GB434358A - A process for the production of sulphuric acids of aliphatic amino-ethers of high molecular weight - Google Patents

A process for the production of sulphuric acids of aliphatic amino-ethers of high molecular weight

Info

Publication number
GB434358A
GB434358A GB2864/34A GB286434A GB434358A GB 434358 A GB434358 A GB 434358A GB 2864/34 A GB2864/34 A GB 2864/34A GB 286434 A GB286434 A GB 286434A GB 434358 A GB434358 A GB 434358A
Authority
GB
United Kingdom
Prior art keywords
ethers
acid
acids
aliphatic amino
sulphonic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2864/34A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of GB434358A publication Critical patent/GB434358A/en
Expired legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C309/00Sulfonic acids; Halides, esters, or anhydrides thereof
    • C07C309/01Sulfonic acids
    • C07C309/02Sulfonic acids having sulfo groups bound to acyclic carbon atoms
    • C07C309/03Sulfonic acids having sulfo groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
    • C07C309/07Sulfonic acids having sulfo groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton containing oxygen atoms bound to the carbon skeleton
    • C07C309/09Sulfonic acids having sulfo groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton containing oxygen atoms bound to the carbon skeleton containing etherified hydroxy groups bound to the carbon skeleton

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Sulphonic acids of aliphatic amino ethers which are stated to be wetting, washing and emulsifying agents in the form of their salts with alkalies or organic bases, are prepared by acylating a sulphonic acid of an aliphatic amino-ether or a salt thereof with a fatty acid containing at least ten carbon atoms or a resin acid or a chloride thereof. The free sulphonic acids are stated to be carbonizing agents. Sulphonic acids of aliphatic amino ethers may be prepared by treating with ammonia or a primary amine the halogenated ether sulphonic acids obtained by reacting dihalogen aliphatic ethers with alkali or ammonium sulphite. In an example, b : b <1>-dichlordiethylether is treated with alcoholic sodium sulphite, and the resulting product treated with methylamine and acylated with lauric acid chloride. The latter may be replaced by abietic acid chloride, and ethylamine or aniline may be used instead of methylamine. The use of oleic, palmitic and linoleic acids is mentioned. The Specification as open to inspection under Sect. 91 comprises also the use of naphthenic, myristic, and oleostearic acids and the dihalogenated ethers obtained from an aldehyde, e.g. formaldehyde and hydrochloric acid, the condensation products of halogenated alcohols with aldehydes and hydrochloric acid and ethers of halogen hydrins of polyhydric alcohols. Dichlordimethylether, chlormethyl-b -chlorethylether, methylether of b : b :glycerine dichlorhydrin and alkylether of pentaerythrite di- or trichlorhydrin are specified starting materials. This subject-matter does not appear in the Specification as accepted.ALSO:Sulphonic acids of aliphatic aminoethers, which are stated to be emulsifying agents are prepared by acylating a sulphonic acid of an aliphatic amino ether or a salt thereof with a fatty acid containing at least ten carbon atoms or a resin acid or a chloride thereof. In an example, b : b <1>-dichlordiethylether is treated with alcoholic sodium sulphite and the resulting chlorethersulphonic acid condensed with methylamine and acylated with lauric acid chloride. The latter may be replaced by abietic acid chloride, and ethylamine or aniline may be used instead of methylamine. The use of oleic, palmitic and linoleic acids is mentioned. The Specification as open to inspection under Sect. 91 comprises also the use of naphthenic, myristic and oleostearic acids for the acylation and for the preparation of the sulphonic acids of aliphatic amino ethers, the dihalogenated ethers obtained from an aldehyde, e.g. formaldehyde and hydrochloric acid, the condensation products of halogenated alcohols with aldehydes and hydrochloric acid and ethers of halogen hydrises of polyhydric alcohols are mentioned. Dichlordimethylether, chlormethyl-b - chlorethylether, methylether of b : b -glycerinedichlorhydrin and alkylether of pentaerythrite di- or trichlorhydrin are specified. This subject-matter does not appear in the Specification as accepted.
GB2864/34A 1933-10-07 1934-01-27 A process for the production of sulphuric acids of aliphatic amino-ethers of high molecular weight Expired GB434358A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
AT434358X 1933-10-07

Publications (1)

Publication Number Publication Date
GB434358A true GB434358A (en) 1935-08-27

Family

ID=3674143

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2864/34A Expired GB434358A (en) 1933-10-07 1934-01-27 A process for the production of sulphuric acids of aliphatic amino-ethers of high molecular weight

Country Status (1)

Country Link
GB (1) GB434358A (en)

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