioxolane, dioxane, mesityl oxide, cyclopentanone, cyclohexanone, nitroparaffins and dimethyl formamide. Solutions of dyes may be used, but pigments, e.g. iron or chromium oxide or finely powdered metals, are best applied as a paste of base pigment, e.g. zinc oxide, with the liquid. The process is applicable to pigmented polyvinyl chloride compositions and is of particular use in the production of surgical prostheses, e.g. noses and ears. Dye solutions may be applied by brushing or patterned effects may be obtained by means of a pad of cotton wool wetted with solution applied to a stencil covering a polyvinyl chloride sheet, or they may be coated upon a printing plate and transferred to the polyvinyl chloride surface in the usual way. Specification 570,915 is referred to.
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB592542A true GB592542A (en) | 1947-09-22 |
Family
ID=1706854
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1123245A Expired GB592542A (en) | 1945-05-03 | The colouring of surfaces of vinyl chloride polymer compositions |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB592542A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3041303A (en) * | 1955-08-03 | 1962-06-26 | Monsanto Chemicals | Molding powder comprising polystyrene, white inorganic pigment and finely divided metal powder |
| FR2029589A1 (en) * | 1969-01-28 | 1970-10-23 | Askim Gummivarefabrikk | |
| FR2180596A2 (en) * | 1972-04-21 | 1973-11-30 | Askim Gummivarefabrik As | Dyeing PVC soles - with cpds penetrating polymer plasticiser, to give resis-tant colours |
-
1945
- 1945-05-03 GB GB1123245A patent/GB592542A/en not_active Expired
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3041303A (en) * | 1955-08-03 | 1962-06-26 | Monsanto Chemicals | Molding powder comprising polystyrene, white inorganic pigment and finely divided metal powder |
| FR2029589A1 (en) * | 1969-01-28 | 1970-10-23 | Askim Gummivarefabrikk | |
| FR2180596A2 (en) * | 1972-04-21 | 1973-11-30 | Askim Gummivarefabrik As | Dyeing PVC soles - with cpds penetrating polymer plasticiser, to give resis-tant colours |
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