GB488620A - Wetting and penetrating agents for strong alkali lyes - Google Patents
Wetting and penetrating agents for strong alkali lyesInfo
- Publication number
- GB488620A GB488620A GB636/37A GB63637A GB488620A GB 488620 A GB488620 A GB 488620A GB 636/37 A GB636/37 A GB 636/37A GB 63637 A GB63637 A GB 63637A GB 488620 A GB488620 A GB 488620A
- Authority
- GB
- United Kingdom
- Prior art keywords
- lyes
- acid
- naphthenic acids
- added
- acids
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000009736 wetting Methods 0.000 title abstract 4
- 239000003513 alkali Substances 0.000 title abstract 3
- 230000000149 penetrating effect Effects 0.000 title abstract 2
- 239000003795 chemical substances by application Substances 0.000 title 1
- 125000005608 naphthenic acid group Chemical group 0.000 abstract 9
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 abstract 5
- -1 ether alcohols Chemical class 0.000 abstract 4
- 229920000742 Cotton Polymers 0.000 abstract 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 abstract 2
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 2
- 150000001414 amino alcohols Chemical class 0.000 abstract 2
- 239000012752 auxiliary agent Substances 0.000 abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- 229940028356 diethylene glycol monobutyl ether Drugs 0.000 abstract 2
- 239000002270 dispersing agent Substances 0.000 abstract 2
- 150000002148 esters Chemical class 0.000 abstract 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 2
- 235000011187 glycerol Nutrition 0.000 abstract 2
- FGKJLKRYENPLQH-UHFFFAOYSA-N isocaproic acid Chemical compound CC(C)CCC(O)=O FGKJLKRYENPLQH-UHFFFAOYSA-N 0.000 abstract 2
- JCGNDDUYTRNOFT-UHFFFAOYSA-N oxolane-2,4-dione Chemical compound O=C1COC(=O)C1 JCGNDDUYTRNOFT-UHFFFAOYSA-N 0.000 abstract 2
- 159000000000 sodium salts Chemical class 0.000 abstract 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 abstract 2
- XMKDPSQQDXTCCK-UHFFFAOYSA-N 2,4-dimethylpentanoic acid Chemical compound CC(C)CC(C)C(O)=O XMKDPSQQDXTCCK-UHFFFAOYSA-N 0.000 abstract 1
- AAHIANQEIRNOIH-UHFFFAOYSA-N 2-(butylamino)ethane-1,1-diol Chemical compound CCCCNCC(O)O AAHIANQEIRNOIH-UHFFFAOYSA-N 0.000 abstract 1
- MZMOSZFCJWMUBI-UHFFFAOYSA-N 2-(pentylamino)ethane-1,1-diol Chemical compound OC(CNCCCCC)O MZMOSZFCJWMUBI-UHFFFAOYSA-N 0.000 abstract 1
- SALYKAIZVOFAEJ-UHFFFAOYSA-N 2-(pentylamino)ethanol Chemical compound CCCCCNCCO SALYKAIZVOFAEJ-UHFFFAOYSA-N 0.000 abstract 1
- HNNQYHFROJDYHQ-UHFFFAOYSA-N 3-(4-ethylcyclohexyl)propanoic acid 3-(3-ethylcyclopentyl)propanoic acid Chemical compound CCC1CCC(CCC(O)=O)C1.CCC1CCC(CCC(O)=O)CC1 HNNQYHFROJDYHQ-UHFFFAOYSA-N 0.000 abstract 1
- NZQMQVJXSRMTCJ-UHFFFAOYSA-N 3-Methyl-hexanoic acid Chemical compound CCCC(C)CC(O)=O NZQMQVJXSRMTCJ-UHFFFAOYSA-N 0.000 abstract 1
- YKSWLQPMYFCNBG-UHFFFAOYSA-N 3-methyl-octanoic acid Chemical compound CCCCCC(C)CC(O)=O YKSWLQPMYFCNBG-UHFFFAOYSA-N 0.000 abstract 1
- VGVHNLRUAMRIEW-UHFFFAOYSA-N 4-methylcyclohexan-1-one Chemical compound CC1CCC(=O)CC1 VGVHNLRUAMRIEW-UHFFFAOYSA-N 0.000 abstract 1
- MHPUGCYGQWGLJL-UHFFFAOYSA-N 5-methyl-hexanoic acid Chemical compound CC(C)CCCC(O)=O MHPUGCYGQWGLJL-UHFFFAOYSA-N 0.000 abstract 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 1
- XVRXMBJIKCUROE-UHFFFAOYSA-M C(CCC)OC(C)S(=O)(=O)[O-].[Na+] Chemical compound C(CCC)OC(C)S(=O)(=O)[O-].[Na+] XVRXMBJIKCUROE-UHFFFAOYSA-M 0.000 abstract 1
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 abstract 1
- 239000005751 Copper oxide Substances 0.000 abstract 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 abstract 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 abstract 1
- 239000005708 Sodium hypochlorite Substances 0.000 abstract 1
- NIJJYAXOARWZEE-UHFFFAOYSA-N Valproic acid Chemical compound CCCC(C(O)=O)CCC NIJJYAXOARWZEE-UHFFFAOYSA-N 0.000 abstract 1
- 150000001241 acetals Chemical class 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- 125000001931 aliphatic group Chemical class 0.000 abstract 1
- BAZMYXGARXYAEQ-UHFFFAOYSA-N alpha-ethyl valeric acid Chemical compound CCCC(CC)C(O)=O BAZMYXGARXYAEQ-UHFFFAOYSA-N 0.000 abstract 1
- 229910021529 ammonia Inorganic materials 0.000 abstract 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 abstract 1
- 239000002585 base Substances 0.000 abstract 1
- 238000004061 bleaching Methods 0.000 abstract 1
- ZTHQBROSBNNGPU-UHFFFAOYSA-M butyl sulfate(1-) Chemical compound CCCCOS([O-])(=O)=O ZTHQBROSBNNGPU-UHFFFAOYSA-M 0.000 abstract 1
- 239000004359 castor oil Substances 0.000 abstract 1
- 235000019438 castor oil Nutrition 0.000 abstract 1
- 229920002678 cellulose Polymers 0.000 abstract 1
- 239000001913 cellulose Substances 0.000 abstract 1
- 229910000431 copper oxide Inorganic materials 0.000 abstract 1
- 229960004643 cupric oxide Drugs 0.000 abstract 1
- 230000000694 effects Effects 0.000 abstract 1
- 150000002170 ethers Chemical class 0.000 abstract 1
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 abstract 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 abstract 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 abstract 1
- 239000012535 impurity Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 238000012986 modification Methods 0.000 abstract 1
- 230000004048 modification Effects 0.000 abstract 1
- 150000002989 phenols Chemical class 0.000 abstract 1
- 229940072033 potash Drugs 0.000 abstract 1
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 abstract 1
- 235000015320 potassium carbonate Nutrition 0.000 abstract 1
- 235000019353 potassium silicate Nutrition 0.000 abstract 1
- 235000002639 sodium chloride Nutrition 0.000 abstract 1
- 239000011780 sodium chloride Substances 0.000 abstract 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 abstract 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 abstract 1
- 229910052938 sodium sulfate Inorganic materials 0.000 abstract 1
- 235000011152 sodium sulphate Nutrition 0.000 abstract 1
- CEHCOJSZSZWUIG-UHFFFAOYSA-M sodium;propyl sulfate Chemical group [Na+].CCCOS([O-])(=O)=O CEHCOJSZSZWUIG-UHFFFAOYSA-M 0.000 abstract 1
- 150000005846 sugar alcohols Polymers 0.000 abstract 1
- 239000004753 textile Substances 0.000 abstract 1
- 235000005074 zinc chloride Nutrition 0.000 abstract 1
- 239000011592 zinc chloride Substances 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/368—Hydroxyalkylamines; Derivatives thereof, e.g. Kritchevsky bases
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/192—Polycarboxylic acids; Anhydrides, halides or salts thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S516/00—Colloid systems and wetting agents; subcombinations thereof; processes of
- Y10S516/01—Wetting, emulsifying, dispersing, or stabilizing agents
- Y10S516/06—Protein or carboxylic compound containing
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
The wetting and penetrating power of alkali lyes of at least 10 DEG B<\>ae. is increased by the addition of those naphthenic acids which are not salted out by the lyes. In modifications: (a) ether alcohols, amino alcohols or ammonium bases having one or more hydroxyalkyl groups are added when the lyes employed are of lower concentration than the limiting concentration, at which point the activity of the naphthenic acids is at a maximum (b) dispersing agents-other than phenols are added when the concentration of the lyes is not sufficiently high to disperse the naphthenic acids. In examples: (1) shrinkage tables are given for unscoured cotton or crude cotton yarn when immersed in lyes of various strengths containing naphthenic acids of various origins; (2) shrinkage tables are given for cotton when mixtures of naphthenic acids with dihydroxyethylbutylamine, dihydroxyethylamylamine, monohydroxyethylamylamine, diethyleneglycolmonobutylether, the acetal of glycerol and isomeric methylcyclohexanone, glycerol-a -amylether and amylglucoside are added to lyes of various strengths; (3) shrinkage tables are given when naphthenic acids are used with the following dispersing agents; sodium propyl and butylsulphate, the sodium salt of the sulphuric ester of diethyleneglycolmonobutylether, the sodium salt of a highly sulphonated castor oil, sodium butoxyethanesulphonate, isovaleric and methylisobutylacetic acid; (4) naphthenic acids are used in p the manufacture of alkali cellulose, the removal of the resinous impurities is facilitated; (5) naphthenic acids are added to lyes containing the following textile auxiliary agents; common salt, glycerine, sodium sulphate, waterglass, copperoxide ammonia and zinc chloride; the wetting properties are not reduced by the presence of the auxiliary agents; (6) a naphthenic acid is added to a lye containing sodium hypochlorite used for bleaching. The following dispersing agents may also be employed: sulphonic acids of mononuclear alkylated and/or hydroxylated aromatic hydrocarbons, aliphatic and heterocyclic sulphonates with at least three carbon atoms, sulphuric esters of ether alcohols and aminoalcohols, aliphatic monocarboxylic acids with branched or unbranched chains containing 3-12 carbon atoms, e.g. isocaproic acid, isoamylacetic acid, ethylpropylacetic acid, dipropylacetic acid and 1 : 3-dimethylvaleric acid, 3-methylcaproic acid and 3-methylcaprylic acid. Ethers of polyglycerines and acetal compounds of aldehydes with polyhydric alcohols may be used to improve the wetting properties of the naphthenic acids. The use of potash lyes is mentioned. Specifications 27020/97, [Class 42], 276,352, [Class 42 (i)], 414,485, and 461,747 are referred to.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH488620X | 1936-01-09 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB488620A true GB488620A (en) | 1938-07-08 |
Family
ID=4516541
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB636/37A Expired GB488620A (en) | 1936-01-09 | 1937-01-08 | Wetting and penetrating agents for strong alkali lyes |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US2157294A (en) |
| CH (3) | CH201259A (en) |
| DE (1) | DE722258C (en) |
| GB (1) | GB488620A (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2448605A (en) * | 1944-11-13 | 1948-09-07 | Johnson March Corp | Composition for treating coal and the like |
| US2663704A (en) * | 1950-04-19 | 1953-12-22 | American Viscose Corp | Process and composition for producing improved viscose |
| US3140036A (en) * | 1961-10-17 | 1964-07-07 | Joseph C Spery | Wrapper type can carrier |
-
1936
- 1936-01-09 CH CH201259D patent/CH201259A/en unknown
- 1936-01-09 CH CH201260D patent/CH201260A/en unknown
- 1936-01-09 CH CH204116D patent/CH204116A/en unknown
-
1937
- 1937-01-07 US US119528A patent/US2157294A/en not_active Expired - Lifetime
- 1937-01-08 GB GB636/37A patent/GB488620A/en not_active Expired
- 1937-01-08 DE DEC52367D patent/DE722258C/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| CH201260A (en) | 1938-11-30 |
| CH204116A (en) | 1939-04-15 |
| CH201259A (en) | 1938-11-30 |
| DE722258C (en) | 1942-07-06 |
| US2157294A (en) | 1939-05-09 |
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