GB411575A - Improvements in the manufacture and production of mixed fertilisers - Google Patents
Improvements in the manufacture and production of mixed fertilisersInfo
- Publication number
- GB411575A GB411575A GB121533A GB121533A GB411575A GB 411575 A GB411575 A GB 411575A GB 121533 A GB121533 A GB 121533A GB 121533 A GB121533 A GB 121533A GB 411575 A GB411575 A GB 411575A
- Authority
- GB
- United Kingdom
- Prior art keywords
- ammonium
- ammonia
- tri
- solution
- sulphate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B7/00—Fertilisers based essentially on alkali or ammonium orthophosphates
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Fertilizers (AREA)
Abstract
Mixed fertilizers are obtained by decomposing crude calcium phosphate with sufficient nitric acid to produce free phosphoric acid and calcium nitrate, dividing the decomposition solution into two parts, precipitating the lime in one part by the addition of ammonium sulphate, separating the precipitate, treating the mother liquor with excess of ammonia to precipitate tri-ammonium phosphate leaving a solution of ammonium nitrate and finally separating the tri-ammonium phosphate and adding it to the other part of the decomposition solution. Alternatively, the crude phosphate is divided into two parts, one part being decomposed with nitric acid and the other with nitric acid and ammonium sulphate. Ammonium nitrate solution, ammonia and/or nitric acid with or without potassium salts such as potassium chloride may be added to the mixture of tri-ammonium phosphate and the other part of the decomposition solution, or to one of the components. The tri-ammonium phosphate may be heated to drive off some of its ammonia before it is added to the other part of the decomposition solution. The tri-ammonium phosphate may be precipated, say at -5 to -10 DEG C., by means of gaseous ammonia obtained by evaporating liquid ammonia, the cold produced in the evaporation being utilized. The precipitated calcium sulphate may be reacted with ammonia and carbon dioxide to reform ammonium sulphate for reuse in the process and calcium carbonate which may be worked up with the ammonium nitrate solution withdrawn from the process to produce a mixed fertilizer consisting of calcium carbonate and ammonium nitrate. According to the Provisional Specification, the lime may be precipitated by means of alkali metal sulphates or mixtures thereof instead of ammonium sulphate; when employing potassium sulphate, it is preferable to separate potassium nitrate from the acid solution before the treatment with ammonia. Examples are given.ALSO:Mixed fertilizers are obtained by decomposing crude calcium phosphate with sufficient nitric acid to produce free phosphoric acid and calcium nitrate, dividing the decomposition solution into two parts, precipitating the lime in one part by the addition of ammonium sulphate, separating the precipitate, treating the mother liquor with excess of ammonia to precipitate tri-ammonium phosphate leaving a solution of ammonium nitrate and finally separating the tri-ammonium phosphate and adding it to the other part of the decomposition solution. Alternatively, the crude phosphate is divided into two parts, one part being decomposed with nitric acid and the other with nitric acid and-ammonium sulphate. Ammonium nitrate solution, ammonia and/or nitric acid with or with out potassium salts such as potassium chloride may be added to the mixture of tri-ammonium phosphate and the other part of the decomposition solution, or to one of the components. The tri-ammonium phosphate may be heated to drive off some of its ammonia before it is added to the other part of the decomposition solution. The tri-ammonium phosphate may be precipated, say at -5 to-10 DEG C., by means of gaseous ammonia obtained by evaporating liquid ammonia, the cold produced in the evaporation being utilized. The precipitated calcium sulphate may be reacted with ammonia and carbon dioxide to reform ammonium sulphate for reuse in the process and calcium carbonate which may be worked up with the ammonium nitrate solution withdrawn from the process to produce a mixed fertilizer consisting of calcium carbonate and ammonium nitrate. According to the Provisional Specification, the lime may be precipitated by means of alkali metal sulphates or mixtures thereof instead of ammonium sulphate; when employing potassium sulphate, it is preferable to separate potassium nitrate from the acid solution before the treatment with ammonia. Examples are given.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB121533A GB411575A (en) | 1933-01-13 | 1933-01-13 | Improvements in the manufacture and production of mixed fertilisers |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB121533A GB411575A (en) | 1933-01-13 | 1933-01-13 | Improvements in the manufacture and production of mixed fertilisers |
Publications (1)
Publication Number | Publication Date |
---|---|
GB411575A true GB411575A (en) | 1934-06-14 |
Family
ID=9718130
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB121533A Expired GB411575A (en) | 1933-01-13 | 1933-01-13 | Improvements in the manufacture and production of mixed fertilisers |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB411575A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2753252A (en) * | 1952-03-22 | 1956-07-03 | Monsanto Chemicals | Fertilizer manufacture |
-
1933
- 1933-01-13 GB GB121533A patent/GB411575A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2753252A (en) * | 1952-03-22 | 1956-07-03 | Monsanto Chemicals | Fertilizer manufacture |
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