GB401712A - Improvements in waterproofing porous materials - Google Patents
Improvements in waterproofing porous materialsInfo
- Publication number
- GB401712A GB401712A GB1369632A GB1369632A GB401712A GB 401712 A GB401712 A GB 401712A GB 1369632 A GB1369632 A GB 1369632A GB 1369632 A GB1369632 A GB 1369632A GB 401712 A GB401712 A GB 401712A
- Authority
- GB
- United Kingdom
- Prior art keywords
- carbon atoms
- acids
- water
- esters
- cellulose
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Colloid Chemistry (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
Abstract
Aqueous media employed for waterproofing comprise (1) open chain or cyclo-aliphatic acids containing at least 8 carbon atoms (including sulphonic acids or sulphuric esters of aliphatic alcohols), or water-soluble ammonium, alkali, or amine salts of such compounds; (2) water-soluble salts of polyvalent metals, which react with the substances in (1), and (3) water-soluble protective colloids obtained by reacting water-insoluble or difficultly soluble organic compounds containing at least 6 carbon atoms and at least one reactive hydrogen atom with an ethylene halogen hydrin, ethylene oxide, polyglycerol or an epihalogen hydrin. The polyvalent metals may be aluminium, copper, zinc, cadmium, calcium, barium, strontium and rare earth metals such as cerium, lanthanum or praseodymium in the form or formates, acetates, chlorides or sulphonates; reagents which react to form p such water-soluble salts, for example sodium aluminate and formic acid may be used. The water-soluble protective colloids correspond to the general formul R-Y-(-C2 H4-O-)x-H or R-Y-(-CH2-CH (OH)-CH2-O)x-H in which x is 2 or more, R is an organic radical containing at least 6 carbon atoms and Y is an oxygen atom or -NH- or -NR1- group in which R1 is an organic radical which may be the same as R. The following may also be added:--soap, ethylene oxide polymers, for example those described in Specification 346,550, [Group IV], aqueous dispersions of waxes such as carnauba, montan, paraffin or beeswax or of wax-like products, for example anhydrides of long chain fatty acids such as palmitic or stearic anhydrides, ethers of alcohols containing at least 12 carbon atoms such as di-octadecyl ether, drying oils such as linseed oil, starch, dextrin, glue, vegetable mucilages, cellulose esters, the reaction products of monochloracetic acid with alkali cellulose described in Specification 138,116, [Class 2 (ii), Cellulose &c.], and hydroxy-alkyl ethers of cellulose, as well as fatty acids, fatty acid esters such as glycerides, hydroxy fatty acid glycerides, fatty acid anhydrides, paraffin wax, alcohols containing at least 10 carbon atoms and their esters, ethers or corresponding amines.ALSO:Water-soluble protective colloids corresponding to the general formul R-Y-(-C2H4-O-)x-H or R-Y-(-CH2-CH (OH) -CH2-O)x-H in which x is 2 or an integral number above 2, R is an organic radical containing at least 6 carbon atoms and Y is an oxygen atom or -NH- or -NR1, group in which R1 is an organic radical which may be the same as R, are obtained by reacting water-insoluble or difficultly soluble organic compounds containing at least 6 carbon atoms and at least one reactive hydrogen atom with an ethylene halogen hydrin, ethylene oxide, polyglycerol or an epihalogen hydrin. The water-insoluble or difficultly soluble organic compounds containing at least 6 carbon atoms include fatty acids such as stearic, lauric, palmitic, oleic, linoleic, ricinoleic, montanic, naphthenic and abietic acids, mixtures of the fatty acids of oils e.g. coconut or palm kernel oils, fatty acids obtained by partial oxidation of paraffin wax by blowing with oxygen containing gases at about 160 DEG C.; the alkyl, hydroxyalkyl and hydroxyamino-alkyl esters of such acids for example the glyceryl esters contained in animal and vegetable oils such as olive, castor, soya bean, sperm and train oils, tallow and wool fat; their methyl, ethyl and butyl esters; their esters with long chain alcohols for example the stearic acid ester of stearyl alcohol or octadecyl alcohol; the amides of such acids or the amide prepared from the acids of coconut fat and mono-ethanolamine as described in Specification 337,737, [Class 2 (iii), Dyes &c.]; the reaction products of long chain fatty acid chlorides with amino-carboxylic acids, for example from oleic or stearic chloride and glycocoll, sarcosine or protalbinic acid; alcohols containing at least 10 carbon atoms, for example olive or lauric alcohol or montanol; alkylamines containing at least 6 carbon atoms and their arylated derivatives, for example octadecylamine, oleylamine, hydroxyethyl-dodecyl-aniline, hydroxyethyl octadecyl aniline and octadecyl - a - naphthylamine; aromatic hydroxy compounds containing at least 10 carbon atoms, for example b -naphthol; aromatic amines, for example a - or b -naphthylamine; high molecular weight natural products such as casein, gelatine and glue; carbohydrates, for example starch and cellulose. Specifications 138,116, [Class 2 (ii), Cellulose &c.], and 346,550 also are referred to.ALSO:Glue or gelatine is treated with ethylene halogen hydrin, ethylene oxide, polyglycerol or an epihalogen hydrin.
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEI44068D DE729286C (en) | 1932-03-23 | 1932-03-23 | Process for impregnating textile fabrics |
GB1369632A GB401712A (en) | 1932-03-23 | 1932-05-12 | Improvements in waterproofing porous materials |
FR753510D FR753510A (en) | 1932-03-23 | 1933-03-20 | Process for impregnating porous materials |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEI44068D DE729286C (en) | 1932-03-23 | 1932-03-23 | Process for impregnating textile fabrics |
GB1369632A GB401712A (en) | 1932-03-23 | 1932-05-12 | Improvements in waterproofing porous materials |
Publications (1)
Publication Number | Publication Date |
---|---|
GB401712A true GB401712A (en) | 1933-11-13 |
Family
ID=25981691
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1369632A Expired GB401712A (en) | 1932-03-23 | 1932-05-12 | Improvements in waterproofing porous materials |
Country Status (3)
Country | Link |
---|---|
DE (1) | DE729286C (en) |
FR (1) | FR753510A (en) |
GB (1) | GB401712A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE739101C (en) * | 1940-03-24 | 1943-09-11 | Hanns Kumetat | Maps and plans mounted on fabric |
US2838422A (en) * | 1953-05-18 | 1958-06-10 | Hoechst Ag | Process for rendering fibrous materials water-repelling |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE765123C (en) * | 1936-12-03 | 1953-11-09 | Chem Fab Theod Rotta | Process for making textile fabrics waterproof and water-repellent while maintaining air permeability |
DE1039476B (en) * | 1955-03-25 | 1958-09-25 | Gerbstoffwerk Oberlahnstein A | Process for the production of impregnation dispersions |
-
1932
- 1932-03-23 DE DEI44068D patent/DE729286C/en not_active Expired
- 1932-05-12 GB GB1369632A patent/GB401712A/en not_active Expired
-
1933
- 1933-03-20 FR FR753510D patent/FR753510A/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE739101C (en) * | 1940-03-24 | 1943-09-11 | Hanns Kumetat | Maps and plans mounted on fabric |
US2838422A (en) * | 1953-05-18 | 1958-06-10 | Hoechst Ag | Process for rendering fibrous materials water-repelling |
Also Published As
Publication number | Publication date |
---|---|
DE729286C (en) | 1942-12-15 |
FR753510A (en) | 1933-10-17 |
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