GB446813A - Manufacture of amino-carboxylic acids of capillary action - Google Patents
Manufacture of amino-carboxylic acids of capillary actionInfo
- Publication number
- GB446813A GB446813A GB615536A GB615536A GB446813A GB 446813 A GB446813 A GB 446813A GB 615536 A GB615536 A GB 615536A GB 615536 A GB615536 A GB 615536A GB 446813 A GB446813 A GB 446813A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acids
- acid
- fatty acid
- products
- oil fatty
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/325—Amines
- D06M13/342—Amino-carboxylic acids; Betaines; Aminosulfonic acids; Sulfo-betaines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/642—Compounds containing nitrogen
- D06P1/647—Nitrogen-containing carboxylic acids or their salts
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Products useful as wetting, washing, and dispersing agents are obtained by reacting non-hydroxylated secondary amines containing a straight-chain aliphatic, cycloaliphatic or hydroaromatic radicle of at least nine carbon atoms with a salt of a p halogencarboxylic acid. Specified amines are (a) methyldodecylamine, methyloleylamine and N-dodecylaniline; (b) non-hydroxylated secondary amines obtainable, for example, by the process of Specification 421,718, from higher fatty acids or their esters, such as palm nut fatty acid, palm oil fatty acid, montanic acid, acids obtained by the oxidation of paraffin, linseed oil fatty acid, castor oil fatty acid, and hardened fish oil fatty acid; (c) the reaction products of primary amines with higher alcohols, ketones or aldehydes, e.g. the neutral oxidation products of paraffin; (d) cycloaliphatic secondary amines such as those derivable from abietic acids or naphthenic acids containing at least nine carbon atoms. Specified halogencarboxylic acids are monochloracetic, b -chloropropionic, bromosuccinic, and 1 : 2 : 5-chloromethylsalicylic acids. The products may be applied in the textile, leather and paper industries, particularly (a) in washing wool, cotton and linen; (b) as assistants or dispersing or levelling agents in dye baths; (c) for after-soaping prints and improving their fastness to rubbing; (d) as assistants or resists in printing pastes; (e) in fulling baths and bucking lyes; and (f) as softening agents for textiles. The products may be used alone or with appropriate additions such as (a) other wetting, washing or dispersing agents such as turkey red oil, sulphuric esters of higher alcohols, and sulphonic acids of higher aliphatic or aromatic compounds, such as the reaction products of fatty acids with hydroxyalkyl- or aminoalkyl-sulphonic acids; (b) solvents such as carbon tetrachloride, cyclohexanol and benzyl alcohol; (c) salts such as sodium sulphate, perborates and waterglass; and (d) protective colloids such as glue, gelatin and dextrin. In the examples: (1) methyldodecylamine and sodium monochloracetate in aqueous solution yield methyldodecylaminoacetic acid, the sodium salt of which is useful as a softening agent for artificial silk; (2) methyloleylamine and sodium monochloracetate similarly yield methyloleylaminoacetic acid, the sodium salt of which is useful as a wetting agent. A sample has been furnished under Sect. 2 (5) of methyldodecylaminoacetic acid prepared by heating an alcoholic solution of methyldodecylamine with dry sodium monochloracetate. The Provisional Specification includes additional matter, included also in Specification 446,737.ALSO:Products useful as dispersing agents are obtained by reacting non-hydroxylated secondary amines containing a straight-chain aliphatic, cycloaliphatic or hydroaromatic radicle of at least nine carbon atoms with a salt of a halogencarboxylic acid. Specified amines are (a) methyldodecylamine, methyloleylamine and N-dodecylaniline; 9b) non-hydroxylated secondary amines obtainable, for example by the process of Specification 421,718, from higher fatty acids or their esters, such as palm nut fatty acid, palm oil fatty acid, montanic acid, acids obtained by the oxidation of paraffin, linseed oil fatty acid, castor oil fatty acid, and hardened fish oil fatty acid; (c) the reaction products of primary amines with higher alcohols, ketones or aldehydes, e.g. the neutral oxidation products of paraffin; (d) cycloaliphatic secondary amines such as those derivable from abietic acids or naphthenic acids containing at least nine carbon atoms. Specified halogencarboxylic acids are monochloracetic, b -chloropropionic, bromosuccinic, and 1 : 2 : 5-chloromethylsalicylic acids. The products may be used alone or with appropriate additions such as (a) other wetting, washing, or dispersing agents such as turkey red oil, sulphuric esters of higher alcohols, and sulphonic acids of higher aliphatic or aromatic compounds, such as the reaction products of fatty acids with hydroxyalkyl- or amino-alkyl-sulphonic acids; (b) solvents such as carbon tetrachloride, cyclohexanol and benzyl alcohol; (c) salts such as sodium sulphate, perborates and waterglass; and (d) protective colloids such as glue-gelatin and dextrin. In the examples: (1) methyldodecylamine and sodium monochloracetate in aqueous solution yield methyldodecylaminoacetic acid; (2) methyloleylamine and sodium monochloracetate similarly yield methyloleylaminoacetic acid. A sample has been filed under Sect. 2 (5) of methyldodecylaminoacetic acid. the Provisional Specification includes additional matter, included also in Specification 446,737.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB615536A GB446813A (en) | 1934-08-21 | 1934-08-21 | Manufacture of amino-carboxylic acids of capillary action |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB615536A GB446813A (en) | 1934-08-21 | 1934-08-21 | Manufacture of amino-carboxylic acids of capillary action |
Publications (1)
Publication Number | Publication Date |
---|---|
GB446813A true GB446813A (en) | 1936-04-21 |
Family
ID=9809407
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB615536A Expired GB446813A (en) | 1934-08-21 | 1934-08-21 | Manufacture of amino-carboxylic acids of capillary action |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB446813A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2468012A (en) * | 1945-08-06 | 1949-04-19 | Gen Mills Inc | Beta amino propionates |
US3974208A (en) * | 1975-07-09 | 1976-08-10 | Millmaster Onyx Corporation | Amphoteric surface-active agents |
US3991208A (en) * | 1973-12-28 | 1976-11-09 | Millmaster Onyx Corporation | Amphoteric surface-active agents |
-
1934
- 1934-08-21 GB GB615536A patent/GB446813A/en not_active Expired
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2468012A (en) * | 1945-08-06 | 1949-04-19 | Gen Mills Inc | Beta amino propionates |
US3991208A (en) * | 1973-12-28 | 1976-11-09 | Millmaster Onyx Corporation | Amphoteric surface-active agents |
US3974208A (en) * | 1975-07-09 | 1976-08-10 | Millmaster Onyx Corporation | Amphoteric surface-active agents |
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