GB492743A - Process for increasing the affinity for dyestuffs of articles of cellulose, cellulose derivatives or polymers soluble in organic solvents - Google Patents
Process for increasing the affinity for dyestuffs of articles of cellulose, cellulose derivatives or polymers soluble in organic solventsInfo
- Publication number
- GB492743A GB492743A GB1836/37A GB183637A GB492743A GB 492743 A GB492743 A GB 492743A GB 1836/37 A GB1836/37 A GB 1836/37A GB 183637 A GB183637 A GB 183637A GB 492743 A GB492743 A GB 492743A
- Authority
- GB
- United Kingdom
- Prior art keywords
- solution
- pyridine
- cellulose
- acid
- product
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920002678 cellulose Polymers 0.000 title abstract 10
- 239000001913 cellulose Substances 0.000 title abstract 10
- 239000003960 organic solvent Substances 0.000 title abstract 2
- 229920000642 polymer Polymers 0.000 title abstract 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 abstract 30
- 239000000243 solution Substances 0.000 abstract 21
- WGQKYBSKWIADBV-UHFFFAOYSA-N benzylamine Chemical compound NCC1=CC=CC=C1 WGQKYBSKWIADBV-UHFFFAOYSA-N 0.000 abstract 18
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 abstract 15
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 abstract 12
- 239000000047 product Substances 0.000 abstract 10
- -1 sulphonic acid ester Chemical class 0.000 abstract 9
- 229920002472 Starch Polymers 0.000 abstract 7
- 239000002253 acid Substances 0.000 abstract 7
- 239000007795 chemical reaction product Substances 0.000 abstract 7
- 239000008107 starch Substances 0.000 abstract 7
- 235000019698 starch Nutrition 0.000 abstract 7
- KDSNLYIMUZNERS-UHFFFAOYSA-N 2-methylpropanamine Chemical compound CC(C)CN KDSNLYIMUZNERS-UHFFFAOYSA-N 0.000 abstract 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 6
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 abstract 5
- 229960000583 acetic acid Drugs 0.000 abstract 5
- 229920002955 Art silk Polymers 0.000 abstract 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 abstract 4
- 210000002268 wool Anatomy 0.000 abstract 4
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 abstract 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 abstract 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 3
- 229920002284 Cellulose triacetate Polymers 0.000 abstract 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract 3
- NNLVGZFZQQXQNW-ADJNRHBOSA-N [(2r,3r,4s,5r,6s)-4,5-diacetyloxy-3-[(2s,3r,4s,5r,6r)-3,4,5-triacetyloxy-6-(acetyloxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6s)-4,5,6-triacetyloxy-2-(acetyloxymethyl)oxan-3-yl]oxyoxan-2-yl]methyl acetate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](OC(C)=O)[C@H]1OC(C)=O)O[C@H]1[C@@H]([C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](COC(C)=O)O1)OC(C)=O)COC(=O)C)[C@@H]1[C@@H](COC(C)=O)O[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@H]1OC(C)=O NNLVGZFZQQXQNW-ADJNRHBOSA-N 0.000 abstract 3
- 150000001412 amines Chemical class 0.000 abstract 3
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 abstract 3
- 239000004744 fabric Substances 0.000 abstract 3
- 239000012362 glacial acetic acid Substances 0.000 abstract 3
- 239000002904 solvent Substances 0.000 abstract 3
- GPXWKSACSYMTQN-UHFFFAOYSA-N (4-cyanophenyl) 4-(4-heptylcyclohexyl)benzoate Chemical compound C1CC(CCCCCCC)CCC1C1=CC=C(C(=O)OC=2C=CC(=CC=2)C#N)C=C1 GPXWKSACSYMTQN-UHFFFAOYSA-N 0.000 abstract 2
- HXDLWJWIAHWIKI-UHFFFAOYSA-N 2-hydroxyethyl acetate Chemical compound CC(=O)OCCO HXDLWJWIAHWIKI-UHFFFAOYSA-N 0.000 abstract 2
- 229920000742 Cotton Polymers 0.000 abstract 2
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 abstract 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 abstract 2
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 abstract 2
- SJEYSFABYSGQBG-UHFFFAOYSA-M Patent blue Chemical compound [Na+].C1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=CC=1)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](CC)CC)C=C1 SJEYSFABYSGQBG-UHFFFAOYSA-M 0.000 abstract 2
- NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical compound C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 abstract 2
- 229920000297 Rayon Polymers 0.000 abstract 2
- 239000000980 acid dye Substances 0.000 abstract 2
- MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 abstract 2
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 abstract 2
- 239000004202 carbamide Substances 0.000 abstract 2
- PAFZNILMFXTMIY-UHFFFAOYSA-N cyclohexylamine Chemical compound NC1CCCCC1 PAFZNILMFXTMIY-UHFFFAOYSA-N 0.000 abstract 2
- 239000000982 direct dye Substances 0.000 abstract 2
- FPAYXBWMYIMERV-UHFFFAOYSA-L disodium;5-methyl-2-[[4-(4-methyl-2-sulfonatoanilino)-9,10-dioxoanthracen-1-yl]amino]benzenesulfonate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)C1=CC(C)=CC=C1NC(C=1C(=O)C2=CC=CC=C2C(=O)C=11)=CC=C1NC1=CC=C(C)C=C1S([O-])(=O)=O FPAYXBWMYIMERV-UHFFFAOYSA-L 0.000 abstract 2
- 238000004043 dyeing Methods 0.000 abstract 2
- 239000003995 emulsifying agent Substances 0.000 abstract 2
- 239000000839 emulsion Substances 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 229920003023 plastic Polymers 0.000 abstract 2
- 239000004033 plastic Substances 0.000 abstract 2
- 239000011780 sodium chloride Substances 0.000 abstract 2
- 235000011121 sodium hydroxide Nutrition 0.000 abstract 2
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 abstract 2
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 abstract 1
- BMVXCPBXGZKUPN-UHFFFAOYSA-N 1-hexanamine Chemical compound CCCCCCN BMVXCPBXGZKUPN-UHFFFAOYSA-N 0.000 abstract 1
- KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-naphthol Chemical compound C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 abstract 1
- LHYQAEFVHIZFLR-UHFFFAOYSA-L 4-(4-diazonio-3-methoxyphenyl)-2-methoxybenzenediazonium;dichloride Chemical compound [Cl-].[Cl-].C1=C([N+]#N)C(OC)=CC(C=2C=C(OC)C([N+]#N)=CC=2)=C1 LHYQAEFVHIZFLR-UHFFFAOYSA-L 0.000 abstract 1
- QVIAMKXOQGCYCV-UHFFFAOYSA-N 4-methylpentan-1-amine Chemical compound CC(C)CCCN QVIAMKXOQGCYCV-UHFFFAOYSA-N 0.000 abstract 1
- YYROPELSRYBVMQ-UHFFFAOYSA-N 4-toluenesulfonyl chloride Chemical compound CC1=CC=C(S(Cl)(=O)=O)C=C1 YYROPELSRYBVMQ-UHFFFAOYSA-N 0.000 abstract 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 abstract 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract 1
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 abstract 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 abstract 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 abstract 1
- AVKFYMCRAOFHOC-YZJMRIMCSA-N acetic acid (2R,3S,4R,5R)-2,3,4,5,6-pentahydroxyhexanal Chemical compound CC(O)=O.CC(O)=O.CC(O)=O.OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O AVKFYMCRAOFHOC-YZJMRIMCSA-N 0.000 abstract 1
- 229920013820 alkyl cellulose Polymers 0.000 abstract 1
- 229910021529 ammonia Inorganic materials 0.000 abstract 1
- CSKNSYBAZOQPLR-UHFFFAOYSA-N benzenesulfonyl chloride Chemical compound ClS(=O)(=O)C1=CC=CC=C1 CSKNSYBAZOQPLR-UHFFFAOYSA-N 0.000 abstract 1
- 150000001719 carbohydrate derivatives Chemical class 0.000 abstract 1
- 150000001720 carbohydrates Chemical class 0.000 abstract 1
- 235000014633 carbohydrates Nutrition 0.000 abstract 1
- 235000010980 cellulose Nutrition 0.000 abstract 1
- 229920002301 cellulose acetate Polymers 0.000 abstract 1
- 239000000460 chlorine Substances 0.000 abstract 1
- 229910052801 chlorine Inorganic materials 0.000 abstract 1
- WYYQVWLEPYFFLP-UHFFFAOYSA-K chromium(3+);triacetate Chemical compound [Cr+3].CC([O-])=O.CC([O-])=O.CC([O-])=O WYYQVWLEPYFFLP-UHFFFAOYSA-K 0.000 abstract 1
- 239000007859 condensation product Substances 0.000 abstract 1
- JROAZQFKSSYEBL-TWNXTNBYSA-L disodium;5-[(z)-(3-carboxy-5-methyl-4-oxocyclohexa-2,5-dien-1-ylidene)-(2,6-dichlorophenyl)methyl]-3-methyl-2-oxidobenzoate Chemical compound [Na+].[Na+].C1=C(C([O-])=O)C(=O)C(C)=C\C1=C(C=1C(=CC=CC=1Cl)Cl)/C1=CC(C)=C(O)C(C([O-])=O)=C1 JROAZQFKSSYEBL-TWNXTNBYSA-L 0.000 abstract 1
- 239000000975 dye Substances 0.000 abstract 1
- 230000000694 effects Effects 0.000 abstract 1
- 239000003792 electrolyte Substances 0.000 abstract 1
- 238000009963 fulling Methods 0.000 abstract 1
- 229920013821 hydroxy alkyl cellulose Polymers 0.000 abstract 1
- JJWLVOIRVHMVIS-UHFFFAOYSA-N isopropylamine Chemical compound CC(C)N JJWLVOIRVHMVIS-UHFFFAOYSA-N 0.000 abstract 1
- 235000010355 mannitol Nutrition 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 229920000609 methyl cellulose Polymers 0.000 abstract 1
- 239000001923 methylcellulose Substances 0.000 abstract 1
- CNXZLZNEIYFZGU-UHFFFAOYSA-N n-(4-amino-2,5-diethoxyphenyl)benzamide Chemical compound C1=C(N)C(OCC)=CC(NC(=O)C=2C=CC=CC=2)=C1OCC CNXZLZNEIYFZGU-UHFFFAOYSA-N 0.000 abstract 1
- 229940055577 oleyl alcohol Drugs 0.000 abstract 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 abstract 1
- 229920002223 polystyrene Polymers 0.000 abstract 1
- 229920000915 polyvinyl chloride Polymers 0.000 abstract 1
- 239000004800 polyvinyl chloride Substances 0.000 abstract 1
- KMUONIBRACKNSN-UHFFFAOYSA-N potassium dichromate Chemical compound [K+].[K+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O KMUONIBRACKNSN-UHFFFAOYSA-N 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 239000008149 soap solution Substances 0.000 abstract 1
- 239000001632 sodium acetate Substances 0.000 abstract 1
- 235000017281 sodium acetate Nutrition 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 238000006467 substitution reaction Methods 0.000 abstract 1
- 235000000346 sugar Nutrition 0.000 abstract 1
- 150000008163 sugars Chemical class 0.000 abstract 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical class OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 abstract 1
- 230000002522 swelling effect Effects 0.000 abstract 1
- 150000003567 thiocyanates Chemical class 0.000 abstract 1
- 150000004764 thiosulfuric acid derivatives Chemical class 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/22—Effecting variation of dye affinity on textile material by chemical means that react with the fibre
- D06P5/225—Aminalization of cellulose; introducing aminogroups into cellulose
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L1/00—Compositions of cellulose, modified cellulose or cellulose derivatives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L1/00—Compositions of cellulose, modified cellulose or cellulose derivatives
- C08L1/08—Cellulose derivatives
- C08L1/22—Cellulose xanthate
- C08L1/24—Viscose
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
- D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
- D06M11/13—Ammonium halides or halides of elements of Groups 1 or 11 of the Periodic Table
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
- D06M15/11—Starch or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/22—Effecting variation of dye affinity on textile material by chemical means that react with the fibre
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Coloring (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The affinity for dyestuffs of articles such as threads, yarns, fabrics or films, made from cellulose, cellulose derivatives, or polymers, (e.g. polystyrol or polyvinyl chloride) soluble in organic solvents is increased by incorporating in substance therein a reaction product of a sulphonic acid ester of a carbohydrate or carbohydrate derivative with ammonia, an amine or urea, thiourea or a substitution product thereof, which reaction product still contains sulphonic acid ester groups. Such products may be incorporated by admixture into the solutions or plastic masses from which the articles are made or by treatment of the finished articles. In the latter case the product may be applied in a solvent or emulsifying agent having a swelling action on the material treated. Specified sulphonic acid ester components are the benzene, toluene, ethane and other sulphonic acid esters of sugars, mannite, starch, cellulose and alkyl-and hydroxyalkyl-celluloses. Specified amines are isopropylamine, isobutylamine, hexylamine, isohexylamine, cyclohexylamine, diethanolamine, ethylenediamine, benzylamine, pyridine, piperidine and morpholine. For admixture into solutions or plastic masses of cellulose the reaction products may, in the case of viscose be dissolved in a solvent such as isobutylamine or benzylamine with or without an emulsifying agent and, in the case of cuprammonium cellulose, be emulsified in aqueous ammonia. Specified solvents for use in treatment of the finished articles, especially of cellulose derivatives, are glacial acetic acid, glycol monoacetate, butylamine, benzylamine and pyridine. The fixation of the reaction products on the articles may be improved by an after-treatment with a solution of an electrolyte such as sodium chloride and/or by adding salts of amines, thiocyanates, thiosulphates, or mordants to the impregnating and/or the after-treatment baths. In examples: (1) a solution of p-toluenesulphonic acid chloride in ethylene dichloride is added to a solution of glucose triacetate in acetic acid, ethylene dichloride and pyridine and after 5-6 hours at 30-40 DEG C. the ethylene dichloride is distilled off and the mass poured into water, washed with water and methyl alcohol, dried and heated with benzyl amine for 1 hour at 80 DEG C.; the product is precipitated with water, washed and mixed with a solution of cellulose triacetate in glacial acetic acid; articles precipitated from this solution are intensively dyed by acid wool dyestuffs such as Acid anthracene red 3BL or Alizarin cyanin green 5G; (2) benzenesulphonic acid chloride, emulsified in water with a condensation product from oleyl alcohol and ethylene oxide, is mixed into a solution of soluble starch in dilute caustic soda and after 8-12 hours at 30-40 DEG C. with addition of caustic soda solution at intervals, the product is filtered off, washed, dried and heated with pyridine for 2 hours at 80-90 DEG C.; after distilling off the excess of pyridine the product is precipitated with water, dried and dissolved in acetic acid with an addition of chromium acetate; acetate artificial silk yarns or fabrics are impregnated for 20-30 minutes with this solution at 40-50 DEG C. and are then passed through a solution at 80-90 DEG C. of sodium chloride or acetate, rinsed and dried; the products may be dyed, fast to alkaline fulling, with Alizarin cyanin green 5G, Acid anthracene brown W or Chromoxan pure blue B; (3) cellulose triacetate yarn is impregnated for 20-30 minutes with a solution in aqueous pyridine or glycol monoacetate at 70-80 DEG C. of the product of (2) from the benzenesulphonic acid ester of starch and pyridine, and further treated as in (3); (4) cellulose triacetate yarn is impregnated as in (2) with a solution of a product obtained by reacting the benzene-sulphonic acid ester of starch with benzylamine for 1 hour at 70-80 DEG C.; the treated yarn may be dyed with acid dyes as in (2) and its affinity is increased for direct dyes such as Benzo fast red L, cellulose acetate dyestuffs and grounding components used in ice-colour dyeings; thus it may be dyed with Cellit fast blue A or may be grounded with Fast blue BB base in an aqueous soap solution at 70-80 DEG C., diazotized and developed with Naphthol ASD; the treated yarn may be bleached with chlorine or hydrogen peroxide or carbonized with hydrochloric acid solution at 100 DEG C. prior to dyeing; (5) acetate artificial silk is impregnated as in (2) with a solution of a product obtained by reacting the benzene sulphonic acid ester of starch for 2 hours on the water bath with a mixture of diethanolamine and pyridine, benzylamine and pyridine, isobutylamine and pyridine, benzylamine and diethanolamine or pyridine and urea etc.; (6) cuprammonium artificial silk is impregnated and further treated as in (3) to impart affinity for acid dyes and increased affinity for direct dyes; (7) a cotton fabric is printed with a paste containing a solution in glacial acetic acid of the reaction product of (2) from the benzenesulphonic acid ester of starch and pyridine, dried, washed and dyed with an acid wool dyestuff having no affinity for cotton to obtain a pattern effect; (8) cellulose artificial silk yarn, impregnated as in (2), is dyed with Acid anthracene brown KE and after-treated with potassium bichromate solution; (9) an emulsion or a solution in pyridine or ethylenediamine of a reaction product from a benzenesulphonic acid ester of methylcellulose and pyridine is added to a cuprammonium cellulose solution from which is then formed a film having affinity for acid wool dyestuffs: (10) an emulsion or solution in aqueous benzylamine of a reaction product from a benzenesulphonic acid ester of starch as in (2) and a mixture of pyridine bases and benzylamine is added to a viscose solution which is then formed into threads or films having an affinity for acid wool dyestuffs.
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1836/37A GB492743A (en) | 1936-12-17 | 1937-01-21 | Process for increasing the affinity for dyestuffs of articles of cellulose, cellulose derivatives or polymers soluble in organic solvents |
FR830800D FR830800A (en) | 1936-12-17 | 1937-12-14 | Process for the production of articles from cellulose and cellulose derivatives |
BE425190D BE425190A (en) | 1936-12-17 | 1937-12-14 | |
NL85503A NL49204C (en) | 1936-12-17 | 1937-12-15 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE830800X | 1936-12-17 | ||
GB1836/37A GB492743A (en) | 1936-12-17 | 1937-01-21 | Process for increasing the affinity for dyestuffs of articles of cellulose, cellulose derivatives or polymers soluble in organic solvents |
Publications (1)
Publication Number | Publication Date |
---|---|
GB492743A true GB492743A (en) | 1938-09-22 |
Family
ID=9728846
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1836/37A Expired GB492743A (en) | 1936-12-17 | 1937-01-21 | Process for increasing the affinity for dyestuffs of articles of cellulose, cellulose derivatives or polymers soluble in organic solvents |
Country Status (4)
Country | Link |
---|---|
BE (1) | BE425190A (en) |
FR (1) | FR830800A (en) |
GB (1) | GB492743A (en) |
NL (1) | NL49204C (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE752518C (en) * | 1941-08-06 | 1952-11-10 | Ig Farbenindustrie Ag | Process for coloring molded articles made from nitrogen-free synthetic resins |
GB2195665A (en) * | 1986-08-19 | 1988-04-13 | Nat Res Dev | Dyeable cellulosic fibrous materials |
-
1937
- 1937-01-21 GB GB1836/37A patent/GB492743A/en not_active Expired
- 1937-12-14 BE BE425190D patent/BE425190A/xx unknown
- 1937-12-14 FR FR830800D patent/FR830800A/en not_active Expired
- 1937-12-15 NL NL85503A patent/NL49204C/xx active
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE752518C (en) * | 1941-08-06 | 1952-11-10 | Ig Farbenindustrie Ag | Process for coloring molded articles made from nitrogen-free synthetic resins |
GB2195665A (en) * | 1986-08-19 | 1988-04-13 | Nat Res Dev | Dyeable cellulosic fibrous materials |
Also Published As
Publication number | Publication date |
---|---|
BE425190A (en) | 1938-01-31 |
FR830800A (en) | 1938-08-09 |
NL49204C (en) | 1940-09-16 |
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