GB471861A - Improvements in and relating to froth flotation agents - Google Patents
Improvements in and relating to froth flotation agentsInfo
- Publication number
- GB471861A GB471861A GB7045/36A GB704536A GB471861A GB 471861 A GB471861 A GB 471861A GB 7045/36 A GB7045/36 A GB 7045/36A GB 704536 A GB704536 A GB 704536A GB 471861 A GB471861 A GB 471861A
- Authority
- GB
- United Kingdom
- Prior art keywords
- derivative
- copper
- zinc
- water
- thiocarbanilide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000009291 froth flotation Methods 0.000 title abstract 3
- 239000008396 flotation agent Substances 0.000 title 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 7
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 6
- FCSHMCFRCYZTRQ-UHFFFAOYSA-N N,N'-diphenylthiourea Chemical class C=1C=CC=CC=1NC(=S)NC1=CC=CC=C1 FCSHMCFRCYZTRQ-UHFFFAOYSA-N 0.000 abstract 6
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract 6
- 229910052802 copper Inorganic materials 0.000 abstract 6
- 239000010949 copper Substances 0.000 abstract 6
- 239000001117 sulphuric acid Substances 0.000 abstract 6
- 235000011149 sulphuric acid Nutrition 0.000 abstract 6
- 239000002253 acid Substances 0.000 abstract 5
- 239000010802 sludge Substances 0.000 abstract 5
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 4
- 229910052742 iron Inorganic materials 0.000 abstract 4
- 229910052725 zinc Inorganic materials 0.000 abstract 4
- 239000011701 zinc Substances 0.000 abstract 4
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 abstract 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract 3
- KXZJHVJKXJLBKO-UHFFFAOYSA-N chembl1408157 Chemical compound N=1C2=CC=CC=C2C(C(=O)O)=CC=1C1=CC=C(O)C=C1 KXZJHVJKXJLBKO-UHFFFAOYSA-N 0.000 abstract 3
- 229930003836 cresol Natural products 0.000 abstract 3
- 239000011133 lead Substances 0.000 abstract 3
- GWEHVDNNLFDJLR-UHFFFAOYSA-N 1,3-diphenylurea Chemical class C=1C=CC=CC=1NC(=O)NC1=CC=CC=C1 GWEHVDNNLFDJLR-UHFFFAOYSA-N 0.000 abstract 2
- 239000005909 Kieselgur Substances 0.000 abstract 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- 239000003153 chemical reaction reagent Substances 0.000 abstract 2
- 239000012141 concentrate Substances 0.000 abstract 2
- 239000000725 suspension Substances 0.000 abstract 2
- MBMLMWLHJBBADN-UHFFFAOYSA-N Ferrous sulfide Chemical class [Fe]=S MBMLMWLHJBBADN-UHFFFAOYSA-N 0.000 abstract 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 abstract 1
- NYZRMWCPMJEXKL-UHFFFAOYSA-N [Fe].[Cu].[Zn] Chemical compound [Fe].[Cu].[Zn] NYZRMWCPMJEXKL-UHFFFAOYSA-N 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 abstract 1
- ZOOODBUHSVUZEM-UHFFFAOYSA-N ethoxymethanedithioic acid Chemical compound CCOC(S)=S ZOOODBUHSVUZEM-UHFFFAOYSA-N 0.000 abstract 1
- 238000005188 flotation Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000002244 precipitate Substances 0.000 abstract 1
- 238000001556 precipitation Methods 0.000 abstract 1
- 239000000047 product Substances 0.000 abstract 1
- 239000012991 xanthate Substances 0.000 abstract 1
- GTLDTDOJJJZVBW-UHFFFAOYSA-N zinc cyanide Chemical compound [Zn+2].N#[C-].N#[C-] GTLDTDOJJJZVBW-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/004—Organic compounds
- B03D1/012—Organic compounds containing sulfur
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2201/00—Specified effects produced by the flotation agents
- B03D2201/02—Collectors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2203/00—Specified materials treated by the flotation agents; Specified applications
- B03D2203/02—Ores
Landscapes
- Paper (AREA)
Abstract
A thiocarbanilide derivative which is very finely divided and more soluble in water than thiocarbanilide itself is precipitated by mixing water with a solution of thiocarbanilide in sulphuric acid. The product, which is used as a froth flotation reagent, may be separated from the acid and used in the dry state or made into a sludge with water, or may be used as a sludge or a suspension in the dilute acid solution from which it is precipitated. The derivative may be precipitated on an inert insoluble carrier such as diatomaceous earth.ALSO:A froth flotation reagent is prepared by dissolving thiocarbanilide in sulphuric acid and mixing the solution with water to precipitate a derivative which is very finely divided and is more soluble in water than thiocarbanilide itself. The precipitate may be separated from the acid and used in the dry state or made into a sludge with water, or may be used as a sludge or a suspension in the dilute acid solution from which it is precipitated. Alternatively, the acid solution may be added direct to the pulp, the water in the pulp causing precipitation of the derivative. The derivative may be precipitated on an inert insoluble carrier such as diatomaceous earth which may be added to the pulp either dry or as a sludge. The concentration of various mixed sulphide ores is described. A mixed lead and copper concentrate may be obtained from an ore containing lead, copper, zinc, and iron sulphides either by direct flotation with a mixture of the thiocarbanilide derivative and cresol, or by adding sodium cyanide which depresses the zinc and iron and part of the copper, adding sulphuric acid to reactivate the copper, and then floating with the derivative and cresol. A lead-zinc-iron ore may be floated with the derivative, cresol, and sodium hydroxide with or without sodium cyanide to give a lead concentrate, the zinc being then floated, using copper sulphate and derivative, and the iron, if desired, being finally floated with xanthate. A copper-zinc-iron ore may be treated with sodium cyanide or zinc cyanide to depress the zinc and iron and, in part, the copper, and a solution of this carbanilide in concentrated sulphuric acid then added. The derivative is precipitated and the copper is reactivated by the sulphuric acid and can then be floated with the addition of a frothing agent. Alternatively, the sulphuric acid and the derivative may be added separately.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US471861XA | 1935-03-20 | 1935-03-20 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB471861A true GB471861A (en) | 1937-09-09 |
Family
ID=21947523
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB7045/36A Expired GB471861A (en) | 1935-03-20 | 1936-03-09 | Improvements in and relating to froth flotation agents |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB471861A (en) |
-
1936
- 1936-03-09 GB GB7045/36A patent/GB471861A/en not_active Expired
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