GB387121A - Improvements in the manufacture of halogenated indigo and its derivatives - Google Patents
Improvements in the manufacture of halogenated indigo and its derivativesInfo
- Publication number
- GB387121A GB387121A GB271332A GB271332A GB387121A GB 387121 A GB387121 A GB 387121A GB 271332 A GB271332 A GB 271332A GB 271332 A GB271332 A GB 271332A GB 387121 A GB387121 A GB 387121A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acid
- chlorine
- indigo
- treated
- halogenated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B7/00—Indigoid dyes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Indole Compounds (AREA)
Abstract
Indigo and thioindigo and their derivatives are halogenated by customary methods in alkyl or cycloalkylsulphuric acids as diluents. The halogenation may be effected at from -10 DEG to 80 DEG , under ordinary or elevated pressure and with or without catalysts. The alkyl or cycloalkylsulphuric acids may be recovered by saponification and re-esterification. According to examples, indigo is halogenated with chlorine in ethylsulphuric acid, with bromine in ethylsulphuric acid to give 5 : 5<1>-dibromindigo, and with chlorine in n-amylsulphuric acid; 4 : 4<1>-dichlorindigo is treated with bromine in methylsulphuric acid; thioindigo is treated with chlorine in n-butylsulphuric acid; 7 : 7<1>-dimethylindigo is treated with chlorine in cyclohexylsulphuric acid. The use of tolyl indigo and propylsulphuric acid is also specified.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB271332A GB387121A (en) | 1932-01-29 | 1932-01-29 | Improvements in the manufacture of halogenated indigo and its derivatives |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB271332A GB387121A (en) | 1932-01-29 | 1932-01-29 | Improvements in the manufacture of halogenated indigo and its derivatives |
Publications (1)
Publication Number | Publication Date |
---|---|
GB387121A true GB387121A (en) | 1933-02-02 |
Family
ID=9744478
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB271332A Expired GB387121A (en) | 1932-01-29 | 1932-01-29 | Improvements in the manufacture of halogenated indigo and its derivatives |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB387121A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112227086A (en) * | 2020-10-20 | 2021-01-15 | 佛山市高敦织染有限公司 | Fabric bright color dye and preparation method thereof |
-
1932
- 1932-01-29 GB GB271332A patent/GB387121A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112227086A (en) * | 2020-10-20 | 2021-01-15 | 佛山市高敦织染有限公司 | Fabric bright color dye and preparation method thereof |
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