GB398064A - Process for the manufacture of mixed anhydrides of boric acid and organic acids - Google Patents
Process for the manufacture of mixed anhydrides of boric acid and organic acidsInfo
- Publication number
- GB398064A GB398064A GB34725/32A GB3472532A GB398064A GB 398064 A GB398064 A GB 398064A GB 34725/32 A GB34725/32 A GB 34725/32A GB 3472532 A GB3472532 A GB 3472532A GB 398064 A GB398064 A GB 398064A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acid
- anhydride
- organic acids
- boric
- acetic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000007524 organic acids Chemical class 0.000 title abstract 5
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 title abstract 4
- 239000004327 boric acid Substances 0.000 title abstract 4
- 235000005985 organic acids Nutrition 0.000 title abstract 4
- 150000008064 anhydrides Chemical class 0.000 title abstract 3
- 238000004519 manufacturing process Methods 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 abstract 6
- WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 abstract 6
- 238000010438 heat treatment Methods 0.000 abstract 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 2
- 235000021355 Stearic acid Nutrition 0.000 abstract 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 abstract 2
- 150000001642 boronic acid derivatives Chemical class 0.000 abstract 2
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 abstract 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical class CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 abstract 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 abstract 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 abstract 2
- 239000008117 stearic acid Substances 0.000 abstract 2
- FYSNRJHAOHDILO-UHFFFAOYSA-N thionyl chloride Chemical compound ClS(Cl)=O FYSNRJHAOHDILO-UHFFFAOYSA-N 0.000 abstract 2
- WBYWAXJHAXSJNI-VOTSOKGWSA-M .beta-Phenylacrylic acid Natural products [O-]C(=O)\C=C\C1=CC=CC=C1 WBYWAXJHAXSJNI-VOTSOKGWSA-M 0.000 abstract 1
- LSZSRIVFWDTUJX-UHFFFAOYSA-N 3-phenylprop-2-enoyloxyboronic acid Chemical compound B(O)(O)OC(C=CC1=CC=CC=C1)=O LSZSRIVFWDTUJX-UHFFFAOYSA-N 0.000 abstract 1
- 239000005711 Benzoic acid Substances 0.000 abstract 1
- WBYWAXJHAXSJNI-SREVYHEPSA-N Cinnamic acid Chemical compound OC(=O)\C=C/C1=CC=CC=C1 WBYWAXJHAXSJNI-SREVYHEPSA-N 0.000 abstract 1
- 239000005639 Lauric acid Substances 0.000 abstract 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- 235000010233 benzoic acid Nutrition 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 235000013985 cinnamic acid Nutrition 0.000 abstract 1
- 229930016911 cinnamic acid Natural products 0.000 abstract 1
- 239000003240 coconut oil Chemical class 0.000 abstract 1
- 235000019864 coconut oil Nutrition 0.000 abstract 1
- -1 inorganic acid chlorides Chemical class 0.000 abstract 1
- WBYWAXJHAXSJNI-UHFFFAOYSA-N methyl p-hydroxycinnamate Natural products OC(=O)C=CC1=CC=CC=C1 WBYWAXJHAXSJNI-UHFFFAOYSA-N 0.000 abstract 1
- 150000007522 mineralic acids Chemical class 0.000 abstract 1
- 229910052698 phosphorus Inorganic materials 0.000 abstract 1
- 239000011574 phosphorus Substances 0.000 abstract 1
- GZKLCETYSGSMRA-UHFFFAOYSA-N trioctadecyl borate Chemical compound CCCCCCCCCCCCCCCCCCOB(OCCCCCCCCCCCCCCCCCC)OCCCCCCCCCCCCCCCCCC GZKLCETYSGSMRA-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/02—Boron compounds
- C07F5/022—Boron compounds without C-boron linkages
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Triacidyl borates are prepared by heating boric acid or its anhydride with one or more organic acids, other than acetic acid, in the presence of at least an equivalent quantity of an inorganic acid chloride or organic acid anhydride. When preparing borates of the higher organic acids, it is preferable to employ the anhydrides of lower organic acids in the conversion. According to the examples, (1) tristearyl borate is obtained by heating stearic acid with boric acid or boron trioxide and acetic anhydride, and distilling off the acetic acid formed together with the excess of acetic anhydride; similar products result by replacing the stearic acid with lauric acid, coconut oil acids or benzoic acid; (2) cinnamic boric anhydride is prepared by heating cinnamic acid with boric acid in the presence of thionyl chloride until the evolution of hydrochloric acid ceases. Other inorganic acid chlorides mentioned are phosphorus tri- and pentachlorides.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE398064X | 1931-12-23 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB398064A true GB398064A (en) | 1933-09-07 |
Family
ID=6397306
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB34725/32A Expired GB398064A (en) | 1931-12-23 | 1932-12-07 | Process for the manufacture of mixed anhydrides of boric acid and organic acids |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB398064A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2014143037A1 (en) * | 2013-03-15 | 2014-09-18 | William Brenden Carlson | Boron containing compounds and uses thereof |
| US9352485B2 (en) | 2012-03-23 | 2016-05-31 | Empire Technology Development Llc | Dioxaborinanes and uses thereof |
-
1932
- 1932-12-07 GB GB34725/32A patent/GB398064A/en not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9352485B2 (en) | 2012-03-23 | 2016-05-31 | Empire Technology Development Llc | Dioxaborinanes and uses thereof |
| WO2014143037A1 (en) * | 2013-03-15 | 2014-09-18 | William Brenden Carlson | Boron containing compounds and uses thereof |
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